FAPbI 3 and FA(Mn:Pb)I 3 perovskite films were prepared and evaluated through steady and transient absorption spectroscopy. According to the analysis using Elliot’s model, there were no considerable differences except for the absorption intensity between FAPbI 3 and FA(Mn:Pb)I 3 perovskite films: the value of the optical gap ( E g ) and the position of exciton resonance ( E 0 ) were the same. The femtosecond transient absorption showed biexponential relaxation properties of the charge carriers, suggesting that biexcitons are more easily generated in FA(Mn:Pb)I 3 than FAPbI 3 perovskite. The generation of biexcitons in FA(Mn:Pb)I 3 was also confirmed by the photon pump fluence dependence. Moreover, we were able to estimate the average number of absorbed photons <N> directly from the photon pump power dependence without needing any further experimental measurements such as photoluminescence. Our findings may offer a new way of understanding photoinduced carrier dynamics in perovskite manganites.
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