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Generalized Electron Balance for Dynamic Redox Systems in Mixed-Solvent Media
Department of Oncology, The University Hospital in Cracow, Cracow, Poland
Faculty of Engineering and Chemical Technology, Cracow University of Technology, Cracow, Poland
- 1 Department of Oncology, The University Hospital in Cracow, Cracow, Poland
- 2 Faculty of Engineering and Chemical Technology, Cracow University of Technology, Cracow, Poland
Journal of Analytical Sciences, Methods and Instrumentation·Volume 04 (2014)·Pages 102–109·Published 2 December 2014·DOI10.4236/jasmi.2014.44014
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Abstract
A complex example of electrolytic redox system involving 47 species, 3 electron-active elements and five (3 am-phiprotic + 2 aprotic) co-solvents, is presented. Mixed solvates of the species thus formed are admitted in the system considered. It is proved that the Generalized Electron Balance (GEB) in its simplest form obtained according to the Approach II to GEB is identical with the one obtained for aqueous media and binary-solvent system, and is equivalent to the Approach I to GEB.
KeywordsElectrolytic Redox SystemsGeneralized Electron BalanceMixed-Solvent Media
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