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Ligand Exchange Reaction of Ferrocene with Substituted Benzenes
Department of Applied Chemistry, Ritsumeikan University, Kusatsu, Japan
Department of Applied Chemistry, Ritsumeikan University, Kusatsu, Japan
- 1 Department of Applied Chemistry, Ritsumeikan University, Kusatsu, Japan
- 2 Department of Applied Chemistry, Ritsumeikan University, Kusatsu, Japan
International Journal of Organic Chemistry·Volume 12 (2022)·Pages 1–10·Published 8 March 2022·DOI10.4236/ijoc.2022.121001
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Abstract
Ligand exchange reaction is one of the typical reactions of ferrocene. In this paper, ligand exchange reactions were carried out between ferrocene and var ious substituted benzenes using aluminum chloride catalysis. The product yields of the reactions with alkanoyl- and alkoxybenzenes were low because of the coordination of aluminum chloride to the oxygens of the benzene substituents. Comparing the reactions using o - and p -dimethoxybenzene, the former was revealed to be less reactive; this is likely due to the deviation of the π-electrons of its benzene ring being larger.
KeywordsFerroceneLigand Exchange ReactionSubstituted Benzenes
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