Highly-Controllable Imprinted Polymer Nanoshell on the Surface of Silica Nanoparticles for Selective Adsorption of 17<i>β</i>-Estradiol — Oak Academic Publishing
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Highly-Controllable Imprinted Polymer Nanoshell on the Surface of Silica Nanoparticles for Selective Adsorption of 17<i>β</i>-Estradiol
College of Architecture and Environment, Sichuan University, Chengdu, China
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Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, China
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Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, China
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College of Architecture and Environment, Sichuan University, Chengdu, China
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Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, China
1 College of Architecture and Environment, Sichuan University, Chengdu, China
2 Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, China
3 Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, China
4 College of Architecture and Environment, Sichuan University, Chengdu, China
5 Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, China
A highly-controllable core-shell silica-MIPs absorbent by anchoring a MIPs layer to the surface of SiO 2 nanoparticles via a surface molecular imprinting process was prepared. The templates were covalently modified with functional monomers to form precursor EstSi. The latter together with coupling reagent KH-570, were grafted onto the surface of SiO 2 nanoparticles before polymerization, to ensure the quantity and quality of imprinted sites on the surface of the covalently attached matrix. The as-synthesized core-shell nanomaterials (SiO 2 @MIP2) were then evaluated for selective adsorption of 17 β -estradiol (E2) with Raman spectra as detection method. The results indicate that SiO 2 @MIP2 can fast and selectively adsorb E2 from structural analogues, with detection limit of 0.01 μmol/l.
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