Natural Silicate as a Solid Support for the Calix[4]Thiophosphorus Derivative for Removal Mercury (II), as Picrate from Water — Oak Academic Publishing
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Natural Silicate as a Solid Support for the Calix[4]Thiophosphorus Derivative for Removal Mercury (II), as Picrate from Water
School of Chemical Engineering, Chemical Engineering Department, Altiplano National University, Puno, Perú
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School of Chemical Engineering, Chemical Engineering Department, Altiplano National University, Puno, Perú
1 School of Chemical Engineering, Chemical Engineering Department, Altiplano National University, Puno, Perú
2 School of Chemical Engineering, Chemical Engineering Department, Altiplano National University, Puno, Perú
Currently a technique widely used for gold extraction is mercury by amalgamation technique, the tailing produced pollutes water of all kinds, so it is necessary to develop a form of selective mitigation, for which it is necessary to use complexing agents based on calixarene functionalized with mercury sequestering agents. These are immobilized by adding supports based on natural silica to form polymers and make them insoluble in all types of solvents, so that they can be used as an extractor and at the same time regenerate to their original properties for continuous reuse.
Gutsche, C.D. (2008) Calixarenes. In: Stoddart, F.J., Ed., Monographs in Supram o lecular Chemistry , The Royal Society of Chemistry, London, 77-112.
Gutsche, C.D. (1998) Calixarenes Revisited. In: Stoddart, F.J., Ed., Monographs in Supramolecular Chemistry , The Royal Society of Chemistry, London, 79-114.
Vicens, J. and Böhmer, V. (1991) Calixarenes. In: A Versatile Class of Macrocyclic Compounds , Kluwer Academic Publishers, Dordrecht, 200.
Böhmer, V. (1995) Calixarenes, Macrocycles with (Almost) Unlimited Possibilities. Angewandte Chemie International Edition in English , 34. 713-745. https://doi.org/10.1002/anie.199507131
Atwood, J.L. and Bott, S.G. (1991) Water-Soluble Calixarene Salts. A Class of Compounds with Solid-State Structures Resembling Those of Clays. In: Vicens, J. and Böhmer, V., Eds., Calixarenes : A Versatily Class of Macrocyclic Compound s , Kluwer Academic Publishers, Dordrecht, 199-210. https://doi.org/10.1007/978-94-009-2013-2_8
Ikeda, A. and Shinkai (1997) Novel Cavity Design Using Calix[n]arene Skeletons: Toward Molecular Recognition and Metal Binding. Chemical Reviews , 97, 1713-1734. https://doi.org/10.1021/cr960385x
Uysal, G., Memon, S. and Yilmaz, M. (2002) Synthesis and Binding Properties of Polymeric Calix[4]arene Nitriles. Reactive & Functional Polymers , 50, 77-84. https://doi.org/10.1016/S1381-5148(01)00099-2
Akceylan, E., Yilmaz, A. and Yilmaz, M. (2013) Synthesis and Properties of Calix[4]arene Polymers Containing Amide Groups: Exploration of Their Extraction Properties towards Dichromate and Nitrite Anions. Macromolecular Research , 21, 1091-1096. https://doi.org/10.1007/s13233-013-1152-0
Arnaud-Neu, F. and Schwing-Weill, M.J. (1997) Calixarenes, New Selective Molecular Recpetors. Synthetic Metals , 90, 157-164. https://doi.org/10.1016/S0379-6779(98)80001-5
Memon, S., Uysal, G. and Yilmaz, M. (2001) Syntheses and Binding Properties of polymericcalix[4]crown-4. Reactive &FunctionalPolymers , 47, 165-174. https://doi.org/10.1016/S1381-5148(01)00029-3
Morzherin, Y., Rudkevich, D.M., Verboom, W. and Reinhoudt, D.N. (1993) Chlorosulfonylated Calix[4]arenes: Precursors for Neutral Anion Receptors with a Selectivity for Hydrogen Sulfate. The Journal of Organic Chemistry , 58, 7602-7605. https://doi.org/10.1021/jo00078a052
Scheerder, J., Fochi, M., Engbersen, J.F.J. and Reinhoudt, D.N. (1994) Urea-Deri-vatezed p- Tert -butylcalix[4]arenes: Neutral Ligands for Selective Anion Complexation. The Journal of Organic Chemistry , 59, 7815-7820. https://doi.org/10.1021/jo00104a044
Shahabuddin Memon, S., Gülderen Uysal, G. and Yilmaz, M. (2001) Synthesis and Binding Properties of Polymeric Calix[4]crown-4. Reactive and Functional Pol y mers , 47, 165-174. https://doi.org/10.1016/S1381-5148(01)00029-3
