1-Hydroxyethylidene-1,1-diphosphonic Acid (HEDP) as a Corrosion Inhibitor of AISI 304 Stainless Steel in a Medium Containing Chloride and Sulfide Ions in the Presence of Different Metallic Cations — Oak Academic Publishing
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1-Hydroxyethylidene-1,1-diphosphonic Acid (HEDP) as a Corrosion Inhibitor of AISI 304 Stainless Steel in a Medium Containing Chloride and Sulfide Ions in the Presence of Different Metallic Cations
Laboratório de Pesquisa e Desenvolvimento em Eletroquímica, Departamento de Química do Centro de Ciências Exatas da Universidade Federal do Espírito Santo, Vitória, Brazil
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Laboratório de Pesquisa e Desenvolvimento em Eletroquímica, Departamento de Química do Centro de Ciências Exatas da Universidade Federal do Espírito Santo, Vitória, Brazil
1 Laboratório de Pesquisa e Desenvolvimento em Eletroquímica, Departamento de Química do Centro de Ciências Exatas da Universidade Federal do Espírito Santo, Vitória, Brazil
2 Laboratório de Pesquisa e Desenvolvimento em Eletroquímica, Departamento de Química do Centro de Ciências Exatas da Universidade Federal do Espírito Santo, Vitória, Brazil
The novelty of this paper is the analysis in a medium containing sulfide ion due to the generation of this ion in petroleum industries, in the refining stage (the sulfide ion is also present on the produced water). The performance of 1-hydroxyethylidene-1,1-diphosphonic acid inhibitor (HEDP) was investigated by potentiodynamic polarization, electrochemical impedance spectroscopy, and weight loss measurements in a dissolution of AISI 304 stainless steel immersed in a solution containing chloride and sulfide ions. The protection of the stainless was increased with the addition of divalent cations (Ca 2+ , Zn 2+ , and Mg 2+ ). Potentiodynamic polarization studies have shown that the inhibitor alone has anodic protection, but the addition of Ca 2+ (10 mg · L -1 ) favors the cathodic protection, and the addition of Zn 2+ (20 mg · L -1 ) and Mg 2+ (10 mg · L -1 ) mixed-type is observed. Electrochemical impedance spectroscopy was performed at three distinct potentials: -0.3 [V vs. SCE], E corr [V vs. SCE], and 0.1 [V vs. SCE]. This revealed that calcium is responsible for favoring the formation of the film and the other elements (zinc and magnesium) favor the stabilization of the protective film. Scanning electron microscopy analysis revealed that the addition of cations provided the adsorption of HEDP on the metal surface. Weight loss results showed that the presence of zinc in a solution containing HEDP favored greater inhibitor efficiency (Zn 2+ η m = 85.2% and for Mg 2+ η m = 70.4%).
KeywordsAISI 304 Stainless SteelHEDPCorrosion InhibitorChloride and Sulfide IonsElectrochemical Impedance Spectroscopy
Li, Y.Z., Wang, X. and Zhang, G.A. (2019) Corrosion Behaviour of 13Cr Stainless Steel under Stress and Crevice in 3.5 wt.% NaCl Solution. Corrosion Science, 163, Article ID: 108290. https://doi.org/10.1016/j.corsci.2018.12.018
Xu, X., Liu, S., Liu, Y., Smith, K. and Cui, Y. (2019) Corrosion of Stainless Steel Valves in a Reverse Osmosis System: Analysis of Corrosion Products and Metal Loss. Engineering Failure Analysis, 105, 40-51. https://doi.org/10.1016/j.engfailanal.2019.06.026
Cui, Y., Liu, S., Smith, K., Yu, K., Hu, H. and Jiang, W. (2016) Characterization of Corrosion Scale Formed on Stainless Steel Delivery Pipe for Reclaimed Water Treatment. Water Research, 88, 816-825. https://doi.org/10.1016/j.watres.2015.11.021
Uhlig, H.H. and Revie, R.W. (2008) Corrosion and Corrosion Control. 2nd Edition, John Wiley & Sons Inc., Hoboken, 513.
