Lithium ion battery (LIB) is one of the promising power storage devices in today’s world. Lithium ion battery like other types of electrochemical cell has anodic and cathodic electrode in which lithium ion is intercalated and deinterclated during charging and discharging process respectively. The capacity of lithium ion battery is improved by the development of innovative kinds of electrode. Carbon, metal/semiconductor, metal oxides and metal phosphides/ nitrides/sulfides based nanomaterials improve the capability of LIBs due to their high surface area, low diffusion distance, high electrical and ionic conductivity. Nanostructured materials represent a rapidly growing area in the field of Li-ion batteries because of their substantial advantages in terms of mass transport. In this review anode nanomaterials classified based on type of transition metal/semiconductor such as carbon, silicon, titanium and tin based nanomaterials are discussed. Additionally, different electrochemical reactions, comparative influence of anode materials on LIBs and their applications are widely explained.
KeywordsLithium Ion BatterySemiconductorNanostructureComposite MaterialsTi Based Materials
Chen, J. (2013) Recent Progress in Advanced Materials for Lithium Ion Batteries. Materials, 6, 156-183. https://doi.org/10.3390/ma6010156
Nitta, N., Wu, F., Lee, J.T. and Yushin, G. (2015) Li-Ion Battery Materials: Present and Future. Materials Today, 18, 252-264. https://doi.org/10.1016/j.mattod.2014.10.040
Lahiri, I. and Choi, W. (2013) Carbon Nanostructures in Lithium Ion Batteries: Past, Present, and Future. Critical Reviews in Solid State and Materials Sciences, 38, 128-166. https://doi.org/10.1080/10408436.2012.729765
Wang, G.P., et al. (2008) The Effect of Different Kinds of Nano-Carbon Conductive Additives in Lithium Ion Batteries on the Resistance and Electrochemical Behavior of the LiCoO2 Composite Cathodes. Solid State Ionics, 179, 263-268. https://doi.org/10.1016/j.ssi.2008.01.015
Groot, J. (2012) State-of-Health Estimation of Li-Ion Batteries: Cycle Life Test Methods. Thesis, Chalmers University of Technology, Göteborg, 5.
Pan, X. (2015) Tin Nanoparticles Encapsulated in Hollow TIO2 Spheres as High Performance Anode Materials for Li-Ion Batteries. Thesis, University of Wisconsin-Milwaukee, Milwaukee, 3.
Chen, S. (2014) Novel Nanomaterials for Lithium Ion Batteries and Lithium Sulfur Batteries. Doctoral Dissertation, University of Technology Sydney, Sydney, 10-11.
Zhao, N., Fu, L., Yang, L., Zhang, T., Wang, G., Wu, Y. and van Ree, T. (2008) Nanostructured Anode Materials for Li-Ion Batteries. Pure and Applied Chemistry, 80, 2283-2295. https://doi.org/10.1351/pac200880112283
Pomerantseva, E., Gerasopoulos, K., Chen, X., Rubloff, G. and Ghodssi, R. (2012) Electrochemical Performance of the Nanostructured Biotemplated V2O5 Cathode for Lithium-Ion Batteries. Journal of Power Sources, 206, 282-287. https://doi.org/10.1016/j.jpowsour.2012.01.127
Mauger, A. and Julien, C.M. (2015) Nanoscience Supporting the Research on the Negative Electrodes of Li-Ion Batteries. Nanomaterials, 5, 2279-2301. https://doi.org/10.3390/nano5042279
Lahiri, I. and Wonbong Ch. (2013) Carbon Nanostructures in Lithium Ion Batteries: Past, Present, and Future. Critical Reviews in Solid State and Materials Sciences, 38, 128-166. https://doi.org/10.1080/10408436.2012.729765
Sneha, T., et al. (2015) Carbon Nanotube Based Paper Battery and Lithium Ion Battery. International Journal of Application or Innovation in Engineering & Management (IJAIEM), 4, 179-181.
