Seasonal and Temporal Variations in Volatile Organic Compounds in Indoor and Outdoor Air in Al-Jahra City, Kuwait — Oak Academic Publishing
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Seasonal and Temporal Variations in Volatile Organic Compounds in Indoor and Outdoor Air in Al-Jahra City, Kuwait
Department of Environmental Health, College of Health Sciences, Public Authority for Applied Education and Training (PAAET), Adailiyah, Kuwait
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Department of Chemical Engineering Technology, College of Technological Studies, Public Authority for Applied Education and Training (PAAET), Adailiyah, Kuwait
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Department of Chemical Engineering Technology, College of Technological Studies, Public Authority for Applied Education and Training (PAAET), Adailiyah, Kuwait
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Department of Chemical Engineering Technology, College of Technological Studies, Public Authority for Applied Education and Training (PAAET), Adailiyah, Kuwait
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Department of Pharmacology and Toxicology, Brody School of Medicine, East Carolina University, Greenville, USA
1 Department of Environmental Health, College of Health Sciences, Public Authority for Applied Education and Training (PAAET), Adailiyah, Kuwait
2 Department of Chemical Engineering Technology, College of Technological Studies, Public Authority for Applied Education and Training (PAAET), Adailiyah, Kuwait
3 Department of Chemical Engineering Technology, College of Technological Studies, Public Authority for Applied Education and Training (PAAET), Adailiyah, Kuwait
4 Department of Chemical Engineering Technology, College of Technological Studies, Public Authority for Applied Education and Training (PAAET), Adailiyah, Kuwait
5 Department of Pharmacology and Toxicology, Brody School of Medicine, East Carolina University, Greenville, USA
Indoor and outdoor air samples were simultaneously collected from the largest office building in Jahra City during 57 sampling events between August 2010 and November 2011. The collected samples were analyzed for 78 volatile organic compounds (VOCs) using CO 2 cryogenic preconcentration and GC/MS analysis. Of the 48 VOCs detected, the toluene concentration exceeded the recommended air quality guidelines in 2% of the outdoor samples, and the benzene concentration exceeded these guidelines in 17.5% and 19.5% of the indoor and outdoor samples, respectively. Industrial and vehicle emissions were negligible. Emissions from oil fields, various crude oil production and flaring activities in the north were major sources of VOCs in the ambient air. The VOC profiles; seasonal, monthly, and weekday/weekend variations; and their effects on ozone formation potentials are discussed. The results indicate that the most abundant class of chemical compounds was oxygenated compounds, of which acetone, acetaldehyde, propanal, methanol, ethanol, and 2-propanol were the most dominant species. Propene and toluene were the most abundant species of aliphatic and aromatic hydrocarbons, respectively.
Public Authority for Civil Information (PACI), Kuwait (2012) http://stat.paci.gov.kw/arabicreports/
Organization of the Petroleum Exporting Countries (OPEC) (2012) World Oil Outlook. http://www.opec.org/opec_web/static_files_project/media/downloads/publications/WOO2012.pdf
AL-Hamad, K. and Khan, A.R. (2008) Total Emissions from Flaring in Kuwait Oilfields. American Journal of Environmental Science, 4, 31-38. http://dx.doi.org/10.3844/ajessp.2008.31.38
Ongwandee, M., Moonrinta, R., Panyametheekul, S., Tangbanluekal, C. and Morrison, G. (2011) Investigation of Volatile Organic Compounds in Office Buildings in Bangkok, Thailand: Concentrations, Sources, and Occupant Symptoms. Building and Environment, 46, 1512-1522. http://dx.doi.org/10.1016/j.buildenv.2011.01.026
Zuraimi, M.S., Roulet, C.A., Tham, K.W., Sekhar, S.C., David Cheong, K.W., Wong, N.H. and Lee, K.H. (2006) A Comparative Study of VOCs in Singapore and European Office Buildings. Building and Environment, 4, 316-329. http://dx.doi.org/10.1016/j.buildenv.2005.01.028
Al-Salem, S.M. and Khan, A.R. (2010) Review: Monitoring and Modelling the Trends of Primary and Secondary Air Pollution Precursor rs: The Case of the State of Kuwait. International Journal of Chemical Engineering, 2010, 1-11. http://dx.doi.org/10.1155/2010/879836
Al-Salem, S.M., Bouhamrah, W.S. (2006) Ambient Concentrations of Benzene and Other VOCs at Typical Industrial Sites in Kuwait and Their Cancer Risk Assessment. Research Journal of Chemistry and Environment, 10(4), 42-46.
