Crystallization Kinetics and Magnetic Properties of Fe<sub>40</sub>Ni<sub>40</sub>B<sub>20</sub> Bulk Metallic Glass
- 1 LASEA, Department of Chemistry, University of Badji Mokhtar, Annaba, Algeria
- 2 LASEA, Department of Chemistry, University of Badji Mokhtar, Annaba, Algeria;University of 08 mai 1945 Guelma, Guelma, Algeria;Università di Torino, Via P. Giuria 9, Torino, Italy
- 3 Università di Torino, Via P. Giuria 9, Torino, Italy
Abstract
Fe - based b ulk metallic glasses (BMGs) have been extensively studied due to their potential technological applications and their interesting physical properties such as a low modulus of elasticity, high yielding stress and good magnetic properties. In the present work, the bulk metallic glass (BMG) formation of Fe 40 Ni 40 B 20 (numbers indicate at %) with a ribbon form was fabricated by the single roller melt-spinning method. Rapid solidification leads to a fully amorphous structure for all compositions. The thermal properties associated with crystallization temperature of the glassy samples were measured using differential scanning calorimetry (DSC) at a heating rate of 10 ℃ /mn. The microstructure and constituent phase of the alloy composite have been analyzed by using X-ray diffractometry (XRD). The effect of high temperature on the isothermal crystallization of Fe 40 Ni 40 B 20 ribbon was investigated by HTX-ray diffraction. In addition, these ribbon glasses also exhibit good soft magnetic properties with M-H curvature measured under the magnetic fields between –1 kOe and 1 kOe.
- R. Hasegawa, “Present Status of Amorphous Soft Magnetic Alloys,” Journal of Magnetism and Magnetic Materials, Vol. 215-216, 2000, pp. 215-216, 240. http://dx.doi.org/10.1016/S0304-8853(00)00126-8
- T. Hu and J. P. Desai, “Soft-Tissue Material Properties under Large Deformation: Strain Rate Effect,” Proceedings of the 26th Annual International Conference of the IEEE EMBS, San Francisco, 1-5 September 2004, pp. 2758-2761.
- R. W. Cahn, “Rapidly Solidified Alloys,” H. H. Liebermann, Ed., Marcel Dekker, New York, 1993.
- E. Wit and J. McClure, “Statistics for Microarrays: Design, Analysis, and Inference,” 5th Edition, John Wiley & Sons Ltd., Chichester, 2004. http://dx.doi.org/10.1002/0470011084
- H. S. Chen, “Thermodynamic Considerations on the Formation and Stability of Metallic Glasses,” Acta Metallurgica, Vol. 22, No. 12, 1974, pp. 1505-1511. http://dx.doi.org/10.1016/0001-6160(74)90112-6
- B. M. S. Giambastiani, “Evoluzione Idrologica ed Idrogeologica Della Pineta di San Vitale (Ravenna),” Ph.D. Thesis, Bologna University, Bologna, 2007.
- A. Inoue, Y. Shinohara and J. S. Gook, “Thermal and Magnetic Properties of Bulk Fe-Based Glassy Alloys Prepared by Copper Mold Casting,” Materials Transactions JIM, Vol. 36, No. 12, 1995, pp. 1427-1433.
- A. Inoue, “Stabilization of Metallic Supercooled Liquid and Bulk Amorphous Alloys,” Acta Materialia, Vol. 48, No. 1, 2000, pp. 279-306. http://dx.doi.org/10.1016/S1359-6454(99)00300-6