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Synthesis, Spectral Characterization and Ligation of <i>N</i>-[2-(Phenylseleno)ethyl]phthalimide

¹ School of Studies in Chemistry, Jiwaji University, Gwalior, India
² School of Studies in Chemistry, Jiwaji University, Gwalior, India
³ School of Studies in Chemistry, Jiwaji University, Gwalior, India
⁴ Department of Chemistry, Howard University, Washington DC, USA

Journal of Crystallization Process and Technology·Volume 03 (2013)·Pages 31–34·Published 28 January 2013·DOI10.4236/jcpt.2013.31005

Abstract

PhSe - Na + generated in situ by reduction of Ph S e Se Ph , with sodium borohydride on reaction with N -(2-bromoethyl) phthalimide in N 2 atmosphere results in the formation of N -[2-(phenylseleno)ethyl]phthalimide ( L 1 ). The title compound has been characterized by elemental analysis, FT-IR, 1 H and 13 C NMR techniques. The crystal structure of L 1 has been solved by direct methods and refined by full-matrix least squares. The ligand L 1 crystallize in the monoclinic space group. Selenium forms two Se-C linkages, one is due to Se-C alkyl and the other one to Se-C aryl . Further, the ligation reaction of L 1 with complex 1 is also explored whose identities are characterized by spectroscopic techniques.

KeywordsPhthalimideSeleniumMonoclinicPhenylselenoSodium Borohydride

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Synthesis, Spectral Characterization and Ligation of <i>N</i>-[2-(Phenylseleno)ethyl]phthalimide

Abstract

References (16)