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Determination of Trace Elements in the Tamsagbulag and Tagaan Els crude oils and Their Distillation Fractions Using by ICP-OES
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Advances in Chemical Engineering and Science·Volume 02 (2011)·Pages 113–117·Published 3 November 2011·DOI10.4236/aces.2012.21013
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Abstract
Thirty one trace elements were determined in the petroleum and its fractions of 250℃ - 350℃, 350℃ - 450℃ and up 450℃ by inductively coupled plasma optical emission spectrometry. Such analyses are important for technical diagnostics as well as specific sample characteristics. The sample preparation together with an efficient sample introduction allowed a fast quantification of the analytes using calibration curves prepared with analyte organic standards. Trace element occurrences, forms, distributions are examined as well as their implications in terms of reservoir geochemistry, oil refining and environment.
KeywordsTrace ElementsPetroleumICP-EOSFractionationTertiary PeriodMesozoi
- E. P. Kalinin, “Geochemical Specificity of Oil and Its Nature,” The Bulletin, Vol. 1, 2009, pp. 6-12.
- S. B. John and J. W. Wenger, “Metal Content of Twenty-Four Petroleums,” Journal of Chemical and Engineering data, Vol. 5, No. 4, 1960, pp. 553-557. doi:10.1021/je60008a038
- P. F. Gojik, V. A. Kraushkin, V. P. Klochko, E. E. Guseva and R. M. Morozova, “Vanadium and Nickel in Natural Oil Asia, Africa, the Europe, Northern and South America,” Ukrain National Academy, Vol. 6, No. 3, 2007. pp. 137-141.
- M. S. Roseli, L. S. M. Andri, L. P. S. Carmem and Q. A. Ricardo, “Determination of Mo, Zn, Cd, Ti, Ni, V, Fe, Mn, Cr and Co in Crude Oil Using Inductively Coupled Plasma Optical Emission Spectrometry and Sample Introduction as Detergentless Microemulsions,” Microchemical Journal, Vol. 82, No. 2, 2006, pp. 137-141. doi:10.1016/j.microc.2006.01.005
- J. Sainbayar, A. Esetjan, T. Tugsuu, G. Sukhdorj and G. Monkhoobor, “Vanadium and Nickel in Oil Таmsagbulag by Spectroscopy,” Proceedings of the Mongolian Academy of Sciences, Vol. 2, 2009, pp. 37-45.
- H. F. Royston and J. V. B. Gary, “Geоchemistry of Metal Complexes in Petroleum, Source Rocks and Coals,” American Chemical Society, 1987, pp. 2-16.
- N. P. Slotvinskii-Sidak and V. K. Аndreev, “Vanadium in the Nature and Technics,” Moscow, 1979, pp. 10-24.
- A. J. G. Barwise, “Role of Nickel and Vanadium in Petroleum Classification,” Energy and Fuels, Vol. 4, No. 4, 1990, pp. 647-652. doi:10.1021/ef00024a005
- C. B. Boss and K. J. Fredeen, “Plasma Optical Emission Spectrometry 1999 in USA,” 1999, pp. 21-78.
- ASTM D 5185, “Standard Test Method for Determination of Additive Elements, Wear Metals and Contaminants in Used Lubricating Oils and Determination Selected Elements in Base Oils by Inductively Coupled Plasma Atomic Emission Spectrometry,” 2009.
- G. Michael and W. L. Arthur, “Methods Development for Trace Metal Characterization of Crude Oil by Inductively Coupled Plasma Atomic Emission Spectroscopy,” Modern Instrumental Methods of Elemental Analysis of Petroleum Products and Lubricants, 1991, pp. 62-69.
- I. N. Diyarov, I. Y. Batueva and A. N. Sadikov, “Crude oil Chemistry,” Marcel Dekker, Leningrad, 1990, pp. 30-32.
- ASTM D 1744, “Standard Test Method for Determination of Water in Liquid Petroleum Products by Karl Fischer Reagent,” 1992.