A Novel Design Strategy for Temperature-Responsive IPN Hydrogels Based on a Copolymer of Acrylamide and N-(1,1-Dimethyl-3-Oxobutyl)-Acrylamide — Oak Academic Publishing
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A Novel Design Strategy for Temperature-Responsive IPN Hydrogels Based on a Copolymer of Acrylamide and N-(1,1-Dimethyl-3-Oxobutyl)-Acrylamide
School of Chemistry and Materials Sciences, Guizhou Education University, Guiyang, China
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School of Chemistry and Materials Sciences, Guizhou Education University, Guiyang, China
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School of Chemistry and Materials Sciences, Guizhou Education University, Guiyang, China
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School of Chemistry and Materials Science, Weinan Normal University, Weinan, China
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School of Chemistry and Materials Sciences, Guizhou Education University, Guiyang, China
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School of Chemistry and Materials Science, Weinan Normal University, Weinan, China
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Anshun Engineering Research Centre of Concrete Admixture, Anshun, China
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GuizhouTiejinahengfa New Material Technology Co. Ltd., Anshun, China
1 School of Chemistry and Materials Sciences, Guizhou Education University, Guiyang, China
2 School of Chemistry and Materials Sciences, Guizhou Education University, Guiyang, China
3 School of Chemistry and Materials Sciences, Guizhou Education University, Guiyang, China
4 School of Chemistry and Materials Science, Weinan Normal University, Weinan, China
5 School of Chemistry and Materials Sciences, Guizhou Education University, Guiyang, China
6 School of Chemistry and Materials Science, Weinan Normal University, Weinan, China
7 Anshun Engineering Research Centre of Concrete Admixture, Anshun, China
8 GuizhouTiejinahengfa New Material Technology Co. Ltd., Anshun, China
A methology is described for the synthesis of novel temperature-responsive interpenetrating polymer network (IPN) hydrogels with poly(2-acrylamido- 2-methylpropane sulfonic acid) (PAMPS) as a tightly crosslinked 1st network, temperature-responsive poly(acrylamide-co-N-(1,1-dimethyl-3-oxobutyl)- acrylamide) (P(AM-co-DAAM)) with low cost as a lossely crosslinked 2nd network. The structure and morphology of the IPN hydrogels were characterized by FTIR, TGA and SEM, and the results indicated that PAMPS network introduced P(AM-co-DAAM) hydrogels have large, thermally stable and interconnected porous network. The properties of the IPN hydrogels, which include: swelling capacity, equilibrium swelling/deswelling ratio, temperature- responsive behavior, and the dwelling kinetics as specific temperature, were investigated carefully. Results showed that the obtained IPN hydrogels displayed a controllable equilibrium swelling/deswelling behavior and possessed remarkable thermosensitivity. In addition, the results also indicate that the incorporation of the hydrophobic groups DAAM has a big effect on the LCST of the IPN hydrogels. Consequently, these novel temperature-responsive IPN hydrogels with low cost and slow-releasing performance would be promising for potential applications, such as environmental catalysis, water treatment, and agriculture.
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