Yang, Y.S., Ko, S.W., Song, I.H., Ryu, B.J. and Nam, K.C. (2003) Synthesis and Anion Binding Properties of the Bridged Urea Derivatives of Calix[4]arene. Bulletin of the Korean Chemical Society , 24, 681-683. https://doi.org/10.5012/bkcs.2003.24.5.681
Kawaguchi, M., Ikeda, A., Hamachi, I. and Shinkai, S. (1999) Metal-Induced Conformational Changes in Calix[n]arenes Can Control the Electron-Transfer Efficiency between Porphyrin and [60]fullerene in an On-Off Manner. Tetrahedron Letters , 40, 8245-8249. https://doi.org/10.1016/S0040-4039(99)01750-5
Timmerman, P., Brinks, E.A., Verboom, W. and Reinhoudt, D.N. (1995) Synthetic Receptors with Preorganized Cavities That Complex Prednisolone-21-Acetate. Journal of the Chem ical Society , Chemical Communications , No. 4, 417-418. https://doi.org/10.1039/c39950000417
Shinkai, S., Hawaguchi, H. and Manabe, O. (1998) Selective Adsorption of UO 2 2 to a Polymer Resin Immobilizing Calixarene-Based Uranophiles. Journal of Polymer Science Part C : Polymer Letters , 26, 391-396. https://doi.org/10.1002/pol.1988.140260903
Harris, S.J., Barret, G. and McKervey, M.A. (1991) Polymeric Calixarenes. Synthesis, Polymerisation and Na Complexation of a Calix[4]arene Methacrylate. Journal of the Chemical Society , Chemical Communications , No. 17, 1224-1225. https://doi.org/10.1039/c39910001224
Ohto, K., Tanaka, Y. and Inoue, K. (1997) Adsorptive Separation of Lead and Zinc Ions by Novel Type of Calix[4]arene Carboxylate Resin Immobilized with Polyallylamin. Chemistry Letters , 26, 647-648. https://doi.org/10.1246/cl.1997.647
Hajipour, A., Habibi, S. and Ruoho, A.E. (2010) Synthesis and Characterization of Novel Optically Active Poly(amide-imide)s and Poly(ester-imide)s Containing Calix[4]arene and Amino Acid Units with Binding Ability towards Alkali Metal and Toxic Heavy Metal Cations. Chinese Journal of Polymer Science , 28, 731-743. https://doi.org/10.1007/s10118-010-9125-7
Nishikubo, T., Kameyama, A. and Kudo, H. (2003) Novel High Performance Materials. Calixarene Derivatives Containing Protective Groups and Polymerizable Groups for Photolithography, and Calixarene Derivatives Containing Active Ester Groups for Thermal Curing of Epoxy Resins. Polymer Journal , 35, 213-229. https://doi.org/10.1295/polymj.35.213
Yilmaz, M. and Deligöz, H. (1994) Synthesis of Polymer-Supported Calix[4]arenes and Selective Extraction of Fe 3 . Macromolecular Research , 31, 137.
Deligöz, H., Tavasli, M. and Yilmaz, M. (1994) Selective Extraction of Fe 3 by Polymerirc Calix[4]arene. Journal of Polymer Science Part A : Polymer Chemistry , 32, 2961-2964. https://doi.org/10.1002/pola.1994.080321518
Deligöz, H. (2002) Synthesis and Propierties of a Series of Novel Calix[6]arene Diazo Derivatives. Journal of Inclusion Phenomena and Macrocyclic Chemistry , 43, 285-289. https://doi.org/10.1023/A:1021278504344
Deligöz, H. (2001) The Synthesis of Sodium and Potassium Complexes of Two Calix[4]arene Derivatives. Journal of Inclusion Phenomena and Macrocyclic Chem i stry , 39, 123-125. https://doi.org/10.1023/A:1008192522721
Miloshev, S. and Petrova, P. (2006) Preparation of Copolymers of p-Isopropenyl-calix[8]arene and Styrene. Polymer Bulletin , 56, 485-494. https://doi.org/10.1007/s00289-005-0501-3
Shinkai, S., Mori, S., Koreishi, H., Tsubaki, T. and Manabe, O. (1986) Hexasulfonated Calix[6]arene Derivatives: A New Class of Catalysts, Surfactants, and Host Molecules. Journal of the American Chemical Society , 108, 2409-2416. https://doi.org/10.1021/ja00269a045
Robledo, J. and Rodríguez, P. (2021) Calcium Silicate Cements Application in Lateral Root Perforation Repair: A Case Report with 16-Month Follow-Up. Open Journal of Stomatology , 11, 317-324. https://doi.org/10.4236/ojst.2021.118028
Danil de Namor, A.F., Aparicio-Aragon, W.B., Nwogu, N., El Gamouz, A., Piro, O.E. and Casal, R. (2001) Calixarene and Resorcarene Based Receptors: From Structural and Thermodynamic Studies to the Synthesis of a New Mercury(II) Selective Material. The Journal of Physical Chemistry B , 115, 6922-6934. https://doi.org/10.1021/jp110195f
Flaschka, H.A. (1968) EDTA Titrations. Pergamon Press Inc., New York, USA.