Hydrothermal Carbonization of Nonylphenol Ethoxylates Waste Liquid for Energy Source Generation
- 1 College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, China
- 2 College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, China
- 3 College of Environmental Science and Engineering, Donghua University, Shanghai, China
- 4 College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, China
Abstract
Nonylphenol polyethoxylates (NPEOs) are widely used as nonionic surfactants in many industry fields. High concentration NPEOs waste water is produced in some production processes. It is often treated to realize reduction by distillation. Therefore, NPEOs waste liquid with higher concentration is produced and it is difficult to be treated by traditional water treatment process. In this study, hydrothermal carbonization process was used to convert NPEOs waste liquid to carbonaceous product (hydrochar) with sulfuric acid as additive in 24 h at 200°C. The hydrochar was characterized by scanning electron microscope, Fourier-transform infrared spectrometer and thermogravimetric analysis. The element composition and the high heat value of the hydrochar were similar to lignite, showing that it could be used as an alternative fuel.
- Soares, A., Guieysse, B., Jefferson, B., Cartmell, E. and Lester, J.N. (2008) Nonylphenol in the Environment: A Critical Review on Occurrence, Fate, Toxicity and Treatment in Wastewaters. Environment International, 34, 1033-1049. http://dx.doi.org/10.1016/j.envint.2008.01.004
- Ying, G.G. (2006) Fate, Behavior and Effects of Surfactants and Their Degradation Products in the Environment. Environment International, 32, 417-431. http://dx.doi.org/10.1016/j.envint.2005.07.004
- Sharma, V.K., Anquandah, G.A., Yngard, R., et al. (2009) Nonylphenol, Octylphenol, and Bisphenol-A in the Aquatic Environment: A Review on Occurrence, Fate, and Treatment. Journal of Environmental Science and Health, Part A: Toxic/Hazardous Substances and Environmental Engineering, 44, 423-442. http://dx.doi.org/10.1080/10934520902719704
- Lu, J., Jin, Q., He, Y.L. and Wu, J. (2007) Biodegradation of Nonylphenol Polyethoxylates under Fe(III)-Reducing Conditions. Chemosphere, 69, 1047-1054. http://dx.doi.org/10.1016/j.chemosphere.2007.04.035
- Karci, A., Arslan-Alaton, I., Bekbolet, M., Ozhan, G. and Alpertunga, B. (2014) H2O2/UV-C and Photo-Fenton Treatment of a Nonylphenol Polyethoxylate in Synthetic Freshwater: Follow-Up of Degradation Products, Acute Toxicity and Genotoxicity. Chemical Engineering Journal, 241, 43-51. http://dx.doi.org/10.1016/j.cej.2013.12.022
- Chen, L., Zhou, H.Y., Liu, L and Deng, Y.D. (2007) Mechanism Study on UV-Induced Photodegradation of Nonylphenol Ethoxylates by Intermediate Products Analysis. Chinese Chemical Letters, 18, 473-475. http://dx.doi.org/10.1016/j.cclet.2007.02.004
- Liu, G.M., Zheng, S.R., Yin, D.Q., et al. (2006) Adsorption of Aqueous Alkylphenol Ethoxylate Surfactants by Mesoporous Carbon CMK-3. Journal of Colloid and Interface Science, 302, 47-53. http://dx.doi.org/10.1016/j.jcis.2006.06.006
- Mumme, J., Eckervogt, L., Pielert, J., et al. (2011) Hydrothermal Carbonization of Anaerobically Digested Maize Silage. Bioresource Technology, 102, 9255-9260. http://dx.doi.org/10.1016/j.biortech.2011.06.099
- Funke, A. and Ziegler, F. (2010) Hydrothermal Carbonization of Biomass: A Summary and Discussion of Chemical Mechanisms for Process Engineering. Biofuels Bioproducts & Biorefining, 4, 160-177. http://dx.doi.org/10.1002/bbb.198
- Libra, J.A., Ro, K.S., Kammann, C., et al. (2010) Hydrothermal Carbonization of Biomass Residuals: A Comparative Review of the Chemistry, Processes and Applications of Wet and Dry Pyrolysis. Biofuels, 2, 71-106. http://dx.doi.org/10.4155/bfs.10.81