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Synthesis, Photochromic Property and Application for Optical Recording of a New Asymmetrical Diarylethene
Department of Chemistry and Chemical Engineering, Sichuan University of Arts and Science, Dazhou, China
Department of Chemistry and Chemical Engineering, Sichuan University of Arts and Science, Dazhou, China
Sichuan Higher Education Key Laboratory of Characteristic Plant Development and Research, Sichuan University of Arts and Science, Dazhou, China
- 1 Department of Chemistry and Chemical Engineering, Sichuan University of Arts and Science, Dazhou, China
- 2 Department of Chemistry and Chemical Engineering, Sichuan University of Arts and Science, Dazhou, China
- 3 Sichuan Higher Education Key Laboratory of Characteristic Plant Development and Research, Sichuan University of Arts and Science, Dazhou, China
International Journal of Organic Chemistry·Volume 02 (2012)·Pages 387–390·Published 27 December 2012·DOI10.4236/ijoc.2012.24053
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Abstract
The reversible molecule switching of an assymmetrical photochromic diarylethene 1-[2-methy1-5-(3-chlorophenyl)-3-thienyl]-2-(1,2-dimethy1-3-indol) perfluorocyelopentene ( 1a ) has been prepared for the examination of photo-switching, fluorescence switching. This compound exhibited reversible photochromism, changing from colorless to blue after irradiation with UV light both in solution and in poly-methyl methacrylate (PMMA) amorphous film. Also, it exhibited remarkable fluorescence switching in the solid state. Using diarylethene 1b/PMMA film as recording medium, polarization optical recording was performed perfectly by a He-Ne laser with 633 nm wavelength. The results demonstrated that it can be potentially used as polarization optical recording medium.
KeywordsDiaryletheneFluorescenceOptical Recording
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