Electrochemical Synthesis of Three-Dimensional Polyaniline Network on 3-Aminobenzenesulfonic Acid Functionalized Glassy Carbon Electrode and Its Application — Oak Academic Publishing
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Electrochemical Synthesis of Three-Dimensional Polyaniline Network on 3-Aminobenzenesulfonic Acid Functionalized Glassy Carbon Electrode and Its Application
The electrochemical synthesis of three-dimensional (3D) polyaniline (PAN) network structure on 3-aminobenzenesulfonic acid (ABSA) functionalized glassy carbon electrode (GCE) and its electro-catalytic oxidation towards ascorbic acid (AA) had been studied. ABSA was first covalently grafted on GCE surface via the direct electrochemical oxidation of ABSA on GCE, which was followed by the electrochemical polymerization of aniline on the ABSA functionalized GCE. Then PAN-ABSA composite film modified GCE (PAN-ABSA/GCE) was obtained. Scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), electrochemical impedance spectroscopy (EIS) and electrochemical techniques had been employed to characterize the obtained electrodes. Due to the effective doping of ABSA in PAN, the redox electro-activity of PAN had been extended to neutral and even the basic media, thus, the PAN-ABSA composite film modified GCE could be used for electro-catalytic oxidation of AA in 0.1 M phosphate buffer solution (PBS, pH 6.8). At PAN-ABSA/GCE the oxidation over-potential of AA shifted from 0.39 V at GCE to 0.17 V with a greatly enhanced current response. The electro-catalytic oxidation peak current of AA increased linearly with the increasing AA concentration over the range of 5.00 × 10-4-1.65 × 10-2 M with a correlation coefficient of 0.9973. The detection limit (S/N = 3) for AA was 1.16 × 10-6 M. Chronoamperometry had also been employed to investigate the electro-catalytic oxidation of AA at PAN-ABSA/GCE. The modified electrode had been used for detecting AA in real samples with satisfactory results.
M. S. Cho, S. Y. Park, J. Y. Hwang and H. J. Choi, “Synthesis and Electrical Properties of Polymer Composites with Polyaniline Nanoparticles,” Materials Science and Engineering C, Vol. 24, No. 1-2, January 2004, pp. 15-18.
D. Zhang and Y. Wang, “Synthesis and Applications of One-Dimensional Nano-Structured Polyaniline: An Overview,” Materials Science and Engineering B, Vol. 134, No. 1, September 2006, pp. 9-19.
M. Li, Y. Gou, Y. Wei, A. G. MacDiarmid and P. I. Lelkes, “Electrospinning Polyaniline-Contained Gelatin Nanofibers for Tissue Engineering Applications,” Biomaterials, Vol. 27, No. 13, May 2006, pp. 2705-2715.
D. Cheng, S. Ng and H. S. O. Chan, “Morphology of Polyaniline Nanoparticles Synthesized in Triblock Copolymers Micelles,” Thin Solid Films, Vol. 477, No. 1-2, April 2005, pp. 19-23.
Y. G. Wang, H. Q. Li and Y. Y. Xia, “Ordered Whiskerlike Polyaniline Grown on the Surface of Mesoporous Carbon and Its Electrochemical Capacitance Performance,” Advanced Material, Vol. 18, No. 19, September 2006, pp. 2619-2623.
M. Akhtar, H. A. Weakliem, R. M. Paiste and K. Gaughan, “Polyaniline Thin Film Electrochromic Devices,” Synthetic Metals, Vol. 26, No. 3, November 1988, pp. 203-208.
D. E. Tallman, G. Spinks, A. Dominis and G. G. Wallace, “Electroactive Conducting Polymers for Corrosion Control Part 1. General Introduction and a Review of Non-ferrous Metals,” Journal of Solid State Electrochemistry, Vol. 6, No. 2, February 2002. pp. 73-84.