Loto, R.T., Loto, C.A., Popoola, A.P.I. and Fedotova, T. (2015) Inhibition Effect of Butan-1-Ol on the Corrosion Behavior of Austenitic Stainless Steel (Type 304) in Dilute Sulfuric Acid. Arabian Journal of Chemistry, 12, 2270-2279. https://doi.org/10.1016/j.arabjc.2014.12.024
Wang, X., Yang, Z., Wang, Z., Shi, Q., Xu, B. and Zhou, C. (2019) The Influence of Copper on the Stress Corrosion Cracking of 304 Stainless Steel. Applied Surface Science, 478, 492-498. https://doi.org/10.1016/j.apsusc.2019.01.291
Zhang, G.A., Hou, X.M., Hou, B.S. and Liu, H.F. (2019) Benzimidazole Derivatives as Novel Inhibitors for the Corrosion of Mild Steel in Acidic Solution: Experimental and Theoretical Studies. Journal of Molecular Liquids, 278, 413-427. https://doi.org/10.1016/j.molliq.2019.01.060
Naveen, E., Ramnath, B.V., Elanchezhian, C. and Mohamed, N.S.S. (2017) Influence of Organic Corrosion Inhibitors on Pickling Corrosion Behaviour of Sinter-Forged C45 Steel and 2% Cu Alloyed C45 Steel. Journal of Alloys and Compounds, 695, 3299-3309. https://doi.org/10.1016/j.jallcom.2016.11.133
Qiang, Y., Zhang, S., Tan, B. and Chen, S. (2018) Evaluation of Ginkgo Leaf Extract as an Eco-Friendly Corrosion Inhibitor of X70 Steel in HCl Solution. Corrosion Science, 133, 6-16. https://doi.org/10.1016/j.corsci.2018.01.008
Rosliza, R., Wan, N.W.B., Izman, S. and Prawoto, Y. (2010) Anti-Corrosive Properties of Natural Honey on Al-Mg-Si Alloy in Seawater. Current Applied Physics, 10, 923-929. https://doi.org/10.1016/j.cap.2009.11.074
Goyal, M., Kumar, S., Behadur, I., Verma, C. and Ebenso, E.E. (2018) Organic Corrosion Inhibitors for Industrial Cleaning of Ferrous and Non-Ferrous Metals in Acidic Solutions: A Review. Journal of Molecular Liquids, 256, 565-573. https://doi.org/10.1016/j.molliq.2018.02.045
Awad, H.S. (2005) The Effect of Zinc-to-HEDP Molar Ratio on the Effectiveness of Zinc-1, Hydroxyethylidene-1,1 Diphosphonic Acid in Inhibiting Corrosion of Carbon Steel in Neutral Solutions. Anti-Corrosion on Methods and Materials, 52, 22-28. https://doi.org/10.1108/00035590510574880
Zheng, J., Chen, H., Cai, W., Qiao, L., Ying, Y., Li, W., Yu, J. and Jiang, L. (2017) Reaction Mechanisms of Copper Electrodeposition from 1-Hydroxyethylidene-1,1-Diphosphonic Acid (HEDP) Solution on Glassy Carbon. Materials Science and Engineering B, 224, 18-27. https://doi.org/10.1016/j.mseb.2017.07.004
Hoffmann, T., Friedel, P., Harnisch, C., Hauβler, L. and Pospiech, D. (2012) Investigation of Thermal Decomposition of Phosphonic Acids. Journal of Analytical and Applied Pyrolysis, 96, 43-53. https://doi.org/10.1016/j.jaap.2012.03.001
Yan, R., Gao, X., He, W., Chen, T. and Ma, H. (2019) 1-Hydroxyethylidene-1,1-Diphosphonic Acid (HEDP)-Zn Complex Thin Films for the Corrosion Protection of Cold-Rolled Steel (CRS). Corrosion Science, 157, 116-125. https://doi.org/10.1016/j.corsci.2019.05.033
Deluchat, V., Bollinger, J., Serpaud, B. and Caullet, C. (1997) Divalent Cations Speciation with Three Phosphonate Ligands in the pH-Range of Natural Waters. Talanta, 44, 897-907. https://doi.org/10.1016/S0039-9140(96)02136-4
