It was tried to microencapsulate camellia oil using heterocoagulation between fatty acid dissolved in camellia oil and chitosan dissolved in the continuous water phase. Oleic acid as a fatty acid was dissolved in camellia oil in order to certainly form the microcapsule shell made from oleic acid and chitosan. The microcapsules were observed with optical microscope and characterized about the diameters, ζ -potential, FTIR analysis and adhesion feature on human hair. Microcapsules with the mean diameter in the range from ca. 1.5 μm to 4.5 μm could be prepared with the preparation method presented in this study. The oil droplets of camellia oil charged negatively to be -54.6 mV and the microcapsules charged positively to be 59.6 mV. The microcapsules adhered well on the negatively charged human hair and were kept stably before and after drying at room temperature for 24 h and blowing.
Kondo, T. (1967) Saishin Maikurokapseruka Gijutsu (Microencapsulation Technique). TES, Tokyo.
Tanaka, M. (2008) Key Point of Preparation of Nano/Microcapsules. Techno System Publishing Co. Ltd., Tokyo.
Koishi, M., Eto, K. and Higure, H. (2005) (Preparation + Utilization) Microcapsules. Kogyo Chosakai, Tokyo.
Wang, J.M., Zheng, W., Song, Q.W., Zhu, H. and Zhou, Y. (2009) Preparation and Characterization of Natural Fragrant Microcapsules. Journal of Fiber Bioengineering and Informatics, 1, 293-300. https://doi.org/10.3993/jfbi03200907
Lee, H., Jeong, C., Ghafoor, K., Cho, S. and Park, J. (2011) Oral Delivery of Insulin Using Chitosan Capsules Cross Linked with Phytic Acid. Bio-Medical Materials and Engineering, 21, 25-36.
Suthaphot, N., Chulakup, S., Chonsakorn, S. and Mongkholrattanasit, R. (2012) Application of Aroma Therapy on Cotton Fabric by Microcapsules. International Conference: Textiles & Fashion 2012, Bangkok, 3-4 July 2014.
Satapathy, D., Biswas, D., Behera, B., Sagiri, S.S., Pal, K. and Pramanik, K. (2013) Sunflower-Oil-Based Lecithin Organogelsas Matrices for Controlled Drug Delivery. Journal of Applied Polymer Science, 129, 585-594. https://doi.org/10.1002/app.38498
Hsieha, W.C., Changb, C.P. and Gaoc, Y.L. (2006) Controlled Release Properties of Chitosan Encapsulated Volatile Citronella Oil Microcapsules by Thermal Treatments. Colloids and Surfaces B: Biointerfaces, 53, 209-214. https://doi.org/10.1016/j.colsurfb.2006.09.008
Iamrungraksa, T. and Charuchinda, S. (2010) Preparation and Characteristics of Galangal Essential Oil/Alginate Microcapsules. Journal of Metals, Materials and Minerals, 20, 89-92.
Soliman, E.A., El-Moghazy, A.Y., Mohy El-Din, M.S. and Massoud, M.A. (2013) Microencapsulation of Essential Oils within Alginate: Formulation and in Vitro Evaluation of Antifungal Activity. Journal of Encapsulation and Adsorption Sciences, 3, 48-55. https://doi.org/10.4236/jeas.2013.31006
Paques, J.P., van der Linden, E., van Rijn, C.J. and Sagis, L.M. (2014) Preparation Methods of Alginate Nanoparticles. Advances in Colloid and Interface Science, 209, 163-171. https://doi.org/10.1016/j.cis.2014.03.009
Belyaeva, E., Valle, D.D., Neufeld, R.J. and Poncelet, D. (2004) New Approach to the Formulation of Hydrogel Beads Byemulsi & Cation/Thermal Gelation Using a Static Mixer. Chemical Engineering Science, 59, 2913-2920. https://doi.org/10.1016/j.ces.2004.04.010
