Preparation, Characterization, and Application of Manganese Oxide Coated Zeolite as Adsorbent for Removal of Copper(II) Ions from Seawater — Oak Academic Publishing
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Preparation, Characterization, and Application of Manganese Oxide Coated Zeolite as Adsorbent for Removal of Copper(II) Ions from Seawater
National Institute of Oceanography and Fisheries, Alexandria, Egypt
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National Institute of Oceanography and Fisheries, Alexandria, Egypt
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ChemistryDepartment, Faculty of Science, University of Jeddah, Jeddah, KSA
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Chemistry Department, Faculty of Science, Alexandria University, Alexandria, Egypt
1 National Institute of Oceanography and Fisheries, Alexandria, Egypt
2 National Institute of Oceanography and Fisheries, Alexandria, Egypt
3 ChemistryDepartment, Faculty of Science, University of Jeddah, Jeddah, KSA
4 Chemistry Department, Faculty of Science, Alexandria University, Alexandria, Egypt
The present study is aimed to examine the adsorption characteristics of Cu(II) by using the novel cellulose acetate composite and to apply it for the removal of Cu(II) from real wastewater samples. In order to achieve this objective, ethylenediamine, diethylenetriamine, triethylenetetramine and te-traethylenepentanene were used for immobilization of grafted cellulose acetate-nanoscale manganese dioxide. Cellulose was extracted from mangrove species Avicennia marina and converted to cellulose acetate then it was formed composite with nano-manganese dioxide via precipitation of nano-manganese dioxide on it. The composite was grafted with acrylamide monomer before immobilization. The synthesized compounds were used for adsorption of Cu(II) and characterized by FT-IR, TGA and SEM. The adsorption characteristics of synthesized sorbents were optimized. Langmuir and Freundlich models were used to establish sorption equilibria. The analytical applications of these modified materials were applied successfully for the removal of Cu(II).
KeywordsManganese Oxide Coated ZeoliteRemoval of Copper(II) IonsSeawater
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