Karmán, H., Felhosi, I., Kálmán, E., Cserny, I. and Kovér, L. (1998) The Role of Oxide Layer Formation during Corrosion Inhibition of Mild Steel in Neutral Aqueous Media. Electrochimica Acta, 43, 69-75. https://doi.org/10.1016/S0013-4686(97)00236-3
Sekine, I. and Hirakawa, Y. (1986) Effect of 1-Hydroxyethylidene-1,1-Diphosphonic Acid on the Corrosion of SS 41 Steel in 0.3% Sodium Chloride Solution. Corrosion, 42, 272-277. https://doi.org/10.5006/1.3584904
Sekine, I., Shimode, T., Yuasa, M., Takaoka, K. and Takaoka, K. (1990) Corrosion Inhibition of Structural Steels in the CO2 Absorption Process by 1-(Hydroxyethylidene)-1,1-diphosphonic Acid. Industrial and Engineering Chemistry Research, 29, 1460-1466. https://doi.org/10.1021/ie00103a054
Awad, H.S. and Turgoose, S. (2002) Role of Complexes in Inhibition of Mild Steel by Zinc-1-hydroxyethylidene-1,1-diphosphonic Acid Mixtures. British Corrosion Journal, 37, 147-154. https://doi.org/10.1179/000705902225004347
Mohammedi, D., Benmoussa, A., Fiaud, C. and Sutter, E.M.M. (2004) Synergistic or Additive Corrosion Inhibition of Mild Steel by a Mixture of HEDP and Metasilicate at pH 7 and 11. Materials and Corrosion, 55, 837-844. https://doi.org/10.1002/maco.200403794
Youssef, N., Elshahed, M.S. and McInerney, M.J. (2009) Microbial Processes in Oil Fields: Culprits, Problems, and Opportunities. Advances in Applied Microbiology, 66, 141-251. https://doi.org/10.1016/S0065-2164(08)00806-X
Gieg, L.M., Jack, T.R. and Foght, J.M. (2011) Biological Souring and Mitigation in Oil Reservoirs. Applied Microbiology and Biotechnology, 92, 263-282. https://doi.org/10.1007/s00253-011-3542-6
Fakhru’l-Razi, A., Pendashteh, A., Abdullah, L.C., Biak, D.R., Madaeni, S.S. and Abidin, Z.Z. (2009) Review of Technologies for Oil and Gas Produced Water Treatment. Journal of Hazardous Materials, 170, 530-551. https://doi.org/10.1016/j.jhazmat.2009.05.044
Tibbetts, P.J.C., Buchanan, I.T., Gawel, L.J. and Large, R. (1992) A Comprehensive Determination of Produced Water Composition. In: Ray, J.P. and Engelhardt, F.R., Eds., Produced Water: Technological/Environmental Issues and Solutions, Plenum Publishing Corp., New York, 97-113. https://doi.org/10.1007/978-1-4615-2902-6_9
Hansen, B.R. and Davies, S.R. (1994) Review of Potential Technologies for the Removal of Dissolved Components from Produced Water. Chemical Engineering Research & Design, 72, 176-188.
ASTM A262-15 (2014) Standard Practices for Detecting Susceptibility to Intergranular Attack in Austenitic Stainless Steels.
EIS Spectrum Analyser. http://www.abc.chemistry.bsu.by/vi/analyser
Miao, M., Wang, J. and Hu, W. (2018) Synthesis, Characterization and Inhibition Properties of ZnAlCe Layered Double Hydroxide Intercalated with 1-Hydroxyethylidene-1,1-diphosphonic Acid. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 543, 144-154. https://doi.org/10.1016/j.colsurfa.2018.01.056
ASTM G31-72 (2004) Standard Practive for Laboratory Immersion Corrosion Testing of Metals. American Society for Testing and Materials, West Conshohocken.