T. Tonosaki, T. Oho, K. Isomura and K. Ogura, “Effect of the Protonation Level of Poly(o-Phenylenediamine) (PoPD) on the AC Impedance of Humidity-Sensitive PoPD/Poly(Vinyl Alcohol) Composite Film,” Journal of Electroanalytical Chemistry, Vol. 520, No. 1-2, February 2002, pp. 89-93.
J. Yano, K. Terayama and S. Yamasaki, “Electrochemically Prepared Poly(o-Phenylenediamine)-Prussian Blue Composite Film for a Three-Colour Expressible ECD Material,” Journal of Materials Science, Vol. 31, No. 18, January 1996, pp. 4785-4792.
J. Yano and S. Yamasaki, “Three-Color Electrochromism of an Aramid Film Containing Polyaniline and Poly(o- Phenylenediamine),” Synthetic Metals, Vol. 102, No. 1-3, June 1999, p. 1157.
X. H. Cai, K. Kalcher, C. Neuhold and B. Ogorevc, “An Improved Voltammetric Method for the Determination of Trace Amounts of Uric Acid with Electrochemically Pretreated Carbon Paste Electrodes,” Talanta, Vol. 41, No. 3, March 1994, pp. 407-413.
T. Nagaoka and T. Yoshino, “Surface Properties of Electrochemically Pretreated Glassy Carbon,” Analytical Che- mistry, Vol. 58, No. 6, May 1986, pp. 1037-1042.
J. Yue, Z. H. Wang, K. R. Cromack, A. J. Epstein and A. G. MacDiarmid, “Effect of Sulfonic Acid Group on Polyaniline Backbone,” Journal of the American Chemical Society, Vol. 113, No. 7, March 1991, pp. 2665-2671.
X. L. Wei, Y. Z. Wang, S. M. Long, C. Bobeczko and A. J. Epstein, “Synthesis and Physical Properties of Highly Sulfonated Polyaniline,” Journal of the American Chemical Society, Vol. 118, No. 11, March 1996, pp. 2545- 2555.
L. V. Lukachova, E. A. Shkerin, E. A. Puganova, E. E. Karyakina, S. G. Kiseleva, A. V. Orlov, G. P. Karpacheva and A. A. Karyakin, “Electroactivity of Chemically Synthesized Polyaniline in Neutral and Alkaline Aqueous Solutions: Role of Self-Doping and External Doping,” Journal of Electroanalytical Chemistry, Vol. 544, No. 1, March 2003, pp. 59-63.
L. Zhang, “The Electrocatalytic Oxidation of Ascorbic Acid on Polyaniline Film Synthesized in the Presence of β-Naphthalenesulfonic Acid,” Electrochimica Acta, Vol. 52, No. 24, August 2007, pp. 6969-6973.
C. D. Batich, H. A. Laitinen and H. C. Zhou, “Chromatic Changes in Polyaniline Films,” Journal of The Electrochemical Society, Vol. 137, No. 3, March 1990, pp. 883-885.
M. M. Ayad and A. Z. Eman, “Doping of Polyaniline Films with Organic Sulfonic Acids in Aqueous Media and the Effect of Water on These Doped Films,” European Polymer Journal, Vol. 44, No. 11, November 2008, pp. 3741-3747.
A. A. Karyakin, A. K. Strakhova and A. K. Yatsimirsky, “Self-Doped Polyanilines Electrochemically Active in Neutral and Basic Aqueous Solutions: Electropolymerization of Substituted Anilines,” Journal of Electroanalytical Chemistry, Vol. 371, No. 1-2, June 1994, pp. 259- 265.
C. Sanchís, H. J. Salavagione and E. Morallón, “Ferrocenium Strong Adsorption on Sulfonated Polyaniline Modified Electrodes,” Journal of Electroanalytical Chemistry, Vol. 618, No. 1-2, July 2008, pp. 37-73.
