As a thin film solar cell absorber material, antimony selenide (Sb 2 Se 3 ) has become a potential candidate recently because of its unique optical and electrical properties and easy fabrication method. X-ray photoelectron spectroscopy (XPS) was used to determine the stoichiometry and composition of electroless Sb 2 Se 3 thin films using depth profile studies. The surface layers were analyzed nearly stoichiometric. But the abundant amount of antimony makes the inner layer electrically more conductive.
Wang, W., Cao, Z., Wu, L., Chen, G., Ao, J., Luo, J. and Zhang, Y. (2022) Interface Etching Leads to the Inversion of the Conduction Band Offset between the CdS/Sb2Se3 Heterojunction and High-Efficient Sb2Se3 Solar Cells. ACS Applied Energy Materials, 5, 2531-2541. https://doi.org/10.1021/acsaem.1c04078
Liang, G., Chen, M., Ishaq, M., Li, X., Tang, R., Zheng, Z., Su, Z., Fan, P., Zhang, X. and Chen, S. (2022) Crystal Growth Promotion and Defects Healing Enable Minimum Open-Circuit Voltage Deficit in Antimony Selenide Solar Cells. Advanced Science, 9, Article ID: 2105142. https://doi.org/10.1002/advs.202105142
Wang, W., Wang, X., Chen, G., Yao, L., Huang, X., Chen, T., Zhu, C., Chen, S., Huang, Z. and Zhang, Y. (2019) Over 6% Certified Sb2(S, Se)3 Solar Cells Fabricated Via in situ Hydrothermal Growth and Postselenization. Advanced Electronic Materials, 5, Article ID: 1800683. https://doi.org/10.1002/aelm.201800683
Chen, S., Zheng, Z., Cathelinaud, M., Ma, H., Qiao, X., Su, Z., Fan, P., Liang, G., Fan, X. and Zhang, X. (2019) Magnetron Sputtered Sb2Se3-Based Thin Films towards High Performance Quasi-Homojunction Thin Film Solar Cells. Solar Energy Materials and Solar Cells, 203, Article ID: 110154. https://doi.org/10.1016/j.solmat.2019.110154
Kaelin, M., Rudmann, D. and Tiwari, A.N. (2004) Low Cost Processing of CIGS Thin Film Solar Cells. Solar Energy, 77, 749-756. https://doi.org/10.1016/j.solener.2004.08.015
Islam, M.M., Ishizuka, S., Yamada, A., Sakurai, K., Niki, S., Sakurai, T. and Akimoto, K. (2009) CIGS Solar Cell with MBE-Grown ZnS Buffer Layer. Solar Energy Materials and Solar Cells, 93, 970-972. https://doi.org/10.1016/j.solmat.2008.11.047
Guillermo, H., Rimmaudo, I., Riech, I., Abelenda, A. and López-Sánchez, A. (2022) A Simple Model for Studying the Effects of Activation Treatment on the Defects Structure of Cadmium Telluride Solar Cells. Optik, 262, Article ID: 169296. https://doi.org/10.1016/j.ijleo.2022.169296
Green, M.A., Dunlop, E., Hohl-Ebinger, J., Yoshita, M., Kopidakis, N. and Hao, X. (2021) Solar Cell Efficiency Tables (Version 57). Progress in Photovoltaics, 29, 3-15. https://doi.org/10.1002/pip.3371
Bouich, A., Marí-Guaita, J., Sahraoui, B., Palacios, P. and Marí, B. (2022) Tetrabutylammonium (TBA)-Doped Methylammonium Lead Iodide: High Quality and Stable Perovskite Thin Films. Frontiers in Energy Research, 10, Article ID: 840817. https://doi.org/10.3389/fenrg.2022.840817
Xue, D.J., Yang, B., Yuan, Z.K., Wang, G., Liu, X., Zhou, Y., Hu, L., Pan, D., Chen, S. and Tang, J. (2015) CuSbSe2 as a Potential Photovoltaic Absorber Material: Studies from Theory to Experiment. Advanced Energy Materials, 5, Article ID: 1501203. https://doi.org/10.1002/aenm.201501203
Chantana, J., Uegaki, H. and Minemoto, T. (2017) Influence of Na in Cu2SnS3 Film on Its Physical Properties and Photovoltaic Performances. Thin Solid Films, 636, 431-437. https://doi.org/10.1016/j.tsf.2017.06.044
Hartnauer, S., Korbel, S., Marques, M.A.L., Botti, S., Pistor, P. and Scheer, R. (2016) Research Update: Stable Single-Phase Zn-Rich Cu2ZnSnSe4 through in Doping. APL Materials, 4, Article ID: 070701. https://doi.org/10.1063/1.4953435