ASTM A308/1380M-17 (2017) Standard Practive for Cleaning, Descaling, and Passivation of Stainless Steel Parts, Equipment, and Systems. American Society for Testing and Materials, West Conshohocken.
Qian, S. and Cheng, Y.F. (2019) Synergism of Imidazoline and Sodium Dodecylbenzenesulphonate Inhibitors on Corrosion Inhibition of X52 Carbon Steel in CO2-Saturated Chloride Solutions. Journal of Molecular Liquids, 294, Article ID: 111674. https://doi.org/10.1016/j.molliq.2019.111674
ASM International, Handbook Commitee (2004) Metallography and Microstructure Prepared under the Direction on the ASM Handbook Committee. 9th Edition, Materials Park, 232-234. https://doi.org/10.1149/06120.0025ecst
Soares, T.F., Moreira, R.R., de Andrade, A.R. and Ribeiro, J. (2014) Corrosion Studies of Austenitic and Ferritic Stainless Steels in Solution Containing Chloride Ions. ECS Transactions, 61, 25-36.
Pradhan, S.K., Bruyan, P. and Mandal, S. (2019) Influence of the Individual Microstructural Features on Pitting Corrosion in Type 304 Austenitic Stainless Steel. Corrosion Science, 158, Article ID: 108091. https://doi.org/10.1016/j.corsci.2019.108091
Salasi, M., Shahrabi, T. and Roayaei, E. (2007) Effect of Inhibitor Concentration and Hydrodynamic Conditions on the Inhibitive Behaviour of Combinations of Sodium Silicate and HEDP for Corrosion Control in Carbon Steel Water Transmission Pipes. Anti-Corrosion Methods and Materials, 54, 82-92. https://doi.org/10.1108/00035590710733575
Verma, C., Sorour, A.A., Ebenso, E.E. and Quaraishi, M.A. (2018) Inhibition Performance of Three Naphthyridine Derivatives for Mild Steel Corrosion in 1M HCl: Computation and Experimental Analyses. Results in Physics, 10, 504-511. https://doi.org/10.1016/j.rinp.2018.06.054
EL-Raouf, M.A., Khamis, E.A., Maran, T.H., Kana, A. and Nabel, A.N. (2018) Electrochemical and Quantum Chemical Evaluation of New Bis(coumarins) Derivatives as Corrosion Inhibitors for Carbon Steel Corrosion in 0.5M H2SO4. Journal of Molecular Liquids, 255, 341-353. https://doi.org/10.1016/j.molliq.2018.01.148
Aoun, S.B., Bouklah, M., Khaled, K.F. and Hammouti, B. (2016) Electrochemical Impedance Spectroscopy Investigations of Steel Corrosion in Acid Media in the Presence of Thiophene Derivatives. International Journal of Electrochemical Science, 11, 7343-7358. https://doi.org/10.20964/2016.09.07
Zenobi, M.C., Luengo, C.V., Avena, M.J. and Rueda, E.H. (2008) An ATR-FTIR Study of Different Phosphonic Acids in Aqueous Solution. Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 70, 270-276. https://doi.org/10.1016/j.saa.2007.07.043
Reznik, L.Y., Sathler, L., Cardoso, M.J.B. and Albuquerque, M.G. (2008) Experimental and Theoretical Structural Analysis of Zn(II)-1-hydroxyethane-1,1-diphosphonic Acid Corrosion Inhibitor Films in Chloride Ions Solution. Materials and Corrosion, 59, 685-690. https://doi.org/10.1002/maco.200804108
Moreira, R., Soares, T. and Ribeiro, J. (2014) Electrochemical Investigation of Corrosion on AISI 316 Stainless Steel and AISI 1010 Carbon Steel: Study of the Behaviour of Imidazole and Benzimidazole as Corrosion Inhibitors. Advances in Chemical Engineering and Science, 4, 503-514. https://doi.org/10.4236/aces.2014.44052
