Chitosan—The Application of a Natural Polymer against Iron Hydroxide Deposition
- 1 Leibniz-Institut für Polymerforschung Dresden e.V., Dresden, Germany
- 2 Leibniz-Institut für Polymerforschung Dresden e.V., Dresden, Germany
- 3 Department of Organic Chemistry, Faculty of Science, Charles University in Prague, Prague, Czech Republic
- 4 Leibniz-Institut für Polymerforschung Dresden e.V., Dresden, Germany
- 5 Leibniz-Institut für Polymerforschung Dresden e.V., Dresden, Germany
Abstract
As a consequence of mining, heavy metal ions can be exposed to the environment hence contaminate ground water and surface water amongst others. The natural polymer chitosan was proved to be an excellent adsorber material for the effective removal of iron and sulfate ions in batch as well as in column experiments. The adsorption behavior of iron ions, as well as sulfate ions was investigated by utilizing chitosan flakes as a natural adsorbent. The removal was studied using adsorbance measurements, SEM and SEM-EDX. The adsorption capacity of chitosan was determined at different times. The received adsorption capacities for iron ions were very promising with a maximum adsorption capacity of 85 mg/g and a rate of separation of 100%. The maximum adsorption capacity obtained for sulfate ions was 188.8 mg/g and a rate of 80%.
- Wiegleb, G., Broring, U., Mrzljak, J. and Schulz, F. (2000) Nature Conservation in Post-Mining Landscapes. Physika-Verlag, Heidelberg
- Johnston, D. (2008) Abandoned Mines and the Water Environment. Science project SC030136-41
- Landtag Brandenburg, LUGV, Veranderte Wasserqualitat durch Braunkohletagebaue 2012.
- Dold, B. (2014) Evolution of Acid Mine Drainage Formation in Sulphidic Mine Tailings. Minerals, 4, 621-641. http://dx.doi.org/10.3390/min4030621
- Cummings, D.E., March, A.W., Bostick, B., Spring, S., Caccavo F., Fendorf, S. and Rosenzweig, R.F. (2000) Evidence for Microbial Fe(III) Reduction in Anoxic, Mining-Impacted Lake Sediments (Lake Coeur d’Alene, Idaho). Applied and Environmental Microbiology, 66, 154-162. http://dx.doi.org/10.1128/AEM.66.1.154-162.2000
- Pikaar, I., Sharma, K.R., Hu, S., Gernjak, W., Keller, J. and Yuan, Z. (2014) Reducing Sewer Corrosion through Integrated Urban Management. Science, 345, 812-815. http://dx.doi.org/10.1126/science.1251418
- Genest, S., Petzold, G. and Schwarz, S. (2015) Removal of Micro-Stickies from Model Wastewaters of the Paper Industry by Amphiphilic Starch Derivatives. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 484, 231-241. http://dx.doi.org/10.1016/j.colsurfa.2015.08.002
- Bratskaya, S., Genest, S., Petzold-Welcke, K., Heinze, T. and Schwarz, S. (2014) Flocculation Efficiency of Novel Amphiphilic Starch Derivatives: A Comparative Study. Macromolecular Materials and Engineering, 299, 722-728. http://dx.doi.org/10.1002/mame.201300277
- Schwarz, S. and Petzold, G. (2014) Polyelectrolyte Complexes in Flocculation Applications. Advances in Polymer Science, 256, 25-65.
- Rojas, R., Schwarz, S., Heinrich, G., Petzold, G., Schütze, S. and Bohrisch, J. (2010) Flocculation Efficiency of Novel Amphiphilic Starch Derivatives: A Comparative Study. Carbohydrates Polymers, 81, 317-322. http://dx.doi.org/10.1016/j.carbpol.2010.02.010
- Bratskaya, S., Schwarz, S., Petzold, S., Liebert, T. and Heinze, T. (2006) Cationic Starches of High Degree of Functionalization: 12. Modification of Cellulose Fibers toward High Filler Technology in Papermaking. Industrial & Engineering Chemistry Research, 45, 7374-7379. http://dx.doi.org/10.1021/ie060135z
- Schwarz, S. and Petzold, G. (2006) Polyelectrolyte Interactions with Inorganic Particles. In: Somasundaran, P., Ed., Encyclopedia of Surface and Colloid Science, Vol. 6, CRC Press, Boca Raton, 4735-4754.