Wang, A., Tao, C., Cui, Y., Duan, L., Yang, Y. and Li, J. (2009) Assembly of Environmental Sensitive Microcapsules of PNIPAAm and Alginate Acidand Their Application in Drug Release. Journal of Colloid and Interface Science, 332, 271-279. https://doi.org/10.1016/j.jcis.2008.12.032
Katoh, K., Yoshimura, H. and Fujita, H. (2005) Preparation of Porous Matrices of Natural Polymer Using Microcapsules. http://www.aichi-inst.jp/owari/research/report/owari_2005_08.pdf
Tian, K., Xie, C. and Xia, X. (2013) Chitosan/Alginate Multilayer Film for Controlled Release of IDM on Cu/LDPE Composite Intrauterine Devices. Colloids and Surfaces B: Biointerfaces, 109, 82-89. https://doi.org/10.1016/j.colsurfb.2013.03.036
Su, J.F., Wang, S.B., Zhang, Y.Y. and Huang, Z. (2011) Physicochemical Properties and Mechanical Characters of Methanol-Modified Melamine-Formaldehyde (MMF) Shell MicroPCMS Containing Paraffin. Colloid and Polymer Science, 289, 111-119. https://doi.org/10.1007/s00396-010-2328-1
Yuan, Y., Zhang, N., Tao, W., Cao, X. and He, Y. (2014) Fatty Acids as Phase Change Materials: A Review. Renewable and Sustainable Energy, 29, 482-498. https://doi.org/10.1016/j.rser.2013.08.107
Yang, Z., Peng, Z., Li, J., Li, S., Kong, L., Li, P. and Wang, Q. (2014) Development and Evaluation of Novel Flavour Microcapsules Containing Vanilla Oil Using Complex Coacervation Approach. Food Chemistry, 145, 272-277. https://doi.org/10.1016/j.foodchem.2013.08.074
Chang, C.P., Leung, T.K., Lin, S.M. and Hsu, C.C. (2006) Release Properties on Gelatin-Gum Arabic Microcapsules Containing Camphor Oil with Added Polystyrene. Colloids and Surfaces B: Biointerfaces, 50, 136-140. https://doi.org/10.1016/j.colsurfb.2006.04.008
Soottitantawat, A., Bigeard, F., Yoshii, H., Furuta, T., Ohkawara, M. and Linko, P. (2005) Influence of Emulsion and Powder Size on the Stability of Encapsulated d-Limonene by Spray Drying. Innovative Food Science and Emerging Technologies, 6, 107-114. https://doi.org/10.1016/j.ifset.2004.09.003
Polavarapu, S., Oliver, C.M., Ajlouni, S. and Augustin, M.A. (2012) Impact of Extra Virgin Olive Oil and Ethylenediaminetetraacetic Acid (EDTA) on the Oxidative Stability of Fish Oil Emulsions and Spray-Dried Microcapsules Stabilized by Sugar Beet Pectin. Journal of Agricultural and Food Chemistry, 60, 444-450. https://doi.org/10.1021/jf2034785
Gharsallaoui, A., Saurel, R., Chambin, O., Cases, E., Voilley, A. and Cayot, P. (2010) Utilisation of Pectin Coating to Enhance Spray-Dry Stability of Pea Protein-Stabilised Oil-in-Water Emulsions. Food Chemistry, 122, 447-454. https://doi.org/10.1016/j.foodchem.2009.04.017
Taguchi, Y., Ono, F. and Tanaka, M. (2013) Preparation of Microcapsules Containing β-Carotene with Thermo Sensitive Curdlan by Utilizing Reverse Dispersion. Pharmaceutic, 5, 609-620. https://doi.org/10.3390/pharmaceutics5040609
Jung, E., Lee, J., Back, J., Jung, K., Lee, T., Huh, S., Kim, S., Koh, J., and Park, D. (2007) Effect of Camellia japonica Oil on Human Type I Procollagen Production and Skin Barrier Function. Journal of Ethnopharmacology, 112, 127-131. https://doi.org/10.1016/j.jep.2007.02.012
Tanaka, M. and Tanaka, M. (1989) Effect of Sudden Reduction of Impeller Speed on Particle Size Distribution in Suspension Polymerization of Styrene. Journal of Chemical Engineering of Japan, 22, 559-561. https://doi.org/10.1252/jcej.22.559
Hosogai, K. and Tanaka, M. (1992) Study of Suspension Polymerization of Styrene with a Circular Loop Reactor. Polymer Engineering Science, 32, 431-437. https://doi.org/10.1002/pen.760320608