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Ligand Exchange Reaction of Ferrocene with Heterocycles
Department of Applied Chemistry, Ritsumeikan University, Kusatsu-Shi, Japan
Department of Applied Chemistry, Ritsumeikan University, Kusatsu-Shi, Japan
Department of Applied Chemistry, Ritsumeikan University, Kusatsu-Shi, Japan
- 1 Department of Applied Chemistry, Ritsumeikan University, Kusatsu-Shi, Japan
- 2 Department of Applied Chemistry, Ritsumeikan University, Kusatsu-Shi, Japan
- 3 Department of Applied Chemistry, Ritsumeikan University, Kusatsu-Shi, Japan
International Journal of Organic Chemistry·Volume 05 (2015)·Pages 282–290·Published 24 November 2015·DOI10.4236/ijoc.2015.54028
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Abstract
The ligand exchange reaction with heterocycles containing nitrogen, oxygen or sulfur atoms was carried out. For the reaction with heterocycles, the order of the reactivity was S-heterocycles > N-heterocycles > O-heterocycles. Furthermore, when the results for the heterocycles were compared to those for the corresponding hydrocarbons, the hydrocarbons had a higher reactivity. These results mean that the reactivity would be mainly governed by the electron density of these arenes.
KeywordsFerroceneLigand Exchange ReactionHeterocycle
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