Razykov, T.M., Boltaev, G.S., Bosio, A., Ergashev, B., Kouchkarov, K.M., Mamarasulov, N.K., Mavlonov, A.A., Romeo, A., Romeo, N., Tursunkulov, O.M. and Yuldoshov, R. (2018) Characterisation of SnSe Thin Films Fabricated by Chemical Molecular Beam Deposition for Use in Thin Film Solar Cells. Solar Energy, 159, 834-840. https://doi.org/10.1016/j.solener.2017.11.053
Septina, W., Ikeda, S., Iga, Y., Harada, T. and Matsumura, M. (2014) Thin Film Solar Cell Based on CuSbS2 Absorber Fabricated from an Electrochemically Deposited Metal Stack. Thin Solid Films, 550, 700-704. https://doi.org/10.1016/j.tsf.2013.11.046
Tang, R., Wang, X., Jiang, C., Li, S., Jiang, G., Yang, S., Zhu, C. and Chen, T. (2018) Vacuum Assisted Solution Processing for highly Efficient Sb2S3 Solar Cells. Journal of Materials Chemistry A, 6, 16322-16327. https://doi.org/10.1039/C8TA05614E
Tang, R., Zheng, Z.H., Su, Z.H., Li, X.J., Wei, Y.D., Zhang, X.H., Fu, Y.Q., Luo, J.T., Fan, P. and Liang, G.X. (2019) Highly Efficient and Stable Planar Heterojunction Solar Cell Based on Sputtered and Post-Selenized Sb2Se3 Thin Film. Nano Energy, 64, Article ID: 103929. https://doi.org/10.1016/j.nanoen.2019.103929
Zhou, Y., Leng, M., Xia, Z., Zhong, J., Song, H., Liu, X., Yang, B., Zhang, J., Chen, J., Zhou, K., Han, J., Cheng, Y. and Tang, J. (2014) Solution-Processed Antimony Selenide Heterojunction Solar Cells. Advanced Energy Materials, 4, Article ID: 1301846. https://doi.org/10.1002/aenm.201301846
Liu, X., Chen, J., Luo, M., Leng, M., Xia, Z., Zhou, Y., Qin, S., Xue, D., Lv, L., Huang, H., Niu, D. and Tang, J. (2014) Thermal Evaporation and Characterization of Sb2Se3 Thin Film for Substrate Sb2Se3/CdS Solar Cells. ACS Applied Materials & Interfaces, 6, 10687-10695. https://doi.org/10.1021/am502427s
Donges, E. (1950) Uber Selenohalogenide Des Dreiwertigen Antimons und Wismuts und Uber Antimon(III)-Selenid. Zeitschrift für anorganische und allgemeine, 263, 280-291. https://doi.org/10.1002/zaac.19502630508
Jiajun, L., Jianming, L., Congqiang, L., Wenquan, L., Shirong, L. and Wenchao, S. (1999) Mineralogy of the Stibnite-Antimonselite Series. International Geology Review, 41, 1042-1050. https://doi.org/10.1080/00206819909465189
Black, J., Conwell, E.M., Seigle, L. and Spencer, C.W. (1957) Electrical and Optical Properties of Some M2v-bN3vi-b Semiconductors. Journal of Physics and Chemistry of Solids, 2, 240-251. https://doi.org/10.1016/0022-3697(57)90090-2
Rosi, F.D., Abeles, B. and Jensen, R.V. (1959) Materials for Thermoelectric Refrigeration. Journal of Physics and Chemistry of Solids, 10, 191-200. https://doi.org/10.1016/0022-3697(59)90074-5
Zhou, B. and Zhu, J. (2009) Microwave-Assisted Synthesis of Sb2Se3 Submicro Rods, Compared with Those of Bi2Te3 and Sb2Te3. Nanotechnology, 20, Article ID: 085604. https://doi.org/10.1088/0957-4484/20/8/085604
Mamta, Singh, Y., Maurya, K.K. and Singh, V.N. (2021) A Review on Properties, Applications, and Deposition Techniques of Antimony Selenide. Solar Energy Materials and Solar Cells, 230, Article ID: 111223. https://doi.org/10.1016/j.solmat.2021.111223
Chang, J.A., Rhee, J.H., Im, S.H., Lee, Y.H., Kim, H.J., Seok, S.I., Nazeeruddin, M.K. and Gratzel, M. (2010) High-Performance Nanostructured Inorganic-Organic Heterojunction Solar Cells. Nano Letters, 10, 2609-2612. https://doi.org/10.1021/nl101322h
Arun, P., Vedeshwar, A.G. and Mehra, N.C. (1999) Laser-Induced Crystallization in Amorphous Films of Sb2C3 (C = S, Se, Te), Potential Optical Storage Media. Journal of Physics D: Applied Physics, 32, 183-190. https://doi.org/10.1088/0022-3727/32/3/001