<i>Origanum majorana</i> Extracts as Mild Steel Corrosion Green Inhibitors in Aqueous Chloride Medium — Oak Academic Publishing
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<i>Origanum majorana</i> Extracts as Mild Steel Corrosion Green Inhibitors in Aqueous Chloride Medium
Tunis El Manar University, Institut Préparatoire aux Etudes d’Ingénieurs El Manar, Campus Universitaire El Manar, Tunis, Tunisia
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Tunis El Manar University, Institut Préparatoire aux Etudes d’Ingénieurs El Manar, Campus Universitaire El Manar, Tunis, Tunisia
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Carthage University, Institut Préparatoire aux Etudes Scientifiques & Techniques, Laboratoire de Recherche “Matériaux, Molécules et Applications”, La Marsa, Tunisia
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Carthage University, Faculté des Sciences de Bizerte, Laboratoire de Recherche “Application de la Chimie aux Ressources et Substances Naturelles et à l’Environnement”, Jarzouna, Tunisia
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Carthage University, Faculté des Sciences de Bizerte, Laboratoire de Physique des Matériaux, Jarzouna, Tunisia
1 Tunis El Manar University, Institut Préparatoire aux Etudes d’Ingénieurs El Manar, Campus Universitaire El Manar, Tunis, Tunisia
2 Tunis El Manar University, Institut Préparatoire aux Etudes d’Ingénieurs El Manar, Campus Universitaire El Manar, Tunis, Tunisia
3 Carthage University, Institut Préparatoire aux Etudes Scientifiques & Techniques, Laboratoire de Recherche “Matériaux, Molécules et Applications”, La Marsa, Tunisia
4 Carthage University, Faculté des Sciences de Bizerte, Laboratoire de Recherche “Application de la Chimie aux Ressources et Substances Naturelles et à l’Environnement”, Jarzouna, Tunisia
5 Carthage University, Faculté des Sciences de Bizerte, Laboratoire de Physique des Matériaux, Jarzouna, Tunisia
We optimized Origanum majorana (OM) extraction for mild steel corrosion inhibition in neutral 0.5 M chloride medium. The inhibition mechanism evolved in presence of the optimal extract was discussed when calculating the activation energy (Ea), the activation enthalpy ( Δ a H) as well as the activation entropy ( Δ a S). The OM extract molecules were investigated using the density functional theory (DFT) at B3LYP/6-31G(d,p) basis set level. 1-methyl-4-propan-2-ylcyclohexa-1,3-diene alpha-terpinene was predicted exhibiting the most inhibition capabilities.
Blin, F., Koutsoukos, P., Klepetsianis, P. and Forsyth M. (2007) The Corrosion Inhibition Mechanism of New Rare Earth Cinnamate Compounds—Electrochemical Studies. Electrochimica Acta, 52, 6212-6220. http://dx.doi.org/10.1016/j.electacta.2007.04.001
Yasakau, K.A., Zheludkevich, M.L., Lamaka, S.V. and Ferreira, M.G.S. (2006) Mechanism of Corrosion Inhibition of AA2024 by Rare-Earth Compounds. Journal of Physical Chemistry B, 110, 5515-5528. http://dx.doi.org/10.1021/jp0560664
Amin, M.A., Hassan, H.H. and Abd El Rehim, S.S. (2008) On the Role of Ions in Passivity Breakdown of Zn in Deaerated Neutral Sodium Nitrite Solutions and the Effect of Some Inorganic Inhibitors Potentiodynamic Polarization, Cyclic Voltammetry, SEM and EDX Studies. Electrochimica Acta, 53, 2600-2609. http://dx.doi.org/10.1016/j.electacta.2007.10.034
Abiola, O.K. and James, A.O. (2010) The Effects of Aloe vera Extract on Corrosion and Kinetics of Corrosion Process of Zinc in HCl Solution. Corrosion Science, 52, 661-664. http://dx.doi.org/10.1016/j.corsci.2009.10.026
Quraishi, M.A., Singh, A., Singh, V.K., Yadav, D.K. and Singh, A.K. (2010) Green Approach to Corrosion Inhibition of Mild Steel in Hydrochloric Acid and Sulphuric Acid Solutions by the Extract of Murraya koenigii Leaves. Materials Chemistry and Physics, 122, 114-122. http://dx.doi.org/10.1016/j.matchemphys.2010.02.066
