Crystallization and Characterization of Triglycine Sulfate(TGS) Crystal Doped with NiSO4
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Abstract
Nickel sulfate doped triglycine sulfate crystals have been grown by natural evaporation method. The chemical composition of the pure triglycine sulfate crystals and the presence of nickel ion in doped triglycine sulfate crystal were confirmed by Energy Dispersive X-ray analysis. The functional groups of the grown crystals have been identified by the Fourier Transform Infrared spectroscopy. The structural studies on the grown crystals were carried out by X-ray Diffraction analysis. All the grown crystals are found in monoclinic structure and the lattice parameters of pure TGS crystal are a = 9.6010 Å, b = 12.5600 Å and c = 5.4500 Å. The lattice parameters are slightly distorted due to the incorporation of nickel ion into the lattice sites of the TGS crystal.
- K. Itoh and T. Mitsui, “Studies of the Crystal Structure of Triglycine Sulfate In Connection with Its Ferroelectric Phase Transition”, Ferroelectrics, Vol. 5, 1973, pp. 235- 251. doi: 10.1080/00150197308243954.
- M. I. Kay and R. Klienberg, “The Crystal Structure of Triglycine Sulfate”, Ferroelectrics, Vol. 5, 1973, pp. 45- 52. doi: 10.1080/00150197308235778.
- ] K. B. Ashok, D. A. Mohan, and B. L.Ravindra, “Growth and Characterization of Doped DTGS Crystals for Infrared Sensing Devices”, Materials Letters, Vol. 57, 2003, pp. 3943-3948.doi:10.1016/S0167- 577X(03)00244-1.
- C.Berbacaru,H.V.Alexandru,L. Pintilie, A. Dutu, B. Logofatu, and R. C. Radulescu, “Doped Versus Pure TGS Crystals,” Mater. Sci. Engg., Vol. 118, 2005, pp. 141- 146. doi:10.1016/j.mseb.2004.12.069.
- S. Hashino, Y. Okaya and R. Pepinsky, “Crystal Structure of The Ferroelectric Phase of (Glycine)3?H2SO4” Phys. Rev. Vol.115, 1959, pp. 323-330. doi: 10.1103/PhysRev.115.323.
- R.B. Lal and A.K. Batra, “Growth and Properties of Triglycine Sulfate (TGS) Crystals:Review”, Ferroelectrics, Vol. 142, 1993, pp. 51-82. doi: 10.1080/00150199308237884.
- K. Biedzycki, “Energy Distribution of Electron Emission from -Α Alanine Doped TGS Single Crystals”, Solid State Commun., Vol. 118, 2001, pp. 141-44. doi: 10.1016/038-098(01)00052-7.
- S. Genbo, H. Youping, Y. Hongshi, S. Zikong and ingin, “A New yroelectric Crystal Lysine-Doped TGS (LLTGS)” J.Cryst. Growth. Vol. 209, 2000, pp. 220-222. doi:10.1016/0022-0248(99)00591-6.
- R. Muralidharan, R. Mohankumar, P.M. Ushasree, R. Jayavel and P. Ramasamy, “Growth and Characterization of Zinc Thiourea,” J. Cryst. Growth. Vol. 234, 2002, pp. 545-550. doi:10.1016/S0022-0248(01)01723-7.
- N. T. Shanthi, P. Selverajan and C. K. Mahadevan, “Studies on Triglycine Sulfate (TGS) Crystals Doped with Sodium Bromide (Nabr) Grown by Solution Method”, Ind. J. of Sci. and Technol. Vol. 3, 2009, pp. 49-2. ISSN: 0974-6846.
- F. Khanum, J. Podder, “ctural and Optical Properties of Triglycine Sulfate Single Crystals Doped with Potassium Bromide”, J. Of Cryst. Process and Technol. Vol. 1, 2011, pp. 26-31. doi: 10.4236/jcpt.2011.12005.
- N. Kubota, J. Fukazawa, H. Yashiro and J. W. Mullin, “Impurity Effect of Chromium(III) on the Growth and Dissolution Rates of Potassium Sulfate Cyrstals”, J.Cryst. Growth. Vol.149, 1995, pp. 113-119. doi:10.1016/0022-0248(94)01007-2.