Al-Dabbous, A.N., Khan, A.R., Al-Rashidi, M.S. and Awadi, L. (2013) Carbon Dioxide and Volatile Organic Compounds Levels in Mosque in Hot Arid Climate. Indoor and Built Environment, 22, 456-464. http://dx.doi.org/10.1177/1420326X12441807
Alhumoud, J.M., Al-Ruwaih, F.M., Ali, S.H. and Redhaee, M.H. (2012) Traffic Contribution of Volatile Organic Compounds to the Air-Shed of Kuwait. Management of Environmental Quality: An International Journal, 23, 204-221. http://dx.doi.org/10.1108/14777831211204949
Alenezi, R. and Ashfaque, A. (2011) Assessment of Ambient Air Quality in Al Jahra Governorate, for 2008. International Journal of Energy and Environment, 5, 582-591.
Alenezi, R., Al-Anzi, B., Abusam, A. and Ashfaque, A. (2012) Seasonal Influence on the Ambient Air Quality in Al Jahra City for Year 2010. Journal of Environmental Protection, 3, 1711-1718. http://dx.doi.org/10.4236/jep.2012.312186
Al-Mudhaf, H.F., Abu-Shady, A.I., Al-Khulaifi, N.M. and Selim, M.I. (2013) Indoor and Outdoor Volatile Organic Compounds at Office Buildings in Kuwait. Air Soil and Water Research, 6, 53-72. http://dx.doi.org/10.4137/ASWR.S12153
US Environmental Protection Agency (US-EPA) (1994) Standardized EPA Protocol for Characterizing Indoor Air Quality in Large Office Buildings. Washington DC.
US Environmental Protection Agency (US-EPA) (1999) Compendium Method TO-15: Determination of Volatile Organic Compounds (VOCs) in Ambient Air Using Specially Prepared Canisters with Subsequent Analysis by Gas Chromatography. In: Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, 2nd Edition, Washington DC.
European Council (EC) (2000) Directive 2000/69/EC of the European Parliament and of the Council of 16 November 2000 Relating to Limit Values for Benzene and Carbon Monoxide in Ambient Air. Official Journal of the European Communities, 13 December 2000.
World Health Organization (WHO) (2000) Air Quality Guidelines for Europe. European Series. 2nd Edition, WHO Regional Publications, Copenhagen.