H. Tang, A. Kitani, T. Yamashita and S. Ito, “Highly Sulfonated Polyaniline Electrochemically Synthesized by Polymerizing Aniline-2,5-Disulfonic Acid and Copolymerizing It with Aniline,” Synthetic Metals, Vol. 96, No. 1, July 1998, pp. 43-48.
Y. Wang and W. Knoll, “In situ Electrochemical and Surface Plasmon Resonance (SPR) Studies of Aniline- Carboxylated Aniline Copolymers,” Analytica Chimica Acta, Vol. 558, No. 1-2, February 2006, pp. 150-157.
M. Liu, M. Ye, Q. Yang, Y. Zhang, Q. Xie and S. Yao, “A New Method for Characterizing the Growth and Properties of Polyaniline and Poly (Aniline-co-o-Aminophenol) Films with the Combination of EQCM and in situ FTIR Spectroelectrochemisty,” Electrochimica Acta, Vol. 52, No. 1, October 2006, pp. 342-352.
J. F. Evans, T. Kuwana, M. T. Henne and C. P. Royer, “Electrocatalysis of Solution Species Using Modified Electrodes,” Journal of Electroanalytical Chemistry, Vol. 80, No. 2, July 1977, pp. 409-416.
G. N. Kamau, W. S. Willis and J. F. Rusling, “Electrochemical and Electron Spectroscopic Studies of Highly Polished Glassy Carbon Electrodes,” Analytical Chemistry, Vol. 57, No. 2, 1985, pp. 545-551.
B. Barbier, J. Pinson, G. Desarmot and M. Sanchez, “Electrochemical Bonding of Amines to Carbon Fiber Surface toward Improved Carbon-Epoxy Composites,” Journal of the Electrochemical Society, Vol. 137, No. 6, June 1990, pp. 1757-1764.
R. S. Deinhammar, M. Ho, J. W. Anderegg and M. D. Porter, “Electrochemical Oxidation of Amine-Containing Compounds: A Route to the Surface Modification of Glassy Carbon Electrodes,” Langmuir, Vol. 10, No. 4, February 1994, pp. 1306-1313.
R. E. Dickerson, T. Takano, D. Eisenberg, O. B. Kallai, L. Samson, A. Cooper and E. Margoliash, “Ferricytochrome c I. General Features of the Horse and Bonito Proteins at 2.8 A Resolution,” The Journal of Biological Chemistry, Vol. 246, No. 5, March 1971, pp. 1511-1535.
H. O. Finklea, D. A. Snider, J. Fedyk, E. Sabatani, Y. Gafni and I. Rubinstein, “Characterization of Octadecanethiol- Coated Gold Electrodes as Microarray Electrodes by Cyclic Voltammetry and AC Impedance Spectroscopy,” Langmuir, Vol. 9, No. 12, September 1993, pp. 3660- 3667.
J. J. Gooding, R. Wibowo, J. Q. Liu, W. R. Yang, D. Losic, S. Orbons, F. J. Mearns, J. G. Shapter and D. B. Hibbert, “Protein Electrochemistry Using Aligned Carbon Nanotube Arrays,” Journal of the American Chemical Society, Vol. 125, No. 30, July 2003, pp. 9006-9007.
M. Wang, F. Zhao, Y. Liu and S. Dong, “Direct Electrochemistry of Microperoxidase at Pt Microelectrodes Modified with Carbon Nanotubes,” Biosensors and Bioelectronics, Vol. 21, No. 1, July 2005, pp. 259-166.
M. Lapkowski, “Electrochemical Synthesis of Linear Polyaniline in Aqueous Solutions,” Synthetic Metals, Vol. 35, No. 1-2, February-March 1990, pp. 169-182.
A. J. Bard and L. R. Faulkner, “Electrochemical Methods, Fundamentals and Applications,” Wiley Interscience, New York, 1980, p. 143.
Z. Galus, “Fundamentals of Electrochemical Analysis,” Ellis Horwood, New York, 1976, p. 313.