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HPLC Analysis of Monofluoro-S-Triazine Dye during the Dyeing Process
Department of Textiles, Faculty of Natural Sciences and Engineering, University of Ljubljana, Ljubljana, Slovenia
Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ljubljana, Slovenia
Department of Textiles, Faculty of Natural Sciences and Engineering, University of Ljubljana, Ljubljana, Slovenia
- 1 Department of Textiles, Faculty of Natural Sciences and Engineering, University of Ljubljana, Ljubljana, Slovenia
- 2 Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ljubljana, Slovenia
- 3 Department of Textiles, Faculty of Natural Sciences and Engineering, University of Ljubljana, Ljubljana, Slovenia
American Journal of Analytical Chemistry·Volume 05 (2014)·Pages 215–224·Published 6 March 2014·DOI10.4236/ajac.2014.54027
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Abstract
In the research, the HPLC technique was applied in order to monitor the hydrolysis and dye-fibre bond-forming during the dyeing process. The results show that using a proper execution of calibration curves of the active and hydrolyzed form of the dye and defined equations, HPLC technique enable determining the exact amount of both dye forms anytime during dyeing. Dyeing process was performed in dyeing machine with use of combination of both alkalis—Na2CO3 and NaOH—and with use of one alkali—Na2CO3. It was established that NaOH causes additional hydrolysis of the dye and that the use of Na2CO3 is more appropriate for Novacron Scarlet F-3G dye. The temperature of adsorption has no influence on dye fixation; an amount of fixed dye on fibre is up to 83.0%.
KeywordsMonofluoro-S-Triazine DyeHPLC AnalysisAdsorptionFixationHydrolysis
- Cibacron, L.S. Technical Documentation. Ciba.
- Drimaren, H.F. Technical Documentation. Clariant.
- Bezactiv. Technical Documentation. Bezema.
- Procion Fast H-EXL and Remazol Ultra, R.G.B. Technical Documentation. DyStar.
- Cibacron, S. Technical Documentation. Ciba.
- Pavkov, N., Vrhunc, V. and Gorenšek, M. (2005) Zamenjava Monofunkcionalnih z Bifunkcionalnimi Reaktivnimi Barvili = Substitution of Monofunctional Reactive Dyes with New Bifunctional Reactive Dyes. Tekstilec, 48, 245-251.
- Technical Documentation, Ciba Coagulant, Flocculants, Ciba.
- Motomura, H. and Morita, S. (1979) Diffusion with Simultaneous Reaction of Reactive Dyes in Cellulose: II. Effect of Hydrolysis. Journal of Applied Polymer Science, 24, 1747-1757. http://dx.doi.org/10.1002/app.1979.070240714
- Taylor, J.A., Renfrew A.H.M. and Lovis, J.N. (1991) Reactive Dye for Cellulose. The Reaction of Alkoxychlorotriazinyl Dyes with Hydroxide Ion. Journal of Society of Dyers and Colorists, 107, 455-456. http://dx.doi.org/10.1111/j.1478-4408.1991.tb01299.x
- Smith, C.B. and Tha-kore, K.A. (1991) The Effects of Ultrasound on Fibre Reactive Dye Hydrolysis. Textile Chemist and Colorist, 23, 23-25.
- Wallace, M.L., Beck, K.R. and Smith, C.B. (2000) On-Line Monitoring of Reactive Batch Dyeing Exhaustion and Hydrolysis by FIA-HPLC. Textile Chemists and Colorist and American Dyestuff Reporter, 32, 39-40.
- Zotou, A., Eleftheriadis, I., Heli, M. and Pegiadou, S. (2002) Ion-Pair High Performance Liquid Chromatographic Study of the Hydrolysis Behaviour of Reactive Fluorotriazinic Dyes. Dyes and Pigments, 53, 267-275. http://dx.doi.org/10.1016/S0143-7208(02)00019-0
- Aspland, J.R. and Johnson, A. (1965) Alkaline Hydrolysis of Chloro-N-Heterocyclic Reactive Dyes Containing Ionisable Amino Groups-I. Journal of Society of Dyers and Colorists, 81, 425-429. http://dx.doi.org/10.1111/j.1478-4408.1965.tb02614.x
- Johnston, J.E. and Rattee, I.D. (1973) Further Studies of the Acid-Catalysed Hydrolysis of Type 3 Dye-Fibre Bonds between Cellulose and Triazinyl Reactive Dyes. Journal of Society of Dyers and Colorists, 89, 77-94.
- Grancaric, A.M., Tarbuk, A. and Pusic, T. (2005) Electrokinetic Properties of Textile Fabrics. Coloration Technology, 121, 221-226. http://dx.doi.org/10.1111/j.1478-4408.2005.tb00277.x