Tong, L., Liao, X., Chen, J., Xiao, H., Xu, L., Zhang, F., Niu, Z. and Yu, J. (2013) Pollution Characteristics of Ambient Volatile Organic Compounds (VOCs) in the Southeast Coastal Cities of China. Environmental Science and Pollution Research, 20, 2603-2615. http://dx.doi.org/10.1007/s11356-012-1187-3
Jia, C., Batterman, S. and Godwin, C. (2008) VOCs in Industrial, Urban and Suburban Neighborhoods, Part 2: Factors Affecting Indoor and Outdoor Concentrations. Atmospheric Environment, 42, 2101-2116. http://dx.doi.org/10.1016/j.atmosenv.2007.11.047
Destaillats, H., Maddalena, R.L., Singer, B.C., Hodgson, A.T. and McKone, T.E. (2008) Indoor Pollutants Emitted by Office Equipment: A Review of Reported Data and Information Needs. Atmospheric Environment, 42, 1371-1388. http://dx.doi.org/10.1016/j.atmosenv.2007.10.080
Jia, C., Batterman, S. and Godwin, C. (2007) VOCs in Industrial, Urban and Suburban Neighborhoods, Part 1: Indoor and Outdoor Concentrations, Variation, and Risk Drivers. Atmospheric Environment, 42, 2083-2100. http://dx.doi.org/10.1016/j.atmosenv.2007.11.055
Choi, E., Choi, K. and Seung-Muk, Y. (2011) Non-Methane Hydrocarbons in the Atmosphere of a Metropolitan City and a Background Site in South Korea: Sources and Health Risk Potentials. Atmospheric Environment, 45, 7563-7573. http://dx.doi.org/10.1016/j.atmosenv.2010.11.049
Barletta, B., Meinardi, S., Simpson, I.J., Khwaja, H.A., Blake, D.R. and Rowland, F.S. (2002) Mixing Ratios of Volatile Organic Compounds (VOCs) in the Atmosphere of Karachi, Pakistan. Atmospheric Environment, 36, 3429-3443. http://dx.doi.org/10.1016/S1352-2310(02)00302-3
Saito, S., Nagao, I. and Kanzawa, H. (2009) Characteristics of Ambient C2-C11 Non-Methane Hydrocarbons in Metropolitan Nagoya, Japan. Atmospheric Environment, 43, 4384-4395.
Guo, H., So, K.L., Simpson, I.J., Barletta, B., Meinardi, S. and Blake, D.R. (2007) C1-C8 Volatile Organic Compounds in the Atmosphere of Hong Kong: Overview of Atmospheric Processing and Source Apportionment. Atmospheric Environment, 41, 1456-1472. http://dx.doi.org/10.1016/j.atmosenv.2006.10.011
Hoque, R.R., Khillare, P.S., Agarwal, T., Shridhar, V. and Balachandran, S. (2008) Spatial and Temporal Variation of BTEX in the Urban Atmosphere of Delhi, India. Science of the Total Environment, 392, 30-40. http://dx.doi.org/10.1016/j.scitotenv.2007.08.036
Yurdakul, S., Civan, M. and Tuncel, G. (2013) Volatile Organic Compounds in Suburban Ankara Atmosphere, Turkey: Sources and Variability. Atmospheric Research, 120-121, 298-311. http://dx.doi.org/10.1016/j.atmosres.2012.09.015
Lee, S.C., Chiu, M.Y., Ho, K.F., Zou, S.C. and Wang, X. (2002) Volatile Organic Compounds (VOCs) in Urban Atmosphere of Hong Kong. Chemosphere, 48, 375-382. http://dx.doi.org/10.1016/S0045-6535(02)00040-1
Buczynska, A.J., Krata, A., Stranger, M., Godoi, A.F.L., Kontozova-Deutsch, V., Bencs, L., Naveau, I., Roekens, E. and Grieken, R.V. (2009) Atmospheric BTEX Concentrations in an Area with Intensive Street Traffic. Atmospheric Environment, 43, 311-318. http://dx.doi.org/10.1016/j.atmosenv.2008.09.071
Elbir, T., Cetin, B., Cetin, E., Bayram, A. and Odabasi, M. (2007) Characterization of Volatile Organic Compounds (VOCs) and Their Sources in the Air of Izmir, Turkey. Environmental Monitoring and Assessment, 133, 149-160.
