Basic Engineering of a Two-Stage Process for Co-Upgrading Natural Gas and Petroleum Coke
- 1 Centro de Química, Instituto Venezolano de Investigaciones Científicas, Caracas, Venezuela
- 2 Centro de Química, Instituto Venezolano de Investigaciones Científicas, Caracas, Venezuela
Abstract
This communication highlights the possibility of using a novel two-stage process for the co-upgrading of natural gas and petroleum coke into liquid hydrocarbons. The first stage consists of the catalytic dehydroaromatization of methane characterized by producing hydrogen and aromatics: benzene, naphtalene, toluene, etc. The non-reacted methane plus hydrogen and aromatics produced in the first stage are directed to the second stage to react with the petroleum coke. Basic engineering analysis of proposed two-stage process suggests light petroleum production of 160,000 bbl/day from 20,000 ton/day of petroleum coke actually by-produced from Venezuelan Orinoco’s heavy oil belt. Residual coke should be volatiles free therefore useful as a calcined coke.
- Ma, S.Q., Guo, X.G., Zhao, L.X., Scottc, S. and Bao, X.H. (2013) Recent Progress in Methane Dehydroaromatization: From Laboratory Curiosities to Promising Technology. Review. Journal of Energy Chemistry, 22, 1-20. http://dx.doi.org/10.1016/S2095-4956(13)60001-7
- Calkins, W.H. and Bonifaz, C. (1984) Coal Flash Pyrolysis: 5. Pyrolysis in an Atmosphere of Methane. Fuel, 63, 1716-1719. http://dx.doi.org/10.1016/0016-2361(84)90106-6
- Voigtmann, M.F., Chen, M. and Batts, B.D. (1995) Coal Pyrolysis with Methane in a Reducing Environment. Coal Science and Technology, 24, 1399-1402. http://dx.doi.org/10.1016/S0167-9449(06)80066-2
- Cai, J.Q., Wang, Y.P. and Huang, Q.W. (2008) Rapid Liquefaction of Longkou Lignite Coal by Using a Tubular Reactor under Methane Atmosphere. Fuel, 87, 3388-3392. http://dx.doi.org/10.1016/j.fuel.2008.06.001
- Yang, K., Batts, B.D., Wilson, M.A., Gorbaty, M.L., Maa, P.S., Long, M.A., He, S.X.J. and Attalla, M.I. (1997) Reaction of Methane with Coal. Fuel, 76, 1105-1115. http://dx.doi.org/10.1016/S0016-2361(97)00134-8
- Kamei, O., Onoe, K., Marushima, W. and Yamaguchi, T. (1998) Brown Coal Conversion by Microwave Plasma Reactions under Successive Supply of Methane. Fuel, 77, 1503-1506. http://dx.doi.org/10.1016/S0016-2361(98)00055-6
- Dry, M.E. (1981) The Fischer-Tropsch synthesis. In: Anderson, J.R. and Boudart, M., Eds., Catalysis Science and Technology, Springer-Verlag, Berlin, Vol. 1, 159-255.
- Winslow, J. and Schmetz, E. (2009) Direct Coal Liquefaction Overview Presented to NETL. http://bellona.org/filearchive/fil_Direct_Coal_Liquefaction_Overview.pdf
- Muradov, N., Smith, F. and Raissi, A. (2005) Catalytic Activity of Carbons for Methane Decomposition Reaction. Catalysis Today, 102, 225-233. http://dx.doi.org/10.1016/j.cattod.2005.02.018
- Bai, Z.Q., Chen, H.K., Li, W. and Li, B.Q. (2006) Hydrogen Production by Methane Decomposition over Coal Char. International Journal of Hydrogen Energy, 31, 899-905. http://dx.doi.org/10.1016/j.ijhydene.2005.08.001
- Quintero, D., Padilla, D., Labady, M. and Laine, J. (2007) A Transient Behavior in the Initial Production of Aromatic Compounds from Methane Catalyzed by Mo/HZSM-5. Catalysis Letters, 118, 244-247. http://dx.doi.org/10.1007/s10562-007-9177-7
- Heinemann, H. (1981) A Brief History of Industrial Catalysis. In: Anderson, J.R. and Boudart, M., Eds., Catalysis Science and Technology, Vol. 1, Springer-Verlag, Berlin, 1-41.