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An Efficient α-Phosphoryloxylation of Ketones
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International Journal of Organic Chemistry·Volume 01 (2011)·Pages 1–5·Published 18 March 2011·DOI10.4236/ijoc.2011.11001
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Abstract
An efficient α-phosphoryloxylation of ketones has been developed. When ketones were treated with (diace-toxyiodo)benzene and phosphates in CH2Cl2 at room temperature, the α-phosphoryloxylaction of ketones was easily be carried out, providing the ketol phosphates in good yields.
Keywordsα-PhosphoryloxylationKetol phosphate(Diacetoxyiodo)benzeneSynthesis
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