Study of the Temperature-Programmed Desorption of Carbon Dioxide (CO<sub>2</sub>) on Zeolites X Modified with Bivalent Cations — Oak Academic Publishing
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Study of the Temperature-Programmed Desorption of Carbon Dioxide (CO<sub>2</sub>) on Zeolites X Modified with Bivalent Cations
Laboratoire de Chimie des Milieux et des Matériaux Inorganiques (LC2MI), URCHI/Université des Sciences et Techniques de Masuku (USTM), Franceville, Gabon
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Laboratoire de Chimie des Milieux et des Matériaux Inorganiques (LC2MI), URCHI/Université des Sciences et Techniques de Masuku (USTM), Franceville, Gabon
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Département de Chimie, Faculté des Sciences, Université des Sciences et Techniques de Masuku (USTM), Franceville, Gabon
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Laboratoire de Chimie des Milieux et des Matériaux Inorganiques (LC2MI), URCHI/Université des Sciences et Techniques de Masuku (USTM), Franceville, Gabon
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Département de Chimie, Faculté des Sciences, Université des Sciences et Techniques de Masuku (USTM), Franceville, Gabon
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Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), UMR 7285 CNRS/Université de Poitiers, 4 Rue Michel Brunet, Poitiers Cedex, France
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Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), UMR 7285 CNRS/Université de Poitiers, 4 Rue Michel Brunet, Poitiers Cedex, France
1 Laboratoire de Chimie des Milieux et des Matériaux Inorganiques (LC2MI), URCHI/Université des Sciences et Techniques de Masuku (USTM), Franceville, Gabon
2 Laboratoire de Chimie des Milieux et des Matériaux Inorganiques (LC2MI), URCHI/Université des Sciences et Techniques de Masuku (USTM), Franceville, Gabon
3 Département de Chimie, Faculté des Sciences, Université des Sciences et Techniques de Masuku (USTM), Franceville, Gabon
4 Laboratoire de Chimie des Milieux et des Matériaux Inorganiques (LC2MI), URCHI/Université des Sciences et Techniques de Masuku (USTM), Franceville, Gabon
5 Département de Chimie, Faculté des Sciences, Université des Sciences et Techniques de Masuku (USTM), Franceville, Gabon
6 Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), UMR 7285 CNRS/Université de Poitiers, 4 Rue Michel Brunet, Poitiers Cedex, France
7 Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), UMR 7285 CNRS/Université de Poitiers, 4 Rue Michel Brunet, Poitiers Cedex, France
Study of physisorbed and chemisorbed carbon dioxide (CO 2 ) species was carried out on the NaX zeolite modified by cationic exchanges with bivalent cations (Ca 2+ and Ba 2+ ) by temperature-programmed desorption of CO 2 (CO 2 -TPD). Others results were obtained by infrared to complete the study. The results of this research showed, in the physisorption region (213 - 473 K), that the cationic exchanges on NaX zeolite with bivalent cations increase slightly the interactions of CO 2 molecule with adsorbents and/or cationic site. Indeed, the desorption energies of physisorbed CO 2 obtained on the reference zeolite NaX (13.5 kJ·mol -1 ) are lower than that of exchanged zeolites E-CaX and E-BaX (15.77 and 15.17 kJ·mol -1 respectively). In the chemisorbed CO 2 region (573 - 873 K), the desorption energies related to desorbed species (bidentate carbonates: CO 3 2- ) on the exchanged zeolites E-CaX and E-BaX are about 81 kJ·mol -1 , higher than the desorbed species (bicarbonates: HCO 3 2- ) on the reference R-NaX (62 kJ·mol -1 ). In addition, the exchanged E-BaX zeolite develops the secondary adsorption sites corresponding to bicarbonates species with desorption energies of 35 kJ·mol -1 lower to desorption energies of bicarbonates noted on the reference zeolite NaX.
KeywordsAdsorptionFaujasite XChemisorbed and Physisorbed CO<sub>2</sub>Exchanged ZeolitesBivalent CationsTemperature-Programmed Desorption (TPD)Infrared
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