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Hexanuclear Complex of Platinum(II) with Cleavage Product of Cystamine Dihydrochloride by <i>β</i>-Mercaptoethylamine
The Institute of Catalysis and Inorganic Chemistry Named after Acad. M. F. Nagiyev of the National Academy of Sciences Azerbaijan, Baku, Azerbaijan
The Institute of Catalysis and Inorganic Chemistry Named after Acad. M. F. Nagiyev of the National Academy of Sciences Azerbaijan, Baku, Azerbaijan
The Institute of Catalysis and Inorganic Chemistry Named after Acad. M. F. Nagiyev of the National Academy of Sciences Azerbaijan, Baku, Azerbaijan
The Institute of Catalysis and Inorganic Chemistry Named after Acad. M. F. Nagiyev of the National Academy of Sciences Azerbaijan, Baku, Azerbaijan
- 1 The Institute of Catalysis and Inorganic Chemistry Named after Acad. M. F. Nagiyev of the National Academy of Sciences Azerbaijan, Baku, Azerbaijan
- 2 The Institute of Catalysis and Inorganic Chemistry Named after Acad. M. F. Nagiyev of the National Academy of Sciences Azerbaijan, Baku, Azerbaijan
- 3 The Institute of Catalysis and Inorganic Chemistry Named after Acad. M. F. Nagiyev of the National Academy of Sciences Azerbaijan, Baku, Azerbaijan
- 4 The Institute of Catalysis and Inorganic Chemistry Named after Acad. M. F. Nagiyev of the National Academy of Sciences Azerbaijan, Baku, Azerbaijan
Advances in Chemical Engineering and Science·Volume 06 (2015)·Pages 29–33·Published 30 November 2015·DOI10.4236/aces.2016.61003
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Abstract
Six-nuclear complexes of Platinum(II) with cleavage of a cystamine dihydrochloride by β -mercaptoethylamine with composition [Pt 6 (H 2 NCH 2 CH 2 S) 8 ]Cl 4 ·5H 2 O had been syntesized for the first time. Structure of the complex had been installed together with IKS- and XRD analysis. It has been established that each atom of platinum is surrounded by two atoms of sulfur and nitrogen due to bidentate coordination of a ligand. Only two of the six platinum atoms are on the same plane; other four atoms are in the different crossing planes. Four platinum atoms form adurable metal chelate cycles, which collapse over temperature 260℃. The results of IR spectroscopy confirmed with the RS-analysis.
KeywordsMercaptoamineLigandsPlatinumSix-Nuclear ComplexesSynthesis
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