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Crystal Structure of ZnCl<sub>3</sub> (Methyl-(2-Pyridin-2-yl-Ethyl)-Ammonium)
Université de Carthage, Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Zarzouna, Tunisie
Centre Diffractométrie Henri Longchambon, Université Claude Bernard Lyon 1, Villeurbanne, France
Université de Carthage, Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Zarzouna, Tunisie
- 1 Université de Carthage, Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Zarzouna, Tunisie
- 2 Centre Diffractométrie Henri Longchambon, Université Claude Bernard Lyon 1, Villeurbanne, France
- 3 Université de Carthage, Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Zarzouna, Tunisie
American Journal of Analytical Chemistry·Volume 06 (2015)·Pages 189–195·Published 29 January 2015·DOI10.4236/ajac.2015.63017
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Abstract
A new Zn(II) complex with the monodentate ligand methyl-(2-pyridin-2-yl-ethyl)-ammonium, ZnCl 3 C 8 H 13 N 2 , has been prepared and characterized by single crystal X-ray diffraction. The Zn(II) ion is tetracoordinated by one nitrogen atom of organic ligand and three chlorine ligands. In the atomic arrangement, the ZnNCl 3 tetrahedra form corrugated chains extending along the b -axis. The organic entities are located between these chains through N-H···Cl, C-H···Cl and C-H···N hydrogen bonds to form layers parallel to (b, c) plan. Among these hydrogen bonds two are bifurcated.
KeywordsX-Ray DiffractionCoordination CompoundZinc Complex
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