Monod, A., Sive, B.C., Avino, P., Chen, T., Blake, D.R. and Rowland, F.S. (2001) Monoaromatic Compounds in Ambient Air of Various Cities: A Focus on Correlations between the Xylenes and Ethylbenzene. Atmospheric Environment, 35, 135-149. http://dx.doi.org/10.1016/S1352-2310(00)00274-0
Miller, L., Xu, X., Wheeler, A.J., Atari, D.O., Grgicak-Mannion, A. and Luginaah, I. (2011) Spatial Variability and Application of Ratios between BTEX in Two Canadian Cities. The Scientific World Journal, 11, 2536-2549. http://dx.doi.org/10.1100/2011/167973
Moschonas, N. and Glavas, S. (1996) C3-C10 Hydrocarbons in the Atmosphere of Athens, Greece. Atmospheric Environment, 30, 2769-2772. http://dx.doi.org/10.1016/1352-2310(95)00488-2
Harley, R.A., Hannigan, M.P. and Cass, G.R. (1992) Respeciation of Organic Gas Emissions and the Detection of Excess Unburned Gasoline in the Atmosphere. Environmental Science and Technology, 26, 2395-2408. http://dx.doi.org/10.1021/es00036a010
Yuval, A.Z. and Broday, D.M. (2008) Revealing Source Signatures in Ambient BTEX Concentrations. Environmental Pollution, 156, 553-562. http://dx.doi.org/10.1016/j.envpol.2008.01.016
Duan, J., Tan, J., Yang, L., Wu, S. and Hao, J. (2008) Concentration, Sources and Ozone Formation Potential of Volatile Organic Compounds (VOCs) during Ozone Episode in Beijing. Atmospheric Research, 88, 25-35. http://dx.doi.org/10.1016/j.atmosres.2007.09.004
Sosa, E.R., Bravo, A.H., Mugica, A.V., Sanchez, A.P., Bueno, L.E. and Krupa, S. (2009) Levels and Source Apportionment of Volatile Organic Compounds in Southwestern Area of Mexico City. Environmental Pollution, 157, 1038-1044. http://dx.doi.org/10.1016/j.envpol.2008.09.051
Sarkhosh, M., Mahvi, A.H., Yunesian, M., Nabizadeh, R., Borji, S.H. and Bajgirani, A.G. (2013) Source Apportionment of Volatile Organic Compounds in Tehran, Iran. Bulletin of Environmental Contamination and Toxicology, 90, 440-445. http://dx.doi.org/10.1007/s00128-012-0948-5
Leuchner, M. and Rappenglück, B. (2010) VOC Source-Receptor Relationships in Houston during TexAQS-II. Atmospheric Environment, 44, 4056-4067. http://dx.doi.org/10.1016/j.atmosenv.2009.02.029
Tassi, F., Capecchiacci, F., Giannini, L., Vougioukalakis, G.E. and Vaselli, O. (2013) Volatile Organic Compounds (VOCs) in Air from Nisyros Island (Dodecanese Archipelago, Greece): Natural versus Anthropogenic Sources. Environmental Pollution, 180, 111-121. http://dx.doi.org/10.1016/j.envpol.2013.05.023
Civan, M.Y., Kuntasal, O.O. and Tuncel, G. (2011) Source Apportionment of Ambient Volatile Organic Compounds in Bursa, a Heavily Industrialized City in Turkey. Environmental Forensics, 12, 357-370. http://dx.doi.org/10.1080/15275922.2011.622345
Zhang, J., Sun, Y., Wu, F., Sun, J. and Wang, Y. (2013) The Characteristics, Seasonal Variation and Source Apportionment of VOCs at Gongga Mountain, China. Atmospheric Environment, in Press. http://dx.doi.org/10.1016/j.atmosenv.2013.03.036
Ho, K.F., Lee, S.C., Guo, H. and Tsai, W.Y. (2004) Seasonal and Diurnal Variations of Volatile Organic Compounds (VOCs) in the Atmosphere of Hong Kong. Science of the Total Environment, 322, 155-166. http://dx.doi.org/10.1016/j.scitotenv.2003.10.004
