Retardation of 4-Hydroxy-2-Transnonenal (HNE), a Toxic Aldehyde Formation by Antioxidants in Heat-Treated Corn Oil at Frying Temperature — Oak Academic Publishing
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Retardation of 4-Hydroxy-2-Transnonenal (HNE), a Toxic Aldehyde Formation by Antioxidants in Heat-Treated Corn Oil at Frying Temperature
Department of Food Science and Nutrition, University of Minnesota, Saint Paul, USA
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Department of Food Science and Nutrition, University of Minnesota, Saint Paul, USA
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Department of Food Science and Nutrition, University of Minnesota, Saint Paul, USA
,
Department of Food Science and Nutrition, University of Minnesota, Saint Paul, USA
1 Department of Food Science and Nutrition, University of Minnesota, Saint Paul, USA
2 Department of Food Science and Nutrition, University of Minnesota, Saint Paul, USA
3 Department of Food Science and Nutrition, University of Minnesota, Saint Paul, USA
4 Department of Food Science and Nutrition, University of Minnesota, Saint Paul, USA
The antioxidative properties of four antioxidants such as rosemary extracts (RE), tert - butylhydroquinone (TBHQ), ascorbyl palmitate (AP), citric acid (CA) and their mixtures were investigated on the formation of 4-hydroxy-2-transnonenal (HNE) in commercial corn oil heated at 185 ° C for up to 6 hours. Among the antioxidants 100 ppm RE and a mixture of 200 ppm tertiary butylated hydroquinone (TBHQ) + 100 ppm ascorbyl palmitate (AP) + 50 ppm citric acid (CA) exhibited excellent antioxidative activity, as determined by the thiobarbituric acid reaction (TBARS) assay, measuring the formations of the secondary lipid oxidation products and by high-performance liquid chromatography (HPLC), measuring the formation of the toxic α , β -unsaturated hydroxyaldehyde HNE after heat treatment of corn oil at 185 ° C up to 6 hours. TBHQ, AP and CA alone did not show much protective properties. The synergistic effects of TBHQ + AP + CA mixture shown to reduce the formation of HNE after 6 hours heat-treated corn oil by 27%. RE 100 ppm was also found to be a very effective antioxidant, reducing the formation of HNE after 6 hours heat-treated corn oil in the same condition by 29%.
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