Hydrogen Production from Glucose by Layered Double Oxides Photocatalysis

Abstract

Hydrogen (H 2 ) production from renewable biomass resources plays a significant role in solving the shortage of fossil energy; hence, there is an interest in investigating alternative, cleaner processes. This work intends to study the photocatalytic production of hydrogen from D-(+)-Glucose by using different groups of catalysts that have been prepared (M 2 + = Zn, Mg and Ni) M 2 + /Ti 4 + Al 3 + -LDHs (layered double hydroxides). It is then loaded Pd on the catalyst, and the effect of the composite catalyst, layered double hydroxides, is measured. After calcining, the catalyst for the conversion of Layered Double Hydroxides (LDHs) to Layered Double Oxides (LDOs) is used to produce hydrogen gas from glucose. Photocatalytic reforming of glucose-derived compounds is an efficient method for the production of hydrogen. The purpose is to study the effect of metal ions on layered double oxide (LDO) materials by loading Pd and investigate hydrogen production from glucose. The metal cations in the layer were distributed through the preparation of the catalyst process by ion and atom scale between the layers, which were dispersed systematically, as well as the controlled component catalysis. This process shows that ZnTiAl-LDO had the best effect as a catalyst in producing hydrogen compared to NiTiAl-LDO and MgTiAl-LDO.