Parra, M.A., González, L., Elustondo, D., Garrigó, J., Bermejo, R. and Santamaría, J.M. (2006) Spatial and Temporal Trends of Volatile Organic Compounds (VOC) in a Rural Area of Northern Spain. Science of the Total Environment, 370, 157-167. http://dx.doi.org/10.1016/j.scitotenv.2006.06.022
Moussa, S.G., El-Fadel, M. and Saliba, N.A. (2006) Seasonal, Diurnal and Nocturnal Behaviors of Lower Carbonyl Compounds in the Urban Environment of Beirut, Lebanon. Atmospheric Environment, 40, 2459-2468. http://dx.doi.org/10.1016/j.atmosenv.2005.12.031
Pang, X. and Mu, Y. (2006) Seasonal and Diurnal Variations of Carbonyl Compounds in Beijing Ambient Air. Atmospheric Environment, 40, 6313-6320. http://dx.doi.org/10.1016/j.atmosenv.2006.05.044
Cai, C., Geng, F., Tie, X., Yu, Q. and An, J. (2010) Characteristics and Source Apportionment of VOCs Measured in Shanghai, China. Atmospheric Environment, 44, 5005-5014. http://dx.doi.org/10.1016/j.atmosenv.2010.07.059
Parra, M.A., Elustondo, D., Bermejo, R. and Santamaria, J.M. (2009) Ambient Air Levels of Volatile Organic Compounds (VOC) and Nitrogen Dioxide (NO2) in a Medium Size City in Northern Spain. Science of the Total Environment, 407, 999-1009. http://dx.doi.org/10.1016/j.scitotenv.2008.10.032
Vardoulakis, S., Solazzo, E. and Lumbreras, J. (2011) Intra-Urban and Street Scale Variability of BTEX, NO2 and O3 in Birmingham, UK: Implications for Exposure Assessment. Atmospheric Environment, 45, 5069-5078. http://dx.doi.org/10.1016/j.atmosenv.2011.06.038
Suthawaree, J., Tajima, Y., Khunchornyakong, A., Kato, S., Sharp, A. and Kajii, Y. (2012) Identification of Volatile Organic Compounds in Suburban Bangkok, Thailand and Their Potential for Ozone Formation. Atmospheric Research, 104-105, 245-254. http://dx.doi.org/10.1016/j.atmosres.2011.10.019
Shan, W., Yin, Y., Zhang, J. and Ding, Y. (2008) Observational Study of Surface Ozone at an Urban Site in East China. Atmospheric Research, 89, 252-261. http://dx.doi.org/10.1016/j.atmosres.2008.02.014
Yuan, B., Shao, M., Lu, S. and Wang, B. (2010) Source Profiles of Volatile Organic Compounds Associated with Solvent Use in Beijing, China. Atmospheric Environment, 44, 1919-1926. http://dx.doi.org/10.1016/j.atmosenv.2010.02.014
Gouw, J. and Warneke, C. (2007) Measurements of Volatile Organic Compounds in the Earth’s Atmosphere Using Proton-Transfer-Reaction Mass Spectrometry. Mass Spectrometry Reviews, 26, 223-257. http://dx.doi.org/10.1002/mas.20119
Filella, I. and Penuelas, J. (2006) Daily, Weekly, and Seasonal Time Courses of VOC Concentrations in a Semi-Urban Area near Barcelona. Atmospheric Environment, 40, 7752-7769. http://dx.doi.org/10.1016/j.atmosenv.2006.08.002
Carter, W.P.L. (2010) Development of the SAPRC-07 Chemical Mechanism. Atmospheric Environment, 44, 5324-5335. http://dx.doi.org/10.1016/j.atmosenv.2010.01.026
Tiwari, V., Hanai, Y. and Masunaga, S. (2010) Ambient Levels of Volatile Organic Compounds in the Vicinity of Petrochemical Industrial Area of Yokohama, Japan. Air Quality, Atmosphere and Health, 3, 65-75. http://dx.doi.org/10.1007/s11869-009-0052-0