Studying the Effect of Different Gas-Phase Chemical Kinetic Mechanisms on the Formation of Oxidants, Nitrogen Compounds and Ozone in Arid Regions — Oak Academic Publishing
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Studying the Effect of Different Gas-Phase Chemical Kinetic Mechanisms on the Formation of Oxidants, Nitrogen Compounds and Ozone in Arid Regions
Schulich School of Engineering, University of Calgary, Calgary, AB, Canada
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Faculty of Engineering and Applied Science, Memorial Universityof Newfoundland, St. John’s, NL, Canada
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King Abdulaziz City for Science and Technology, Riyadh, Saudi Arabia
1 Schulich School of Engineering, University of Calgary, Calgary, AB, Canada
2 Faculty of Engineering and Applied Science, Memorial Universityof Newfoundland, St. John’s, NL, Canada
3 King Abdulaziz City for Science and Technology, Riyadh, Saudi Arabia
CMAQ was implemented in the central region of Saudi Arabia and the effect of simulating models using various chemical mechanisms on selected oxidants, nitrogen species, and O 3 was investigated. CB05TUCL predicted OH, MEPX, and NO z about 7%, 7.7%, and 8% more than CB05E51 respectively; however, there was no observable difference in the O 3 predictions. The differences in variations of SAPRC07 mechanism (SAPRC07TB, SAPRC07TC, and SAPRC07TIC) for all parameters were less than 1%. RACM2 produced the highest OH and H 2 O 2 concentrations. RACM2 enhanced OH production in the range of 24% - 32% and H 2 O 2 by 9% over other mechanisms; these are comparatively less than the findings of other studies. Similarly, CB05 produced over 40% more PAN concentration than CB05. Moreover, PAN concentrations produced by all mechanisms were very high compared to other studies. SAPRC07 produced approximately 3% more mean surface O 3 concentration than RACM2 and approximately 10% more than CB05. RACM2 O 3 predictions were higher than CB05 by 7%. The predicted O 3 concentrations by CB05, RACM2, and SAPRC07 were 6%, 11%, and 15% more than the average observed concentrations, which indicate that closest predictions to the observed values were by CB05. This study concludes that there is a wide variation of mechanisms with respect to the predictions of oxidants and nitrogen compounds; however, less variation is noticed in predictions of O 3 . For any air pollution control strategies and photochemical modeling studies in the current region or in any other arid regions, the CB05 mechanism is recommended.
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