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Synthesis of Substituted N-Alkylamines in Aqueous Media
Mamedaliyev Institute of Petrochemical Processes, Azerbaijan National Academy of Sciences, Baku, Azerbaijan
Mamedaliyev Institute of Petrochemical Processes, Azerbaijan National Academy of Sciences, Baku, Azerbaijan
Mamedaliyev Institute of Petrochemical Processes, Azerbaijan National Academy of Sciences, Baku, Azerbaijan
Qafqaz University, Baku, Azerbaijan
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
- 1 Mamedaliyev Institute of Petrochemical Processes, Azerbaijan National Academy of Sciences, Baku, Azerbaijan
- 2 Mamedaliyev Institute of Petrochemical Processes, Azerbaijan National Academy of Sciences, Baku, Azerbaijan
- 3 Mamedaliyev Institute of Petrochemical Processes, Azerbaijan National Academy of Sciences, Baku, Azerbaijan
- 4 Qafqaz University, Baku, Azerbaijan
- 5 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
Green and Sustainable Chemistry·Volume 03 (2013)·Pages 31–35·Published 25 February 2013·DOI10.4236/gsc.2013.31006
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Abstract
Synthesis of N-substituted aminopentanes based on the reaction of the amines with 1-brompentanes ( n- and iso- structure) and amino (bis-amino) hydroxy compounds via opening reaction of epoxides with amines environmentally friendly practices in water medium has been developed. Structure of obtained compounds by elemental analysis and IR-, 1 H and 13 C NMR-spectroscopy were confirmed.
KeywordsN-AlkylaminesIonic LiquidsAmino AlcoholsAntibacterial Properties
- M. A. Fernandez-Rodriguezs, Q. L. Shen and J. F. Hartwig, “A General and Long-Livedcatalysttor the Palladium-Catalyzedcoupling of Arylhalideswith Thiols,” Journal of the American Chemical Society, Vol. 128, No. 7, 2006, pp. 2180-2181. doi:10.1021/ja0580340
- L. Chao-Jun, “Organic Reactions in Agueousmrdia with a Focus on Carbon-Carbon Bond Formations: A Decade Update,” Chemical Reviews, Vol. 105, No. 8, 2005, pp. 3095-3165. doi:10.1021/cr030009u
- R. N. Butler and A. G. Coyne, “Water: Natural’s Reaction Enforcer-Comparative Effects for Organic Synthesis ‘in-Water’ and ‘on-Water’,” Chemical Reviews, Vol.110, No 10, 2010, pp. 6302-6337. doi:10.1021/cr100162c
- Z.-L. Shen, K. KuaKiatGoh, H.-L. Cheong, C. H. A. Wong, Y.-C. Lai, Y.-S. Yang and T.-P. Loh, “Synthesis of Water-Tolerant Indium Homo-Enolate in Agueous Media and Its Application in the Synthesis of 1,4-Dicarbonyl Compounds via Palladium-Catalyzed Coupling with Acidc Hloride,” Journal of the American Chemical Society, Vol. 132, No. 45, 2010, pp. 15852-15855. doi:10.1021/ja106925f
- N. Azizi and M. R. Saidi, “Highly Chemo-Selective Addition of Amines to Epoxides in Water,” Organic Letters, Vol. 7, No. 17, 2005, pp. 3649-3651.
- G. Evans, T. J. K. Gibbs, R. L. Zenkins, S. J. Coles, M. B. Hursthouse, A. J. Platts and N. C. O. Tomkinson, “Kinetics of Iminium Ion Catalysis,” Angewandte Chemie International Edition, Vol. 47, No. 15, 2008, pp. 2820-2823.
- D. Zhu, L. Xu, F. Wu and B. Wan, “A Mild and Efficient Copper-Catalyzed Coupling of Aryl Iodides and Thiols Using an Oximephosphine Oxide Ligand,” Tetrahedron letters, Vol. 47, No. 32, 2006, pp. 5781-5784.
- L. Rout, T. K. Sen and T. Punniyamurthy, “Efficient CuO-Nanoparticlecatalyzed C-S Cross-Copling of Thiols with Iodobenzene,” Angewandte Chemie International Edition, Vol. 46, No. 29, 2007, pp. 5583-5586.
- K. Hu, K. E. Krakowiask, J. S. Bradshaw, N. K. Dalley, G. Xue and R. M. Izzat, “Synthesys of Chiral Azamacrocycles Using the Bis(α-chloroacetamide)s Derived from Chiral 1,2-Di-phenylethy-lenediamine,” Journal of Heterocyclic Chemistry, Vol. 36, No. 2, 1999, pp. 347-354.
- Y. Nagasaki, E. Honzawa, M. Kato and T. Tsuruta, “Novel Synthesis of a Mac-Romonomer Having Organosilyl and Amino Groups,” Journal of Macromolecular Science: Pure and Applied Chemistry, Vol. 29, No. 6, 1992, pp. 457-470.
- M. K. Denk, K. Hatono and A. J. Lough, “Synthesis and Characterization of a Carbine-SO2,” European Journal of Inorganic Chemistry, Vol. 2003, No. 2, 2003, pp. 224-231. doi:10.1002/ejic.200390030