Synthesis of Chiral Schiff Base Metal Complex Inducing CD and Elucidation of Structure of Adsorption on Surface of Gold Nanoparticles — Oak Academic Publishing
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Synthesis of Chiral Schiff Base Metal Complex Inducing CD and Elucidation of Structure of Adsorption on Surface of Gold Nanoparticles
Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo, Japan
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Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo, Japan
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Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo, Japan
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Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo, Japan
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Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo, Japan
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Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo, Japan
1 Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo, Japan
2 Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo, Japan
3 Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo, Japan
4 Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo, Japan
5 Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo, Japan
6 Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo, Japan
We have prepared supramolecular systems of chiral Schiff base Ni(II), Cu(II), Zn(II) complexes and colloidal gold nanoparticles (AuNP) of 10 nm diameters. They demonstrated that direct adsorption of chiral Schiff base metal complex on the surface of AuNP owing to observation of clear induced CD spectra for the first time. We observed and discussed induced CD bands on AuNP from chiral Schiff base Ni(II), Cu(II), Zn(II) complexes.
KeywordsChiral Schiff Base Metal ComplexGold Nanoparticle
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