Analysis of Heavy Metals in Human Hair Using Atomic Absorption Spectrometry (AAS)
- 1 Department of Chemistry and Centre for Agrochemical Technology, University of Agriculture, Makurdi, Nigeria
- 2 Department of Chemistry and Centre for Agrochemical Technology, University of Agriculture, Makurdi, Nigeria
- 3 Department of Chemistry and Centre for Agrochemical Technology, University of Agriculture, Makurdi, Nigeria
Abstract
Hair samples of individual were analysed for heavy metals (Cd, Cr, Pb and As) across gender and various occupational distributions by Atomic Absorption Spectrophotometric technique (AAS). The results of replicate analysis shows the following mean concentrations (mg/kg): Cd = 27.8 ± 8.0, Cr = 2.70 ± 0.7, Pb = 73.8 ± 42.3 and As = 222 ± 34.1. The coefficients of variation for the total distribution is; Cd = 28%, Cr = 26%, Pb = 57% and As = 15%. The distribution of the metals follows the series in decreasing order of As > Pb > Cd > Cr, while their coefficients of variation is in the order of Pb > Cd >Cr > As. The result shows the presence of all the metals in relatively large amounts with As having the highest concentration between the two genders. The difference between male and female concentration could be due to individual differences in exposure to heavy metal load as a result of habitual or environmental factors.
- S. J. Steindel and P. J. Howanitz, “Uncertainty of Hair Analysis for Trace Metals,” Journal of Amercan Medical Association, Vol. 285, No. 1, 2001, pp. 83-85. doi:10.1001/jama.285.1.83
- P. C. D. Lemos, H. M. Dung, Vu C. Dong, Sy, N Thi and N. M. Sinh, “Analysis of Angolan Human Hair Samples by the Ko- NAA Technique on the Dalat Research Reactor: The Study and Application on the Ko-Standardization Method of Neutron Activation Analysis at Dalat Nuclear Reasrch Institute(NRI), Vietnam,” Proceedings of the 5th Asian Workshop on Utilization Reserch Reactors, Jakarta, 2005.
- R. V. Bharathi, A. J. Suresh, M. Thirumal and B. Ku-mudhaveni, “Analysis of Heavy Metal and Inorganic Element Content in Barringtonia acutangula Leaf,” Ethno-botanical Leaflets, Vol. 14, 2010, pp. 856-863.
- J. O. Duruibe, M. O. C. Ogwuegbu and J. N. Egwurugwu, “Heavy Metal Pollution and Human Biotoxic Effects,” International Journal of Physical Sciences, Vol. 2, No. 5, 2007, pp. 112-118.
- D. McCluggage, “Heavy Metal Poisoning,” NCS Magazine, 1991. www.cocktatiels.org/articles/Diseases/Metals.html.
- P. Chattopadhyay, H. Joshi and K. Samaddar, “Hair Cadmium Level of Smoker and Non-Smoker Human Volunteers in and around Calcutta City,” Bulletin of Environmental Contamination and Toxicology, Vol. 45, No. 2, 1990, pp. 177-180. doi:10.1007/BF01700180
- D. J. Ferner, “Toxicity, Heavy Metals,” eMed.J. Vol. 2, No. 5, 2001, p. 1.
- M. O. C. Og-wuegbu and W. Muhanga, “Investigation of Lead Concentration in the Blood of People in the Copperbelt Province of Zambia,” Journal of Environment, Vol. 1, 2005, pp. 66-75.
- A. Sukumar and R. Subramanian, “Elements in Hair and Nails of Urban Residents of New Delhi, CHD Hypertensive and Diabetic Cases,” Biological Trace Element Research, Vol. 34, No. 1, 1992, pp. 89-97. doi:10.1007/BF02783901
- J. R. Holum, “Elements of General and Biological Chemistry,” 6th Edition, John Wiley and Sons, New York, 1983.
- Institute of Environmental Conservation and Research (INECAR), “Position Paper against Mining in Rapu-Rapu,” NECAR, Ateneo de Naga University, 2000. www.adnu.edu.ph/institutes/Inecar/pospaper1.asp
- G. Dodd, “Heavy Metal Poising and Hair Analysis,” 2010. http://holisticvetpetcare.com/pdf/HeavyMetalpoisonhair Analysis-2.pdf
- J. Md Khudzari, H. Wagiran, Md. I. Hossain, N. Ibrahim and M. A. Agam, “Heavy Metals Mn, Fe, Ni, Cu and Zn in Human Hair Sample Using Energy Dispersion X-Ray Fluorescence Analysis,” International Journal of Physical Science, Vol. 6, No. 8, 2011, pp. 2090-2094.