Fu, J., Li, F., Sun, J., Cui, K., Du, X. and Wu, Y. (2019) Effect of Crystallographic Orientations on the Corrosion Resistance of Fe-17Cr Ferritic Stainless Steel. Journal of Electroanalytical Chemistry, 841, 56-62. https://doi.org/10.1016/j.jelechem.2019.04.031
Verma, C., Singh, A., Pallikondo, G., Chakravarty, M. and Quraishi, M.A. (2015) Electrochemical, Thermodynamic, Surface and Theoretical Investigation of 2-Aminobenzene-1,3-dicarbonitriles as Green Corrosion Inhibitor for Aluminum in 0.5M NaOH. Journal of Molecular Liquids, 209, 767-778. https://doi.org/10.1016/j.molliq.2015.06.039
Askari, M., Aliofkhazrali, M., Ghaffari, S. and Hajizadeh, A. (2018) Film Former Corrosion Inhibitors for Oil and Gas Pipelines—A Technical Review. Journal of Natural Gas Science and Engineering, 58, 92-114. https://doi.org/10.1016/j.jngse.2018.07.025
Córdoba-Torres, P., Mesquita, T.J., Devos, O., Tribollet, B., Rocha, V. and Nogueira, R.P. (2012) Theory of the Frequency Dispersion of Electrode Polarization. Topology of Networks with Fractional Power Frequency Dependence. Electrochimica Acta, 72, 172-178. https://doi.org/10.1016/j.electacta.2012.04.020
Zhang, H.H., Pang, X. and Gao, K. (2018) Localized CO2 Corrosion of Carbon Steel with Different Microstructures in Brine Solutions with an Imidazoline-Based Inhibitor. Applied Surface Science, 442, 446-460. https://doi.org/10.1016/j.apsusc.2018.02.115
Felhosi, I., Keresztes, Z., Kármán, F.H., Mohai, M., Bertóti, I. and Kálmán, E. (1999) Effects of Bivalent Cations on Corrosion Inhibition of Steel by 1-Hydroxyethane-1,1-diphosphonic Acid. Journal of The Electrochemical Society, 146, 961-969. https://doi.org/10.1149/1.1391706
Yan, D., Ye, Y., Su, Y., Liu, S., Gong, D. and Zhao, H. (2019) Corrosion Inhibition Behavior and Mechanism of N-Doped Carbon Dots for Metal in Acid Environment. Journal of Cleaner Production, 229, 180-192.
Khan, G., Basirun, W.J., Kazi, S.N., Ahmed, P., Magaji, L., Ahmed, S.M., Khan, G.M., Rehman, M.A. and Badry, A. (2017) Electrochemical Investigation on the Corrosion Inhibition of Mild Steel by Quinazoline Schiff Base Compounds in Hydrochloric Acid Solution. Journal of Colloid and Interface Science, 502, 134-145. https://doi.org/10.1016/j.jcis.2017.04.061
Fernandes, C.M., Fagundes, T.S.F., dos Santos, N.E., Rocha, T.S.M., Garrett, R., Borges, R.M., Muricy, G., Valverde, A.L. and Ponzio, E.A. (2019) Ircinia strobilina Crude Extract as Corrosion Inhibitor for Mild Steel in Acid Medium. Electrochimica Acta, 312, 137-148. https://doi.org/10.1016/j.electacta.2019.04.148
Loto, R.T., Joseph, O.O. and Akanji, O. (2015) Electrochemical Corrosion Behaviour of Austenitic Stainless Steel (Type 304) in Dilute Hydrochloric Acid Solution. Journal of Material Environmental Science, 6, 2409-2417.
Ma, Y.F. Corrosive Effects of Chlorides on Metals. http://cdn.intechopen.com/pdfs/33625/intechcorrosive_effects_of_chlorides_on_metals.pdf
Haddadi, A.S., Alibakhshi, E., Bahlakeh, G., Ramezanzadeh, B. and Mahdavian, M. (2019) A Detailed Atomic Level Computational and Electrochemical Exploration of the Juglans regia Green Fruit Shell Extract as a Sustainable and Highly Efficient Green Corrosion Inhibitor for Mild Steel in 3.5 wt% NaCl Solution. Journal of Molecular Liquids, 284, 682-699. https://doi.org/10.1016/j.molliq.2019.04.045