Microwave Preparation and Spectroscopic Investigation of Binuclear Schiff Base Metal Complexes Derived from 2,6-Diaminopyridine with Salicylaldehyde — Oak Academic Publishing
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Microwave Preparation and Spectroscopic Investigation of Binuclear Schiff Base Metal Complexes Derived from 2,6-Diaminopyridine with Salicylaldehyde
Department of Chemistry, College of Science, University of Kirkuk, Kirkuk, Iraqi
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Department of Chemistry, College of Science, University of Kirkuk, Kirkuk, Iraqi
1 Department of Chemistry, College of Science, University of Kirkuk, Kirkuk, Iraqi
2 Department of Chemistry, College of Science, University of Kirkuk, Kirkuk, Iraqi
The binuclear Schiff base complexes prepared by condensation 2,6-diamino-pyridine and salicylaldehyde (LH) by using microwave and adding metal salts to ligand by same ratio. The Schiff base ligand was checked by infrared, electronic spectra and <SUP>1</SUP>HNMR spectroscopy and prepared complexes characterized by molar conductivity, infrared, electronic spectra and susceptibility measurements. The values of molar conductivities reveal that the complexes are non-electrolytes, from obtained data of electronic spectra and magnetic moment, an octahedral geometry was suggested, coordinated to the metal ions in a manner with N donor sites of imine groups, and oxygen of phenolic OH group.
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