SO<sub>4</sub><sup>2-</sup>/SnO<sub>2</sub>-Catalyzed C3-alkylation of 4-hydroxycoumarin with secondary benzyl alcohols and <i>O</i>-alkylation with <i>O</i>-acetyl compounds — Oak Academic Publishing
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SO<sub>4</sub><sup>2-</sup>/SnO<sub>2</sub>-Catalyzed C3-alkylation of 4-hydroxycoumarin with secondary benzyl alcohols and <i>O</i>-alkylation with <i>O</i>-acetyl compounds
School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Maharashtra, India
,
Department of Chemistry, Rajiv Gandhi University of Knowledge Technologies, Andhra Pradesh, India
,
School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Maharashtra, India
1 School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Maharashtra, India
2 Department of Chemistry, Rajiv Gandhi University of Knowledge Technologies, Andhra Pradesh, India
3 School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Maharashtra, India
Sulfated tin oxide (STO) has been found to be an efficient reusable solid superacid catalyst for C3-alkylation and O-alkylation of 4-hydroxycoumarins with benzylic, allylic alcohols/and corresponding acetates respectively, in acetic acid under reflux conditions with good yield of products.
KeywordsC-C and C-O bond formationsSulfated tin oxide (STO)reusability4-Hydroxy coumarinsecondary benzyl alcoholsecondary benzyl O-acetate
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