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Hydrogen Generation by Reforming of Sodium Hypophosphite on Cobalt-Boron Oxides Containing Catalyst
Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
- 1 Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
- 2 Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
- 3 Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
- 4 Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
- 5 Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
- 6 Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
- 7 Raphael Agladze Institute of Inorganic Chemistry and Electrochemistry, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia
Green and Sustainable Chemistry·Volume 07 (2017)·Pages 85–93·Published 26 January 2017·DOI10.4236/gsc.2017.71007
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Abstract
Cobalt-Boron oxides containing catalyst CoO · B 2 O 3 (CoB 2 O 4 ) are synthesized for hydrogen generation by catalytic reforming of basic solution of sodium hypophosphite (NaH 2 PO 2 ) and identified by chemical and X-ray analysis. Reforming is performed in temperature range of 30 ° C - 80 ° C. Reaction rate constants at each value of temperature (k 30 ° C = 8.53 × 10 ? 4 s ? 1 ; k 40 ° C = 1.62 × 10 ? 4 s ?? ; k 50 ° C = 3.06 × 10 ? 3 s ? 1 ; k 60 ° C = 5.06 × 10 ? 3 s ? 1 ; k 80 ° C = 1.39 × 10 ? 2 s ? 1 ), temperature coefficient of rate of chemical reaction ( γ = 0.917) and activation energy ( E A = 49.59 kJ · mol ? 1 ) are calculated.
KeywordsCobalt-Boron OxideHydrogenCatalystReformingSodium Hypophosphite
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