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Oligoalkylnaphthenic (C<sub>6</sub>-C<sub>12</sub>) Oils Obtained in the Presence of Ti-Containing Ionic-Liquid Catalysts
The Y.H. Mamedaliyev Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences, Baku, Azerbaijan
The Y.H. Mamedaliyev Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences, Baku, Azerbaijan
The Y.H. Mamedaliyev Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences, Baku, Azerbaijan
- 1 The Y.H. Mamedaliyev Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences, Baku, Azerbaijan
- 2 The Y.H. Mamedaliyev Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences, Baku, Azerbaijan
- 3 The Y.H. Mamedaliyev Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences, Baku, Azerbaijan
Green and Sustainable Chemistry·Volume 03 (2013)·Pages 18–26·Published 22 November 2013·DOI10.4236/gsc.2013.34A004
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Abstract
In this present paper, the result of C 6 -C 12 α -olefins oligomerizaton in the presence of recyclable chloroaluminate type ionic-liquid catalysts and their combination with Ti-containing complexes is presented. By different methods of analysis the composition and structure of oligoalkylnaphtenic products obtained in the presence of ionic-liquid catalysts and Ti-containing modifiers have been studied.
KeywordsIonic LiquidOligomerizationPAO
- J. D. Holbrey and K. R Seddon, Clean Product and Processes, Vol. 1, 1999, pp. 223-236.
- A. H. Azizov and Z. H. Asadov, “Production and Usage of α-Olefins and Advantages in the Metal-Complex Catalyzed Selective Oligomerization of Ethylene,” Processes of Petrochemistry and Oil Refining, Vol. 1, 2003, pp. 44-67.
- T. Welton, “Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis,” Chemical Reviews, Vol. 99, No. 8, 1999, pp. 2071-2083. http://dx.doi.org/10.1021/cr980032t
- A. H. Azizov, “Preparation Methods and Solvent Properties of Low Temperature Ionic Liquids,” Process of Petrochemistry and Oil Refening,” Vol. 1, No. 8, 2002, pp. 90-115.
- A. H. Azizov, “Low Temperature Ionic Liquids in Organic and Petrochemical Synthesis,” Processes of Petrochemistry and Oil Refining, Vol. 2, No. 9, 2002, pp. 6-48.
- R. V. Aliyeva, “Ionic Liquids in Catalysis Petrochemical Processes,” Processes of Petrochemistry and Oil Refining, Vol. 1, No. 16, 2004, pp. 26-46.
- R. V. Aliyeva, “Ionic Liquids during Separation and Extraction,” Processes of Petrochemistry and Oil Refining, Vol. 2, No. 25, 2006, pp. 30-39.
- A. A. Xanmetov, Kh. H. Asgerova, R. V. Aliyeva and A. H. Azizov, “Ionic Liquids to Oligomerization and Polymerization Processes of Olefins,” Processes of Petrochemistry and Oil Refining, 11, 42, 2010, pp. 309-328 (in Russian).
- P. Wasserscheid, “Green Industrial Applications of Ionic Liquids,” Kluwer Academic Publishers, Boston, 2003, pp. 29-47.
- K. R. Seddon, “Ionic Liquids for Clean Technology,” Journal of Chemical Technology and Biotechnology, Vol. 68, No. 4, 1997, pp. 351-356. http://dx.doi.org/10.1002/(SICI)1097-4660(199704)68:4 3.0.CO;2-4
- H. Olivier, “Recent Developments in the Use of Non-Aqueous Ionic Liquids for Two-Phase Catalysis,” Journal of Molecular Catalysis A, 146, 1999, pp. 285-289.
- H. Olivier, J. A. Chodorge and P. Travers, “Olefin Oligomerization with Homogeneous Catalysis,” Petroleum Technology Quarter (PTQ), Autumn, 1999, p. 141.
- A. H. Azizov, et al., “Selective Synthesis and the Mechanism of Formation of the Oligoalkylnaphthennic Oils by Oligocyclization of 1-Hexene in the Presence of Ionic-Liquid Catalysts,” Applied Catalysis A: General, Vol. 375, 2010, pp. 70-77.
- N. R. Bektashi, A. M. Mustafayev, Qusyynov, et al., “Chromatographic Investigation of Regularities of Synthesis of Halogen-Containing Unsaturated Polyesters,” Jour- nal Prikladnoy Chimii, Vol. 84, No. 7, 2011, pp. 1211-1217 (in Russian).