Hamed, E. (2010) Studies of the Corrosion Inhibition of Copper in Na2SO4 Solution Using Polarization and Electrochemical Impedance Spectroscopy. Materials Chemistry and Physics, 121, 70-76. http://dx.doi.org/10.1016/j.matchemphys.2009.12.044
Lebrini, M., Robert, F., Lecante, A. and Roos, C. (2011) Corrosion Inhibition of C38 Steel in 1 M Hydrochloric Acid Medium by Alkaloids Extract from Oxandra asbeckii Plant. Corrosion Science, 53, 687-695. http://dx.doi.org/10.1016/j.corsci.2010.10.006
Hussin, M.H. and Kassim, M.J. (2011) The Corrosion Inhibition and Adsorption Behavior of Uncaria gambir Extract on Mild Steel in 1 M HCl. Materials Chemistry and Physics, 125, 461-468. http://dx.doi.org/10.1016/j.matchemphys.2010.10.032
Al-Turkustani, A.M., Arab, S.T. and Al-Qarni, L.S.S. (2011) Medicago sative Plant as Safe Inhibitor on the Corrosion of Steel in 2.0 M H2SO4. Journal of Saudi Chemical Society, 15, 73-82. http://dx.doi.org/10.1016/j.jscs.2010.10.008
Deng, S. and Li, X. (2012) Inhibition by Ginkgo Leaves Extract of the Corrosion of Steel in HCl and H2SO4 Solutions. Corrosion Science, 55, 407-415. http://dx.doi.org/10.1016/j.corsci.2011.11.005
Behpour, M., Ghoreishi, S.M., Khayatkashani, M. and Soltani, N. (2012) Green Approach to Corrosion Inhibition of Mild Steel in Two Acidic Solutions by the Extract of Punica granatum Peel and Main Constituents. Materials Chemistry and Physics, 131, 621-633. http://dx.doi.org/10.1016/j.matchemphys.2011.10.027
Al-Otaibi, M.S, Al-Mayouf, A.M., Khan, A., Mousa, A.A., Al-Mazroa, S.A. and Alkhathlan, H.Z. (2014) Corrosion Inhibitory Action of Some Plant Extracts on the Corrosion of Mild Steel in Acidic Media. Arabian Journal of Chemistry, 7, 340-346. http://dx.doi.org/10.1016/j.arabjc.2012.01.015
Souissi, N. and Triki, E. (2007) A Chemiometric Approach for Phosphate Inhibition of Copper Corrosion in Aqueous Media. Journal of Materials Science, 42, 3259-3265. http://dx.doi.org/10.1007/s10853-006-0809-x
Souissi, N. and Triki, E. (2008) Modelling of Phosphate Inhibition of Copper Corrosion in Aqueous Chloride and Sulphate Media. Corrosion Science, 50, 231-241. http://dx.doi.org/10.1016/j.corsci.2007.06.022
Abdel-Gaber, A.M., Khamis, E. and Hefnawy, A. (2011) Utilizing Arghel Extract as Corrosion Inhibitor for Reinforced Steel in Concrete. Materials and Corrosion, 62, 1159-1162. http://dx.doi.org/10.1002/maco.201005653
Kear, G., Barker, B.D. and Walsh, F.C. (2004) Electrochemical Corrosion of Unalloyed Copper in Chloride Media—A Critical Review. Corrosion Science, 46, 109-135. http://dx.doi.org/10.1016/S0010-938X(02)00257-3
Labjar, N., Bentiss, F., Lebrini, M., Jama, C. and El hajjaji, S. (2011) Study of Temperature Effect on the Corrosion Inhibition of C38 Carbon Steel Using Amino Tris(Methylenephosphonic) Acid in Hydrochloric Acid Solution. International Journal of Corrosion, 2011, Article ID: 548528. http://dx.doi.org/10.1155/2011/548528
Mayakrishnan, G., Pitchai, S., Raman, K., Ramani Vincent, A. and Nagarajan, S. (2011) Inhibitive Action of Clematis gouriana Extract on the Corrosion of Mild Steel in Acidic Medium. Ionics, 17, 843-852. http://dx.doi.org/10.1007/s11581-011-0584-9
Eduok, U.M., Umoren, S.A. and Udoh, A.P. (2012) Synergistic Inhibition Effects between Leaves and Stem Extracts of Sida acuta and Iodide Ion for Mild Steel Corrosion in 1 M H2SO4 Solutions. Arabian Journal of Chemistry, 5, 325- 337. http://dx.doi.org/10.1016/j.arabjc.2010.09.006
Singh, A., Singh, V.K. and Quraishi, M.A. (2010) Effect of Fruit Extracts of Some Environmentally Benign Green Corrosion Inhibitors on Corrosion of Mild Steel in Hydrochloric Acid Solution. Journal of Materials and Environmental Science, 1, 162-147.
