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Organic Melt Crystallization as a Method for Synthesis of Supramolecular Complexes
Department of Chemistry and Bioengineering, Iwate University, Morioka, Japan
Department of Chemistry and Bioengineering, Iwate University, Morioka, Japan
Department of Chemistry and Bioengineering, Iwate University, Morioka, Japan
- 1 Department of Chemistry and Bioengineering, Iwate University, Morioka, Japan
- 2 Department of Chemistry and Bioengineering, Iwate University, Morioka, Japan
- 3 Department of Chemistry and Bioengineering, Iwate University, Morioka, Japan
Advances in Chemical Engineering and Science·Volume 06 (2016)·Pages 76–81·Published 19 February 2016·DOI10.4236/aces.2016.62009
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Abstract
The most simple method for solventless synthesis of supramolecular complex of CMCR·2BPY·BZP, [CMCR = C -methylcalix[4]resorcinarene, BPY = 4,4'-bipyridine, BZP = benzophenone], is proposed. Although CMCR by itself is high melting point compound (above 300 ° C), CMCR was found to be dissolved in melt mixture of BPY and BZPeven below 120 ° C. In the mixture of the three components, the reaction occurs to form CMCR·2BPY·BZP supramolecular complex.
KeywordsOrganic Melt Crystallization as a Method for Synthesis of Supramolecular Complexes
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