Li, L., Yang, H., Zhou, D. and Zhou, Y. (2014) Progress in Application of CNTs in Lithium-Ion Batteries. Journal of Nanomaterials, 2014, Article ID: 187891. https://doi.org/10.1155/2014/187891
Xiong, Z., Yun, Y.S. and Jin, H.J. (2013) Applications of Carbon Nanotubes for Lithium Ion Battery Anodes. Materials, 6, 1138-1158. https://doi.org/10.3390/ma6031138
Zhu, J., Duan, R., Zhang, S., Jiang, N., Zhang, Y. and Zhu, J. (2014) The Application of Graphene in Lithium Ion Battery Electrode Materials. SpringerPlus, 3, Article No. 585. https://doi.org/10.1186/2193-1801-3-585
Sui, Z., Wang, C., Yang, Q., Shu, K., Liu, Y., Han, B. and Wallace, G.G. (2015) A Highly Nitrogen-Doped Porous Graphene—An Anode Material for Lithium Ion Batteries. Journal of Materials Chemistry A, 3, 18229-18237. https://doi.org/10.1039/C5TA05759K
Raccichini, R., Varzi, A., Passerini, S. and Scrosati, B. (2015) The Role of Graphene for Electrochemical Energy Storage. Nature Materials, 14, 271-279. https://doi.org/10.1038/nmat4170
Wang, J., Xu, T., Huang, X., Li, H. and Ma, T. (2016) Recent Progress of Silicon Composites as Anode Materials for Secondary Batteries. RSC Advances, 6, 87778-87790. https://doi.org/10.1039/C6RA08971B
Yin, Y., Wan, L. and Guo, Y. (2012) Silicon-Based Nanomaterials for Lithium-Ion Batteries. Chinese Science Bulletin, 57, 4104-4110. https://doi.org/10.1007/s11434-012-5017-2
Ma, D., Cao, Z. and Hu, A. (2014) Si-Based Anode Materials for Li-Ion Batteries: A Mini Review. Nano-Micro Letters, 6, 347-358. https://doi.org/10.1007/s40820-014-0008-2
Chen, C., Agrawal, R. and Wang, C. (2015) High Performance Li4Ti5O12/Si Composite Anodes for Li-Ion Batteries. Nanomaterials, 5, 1469-1480. https://doi.org/10.3390/nano5031469
Li, X.Z., Wang, X.H., Li, S.W. and Qiu, X.P. (2014) A Novel Silicon/Carbon Nanocomposite Anode for High Performance Lithium-Ion Micro-Battery. Journal of Physics: Conference Series, 557, Article ID: 012059. https://doi.org/10.1088/1742-6596/557/1/012059
Wang, G. X., et al. (2004) Nanostructured Si-C Composite Anodes for Lithium-Ion Batteries. Electrochemistry Communications, 6, 689-692. https://doi.org/10.1016/j.elecom.2004.05.010
Su, X., Wu, Q., Li, J., Xiao, X., Lott, A., Lu, W., Sheldon, B.W. and Wu, J. (2014) Silicon-Based Nanomaterials for Lithium-Ion Batteries: A Review. Advanced Energy Materials, 4, Article ID: 1300882. https://doi.org/10.1002/aenm.201300882
Chen, Y., Zhang, X., Tian, Y. and Zhao, X. (2014) Synthesis and Characterization of Silicon Nanoparticles Inserted into Graphene Sheets as High Performance Anode Material for Lithium Ion Batteries. Journal of Nanomaterials, 2014, Article ID: 734751. https://doi.org/10.1155/2014/734751
Nitta, N. and Yushin, G. (2014) High-Capacity Anode Materials for Lithium-Ion Batteries: Choice of Elements and Structures for Active Particles. Particle & Particle Systems Characterization, 31, 317-336. https://doi.org/10.1002/ppsc.201300231
Kamali, A.R. and Fray, D.J. (2011) Tin-Based Materials as Advanced Anode Materials for Lithium Ion Batteries: A Review. Reviews on Advanced Materials Science, 27, 14-24.
Dhanabalan, A., Li, X., Agrawal, R., Chen, C. and Wang, C. (2013) Fabrication and Characterization of SnO2/Graphene Composites as High Capacity Anodes for Li-Ion Batteries. Nanomaterials, 3, 606-614. https://doi.org/10.3390/nano3040606
Zhao, Q., Ma, L., Zhang, Q., Wang, C. and Xu, X. (2015) SnO2-Based Nanomaterials: Synthesis and Application in Lithium-Ion Batteries and Supercapacitors. Journal of Nanomaterials, 2015, Article ID: 850147. https://doi.org/10.1155/2015/850147
Wu, H.B., Chen, J.S., Hng, H.H. and Lou, X.W. (2012) Nanostructured Metal Oxide-Based Materials as Advanced Anodes for Lithium-Ion Batteries. Nanoscale, 4, 2526-2542. https://doi.org/10.1039/c2nr11966h
Goriparti, S., Miele, E., Angelis, D.F., Fabrizo, D.E., Zaccaria, P.R. and Capliga, C. (2014) Review on Recent Progress of Nanostructured Anode Materials for Li-Ion Batteries. Journal of Power Sources, 257, 421-443. https://doi.org/10.1016/j.jpowsour.2013.11.103
Han, X., Ouyang, M., Lu, L. and Li, J. (2014) Cycle Life of Commercial Lithium-Ion Batteries with Lithium Titanium Oxide Anodes in Electric Vehicles. Energies, 7, 4895-4909. https://doi.org/10.3390/en7084895
Han, C., Yang, D., Yang, Y., Jiang, B., He, Y., Wang, M., Song, A., He, Y, Li, B. and Lin, Z. (2015) Hollow Titanium Dioxide Spheres as Anode Material for Lithium Ion Battery with Largely Improved Rate Stability and Cycle Performance by Suppressing the Formation of Solid Electrolyte Interface Layer. Journal of Material Chemistry, 3, 13340-13349. https://doi.org/10.1039/C5TA02070K