Nofrizal, S., Rahim, A.A., Saad, B., Bothi Raja, P., Shah, A.M. and Yahya, S. (2012) Elucidation of the Corrosion Inhibition of Mild Steel in 1 M HCl by Catechin Monomers from Commercial Green Tea Extracts. Metallurgical and Materials Transactions, 43, 1382-1393. http://dx.doi.org/10.1007/s11661-011-1030-3
El Ashry, H.E., El Nemr, A., Esawy, S.A. and Ragab, S. (2006) Corrosion Inhibitors: Part II: Quantum Chemical Studies on the Corrosion Inhibitions of Steel in Acidic Medium by Some Triazole, Oxadiazole and Thiadiazole Derivatives. Electrochimica Acta, 51, 3957-3968. http://dx.doi.org/10.1016/j.electacta.2005.11.010
Kabanda, M.M., Murulana, L.C., Ozcan, M., Karadag, F., Dehri, I., Obot, I.B. and Ebenso, E.E. (2012) Quantum Chemical Studies on the Corrosion Inhibition of Mild Steel by Some Triazoles and Benzimidazole Derivatives in Acidic Medium. International Journal of Electrochemical Science, 7, 5035-5056.
Obot, I.B., Obi-Egbedi, N.O. and Umoren, S.A. (2010) Adsorption Characteristics and Corrosion Inhibitive Properties of Clotrimazole for Aluminium Corrosion in Hydrochloric Acid. International Journal of Electrochemical Science, 4, 863-877.
Khalil, N. (2003) Quantum Chemical Approach of Corrosion Inhibition. Electrochimica Acta, 48, 2635-2640. http://dx.doi.org/10.1016/S0013-4686(03)00307-4
Parr, R.G. and Pearson, R.G. (1983) Absolute Hardness: Companion Parameter to Absolute Electronegativity. Journal of the American Chemical Society, 105, 7512-7516. http://dx.doi.org/10.1021/ja00364a005
Pearson, R.G. (1988) Absolute Electronegativity and Hardness: Application to Inorganic Chemistry. Inorganic Chemistry, 27, 734-740. http://dx.doi.org/10.1021/ic00277a030
Geerlings, P. and De Proft, F. (2002) Chemical Reactivity as Described by Quantum Chemical Methods. International Journal of Molecular Sciences, 3, 276-309. http://dx.doi.org/10.3390/i3040276
Yang, W. and Parr, R.G. (1985) Hardness, Softness and the Fukui Function in the Electronic Theory of Metals and Catalysis. Proceedings of the National Academy of Sciences of the United States of America, 82, 6723-6726. http://dx.doi.org/10.1073/pnas.82.20.6723
Lukovits, I., Kalman, E. and Zucchi, F. (2011) Corrosion Inhibitors—Correlation between Electronic Structure and Efficiency. Corrosion, 57, 3-8. http://dx.doi.org/10.5006/1.3290328