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2,4-Dinitrophenyl Ether of Polyvinyl Alcohol and Polymer Bound Anionic SIGMA Complexes
K&J Applied Polymer Science Consultants, University of Vermont, Burlington, USA
K&J Applied Polymer Science Consultants, University of Vermont, Burlington, USA
- 1 K&J Applied Polymer Science Consultants, University of Vermont, Burlington, USA
- 2 K&J Applied Polymer Science Consultants, University of Vermont, Burlington, USA
International Journal of Organic Chemistry·Volume 13 (2023)·Pages 87–95·Published 29 August 2023·DOI10.4236/ijoc.2023.133007
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Abstract
A new electrophilic polymer, 2,4-dinitrophenyl ether of polyvinyl alcohol (PVA-DNP), having a degree of substitution of 0.5 was prepared from polyvinyl alcohol (PVA) and 1-fluro-2,4-dinitrobenzene (DNFB). The PVA-DNP polymer was characterized by NMR, IR, and UV-visible spectroscopy. The reaction of PVA-DNP with sodium methoxide was followed by NMR and UV-visible spectroscopy. Evidence of polymer bound spirocyclic SIGMA complex, C-1 and C-3 polymer bound DNP-methoxy SIGMA complexes and the formation and C-1 methoxy complex of 2,4-dinitroanisole was observed.
Keywords24-Dinitrophenyl EtherPolyvinyl AlcoholAnionic SIGMA ComplexThermal StabilityNucleophilic Aromatic Substitution
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