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Unusual Catalytic Process Involving OH and NH Exchange
Applied Chemistry Department, Faculty of Applied Science, Taibah University, Almadinah Almunawrah, Kingdom of Saudi Arabia
Applied Chemistry Department, Faculty of Applied Science, Taibah University, Almadinah Almunawrah, Kingdom of Saudi Arabia
- 1 Applied Chemistry Department, Faculty of Applied Science, Taibah University, Almadinah Almunawrah, Kingdom of Saudi Arabia
- 2 Applied Chemistry Department, Faculty of Applied Science, Taibah University, Almadinah Almunawrah, Kingdom of Saudi Arabia
International Journal of Organic Chemistry·Volume 02 (2012)·Pages 64–70·Published 15 March 2012·DOI10.4236/ijoc.2012.21011
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Abstract
Interaction of some transition metals species with a Schiff base, 1, derived from 4,6-diacetylresorcinol and 2-amino- 5-methylphenol (1:2 mole ratio) yielded the two compounds 4-ethanimidoyl-6-[(1 E )-N-(2-hydroxy-4-methylphenyl) ethanimidoyl]benzene-1,3-diol, 2, and 4,6-diacetyl-1,3-diaminobenzene, 4 via unusual catalytic process involving OH and NH exchange. All the compounds are characterized by elemental analysis, IR, mass and 1 H NMR. The structure of the two compounds 2 and 4 are also determined by X-ray analysis. The crystal structure analysis revealed that the two compounds crystallized in the monoclinic space group P 2 1 /c with a Z value of 4.
KeywordsBicompartment LigandSchiff BasesDiaminobenzeneX-Ray Analysis
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