Melt Infiltration Casting Of Zr<sub>57</sub>Al<sub>10</sub>Nb<sub>5</sub>Cu<sub>15.4</sub>Ni<sub>12.6</sub> Amorphous Matrix Composite
- 1 School of Materials Science and Engineering, Shenyang University of Technology,58 South Xinghua Street, Shenyang 110023, China.
- 2 School of Materials Science and Engineering, Shenyang University of Technology,58 South Xinghua Street, Shenyang 110023, China.
Abstract
The Zr 57 Al 10 Nb 5 Cu 15.4 Ni 12.6 bulk metallic glass-forming alloy is reinforced with tungsten fiber. Cylindrical samples up to 6.3 mm in diameter and 7cm in length have been synthesized using melt infiltration casting method. The structure and microstructure of the composites processed in typical conditions were analyzed by x-ray diffraction and scanning electron microscopy. The suitable interface reaction and fully amorphous matrix can only be obtained through the combination of a suitable infiltration temperature and time. The processing conditions were more rigorous compared to those of making Zr-Ti-Ni-Cu-Be matrix composite due to intermetallic compound nucleation when exposed to the tungsten fibers. A technique map, including infiltrating temperature and time is presented in this paper.
- Inoue, A., Zhang, T., Nishiyama, N., Ohba, K., and Matsuda, T., 1993,“Preparation of 16mm Diameter Rod of Amorphous Zr 65 Al 7.5 Ni 10 Cu 17.5 Alloy”. Materials Transactions JIM. Vol. 34, No.12, pp.1234-1237.
- Inoue, A., and Zhang, T., 1996, “Fabrication of Bulk Glass Zr 55 Al 10 Ni 5 Cu 30 Alloy of 30mm in Diameter by Suction Casting Method”. Materials Transactions JIM. Vol. 37, No.2, pp.185-187.
- Peker, A., and Johnson, W. L., 1993, “A Highly Processable Metallic Glass: Zr 41.25 Ti 13.75 Ni 10 Cu 12.5 Be 22.5 ”. Applied Physics Letters. Vol. 63, No. 17, pp.2342-2344.
- Choi-Yim, H., Conner, R. D, Szuecs, F., and Johnson, W. L., 2001, “Quasistatic and Dynamic Deformation of Tungsten Reinforced Zr 57 Al 10 Nb 5 Cu 15.4 Ni 12.6 Bulk Metallic Glass Matrix Composites”. Scripta Materialia. Vol.45, pp.1039-1045.
- Gilbert, C. J., Schroeder, V., and Ritchie, R. O., 1999, “Mechanisms for Fracture and Fatigue-Crack Propagation in a Bulk Metallic Glass”. Metallurgical & Materials Transactions A: Vol. 30, pp.1739-1754.
- Pang, S. J., Zhang, T., Kimura, H., Asami, K., and Inoue, A., 2000, “Corrosion Behavior of Zr-(Nb-)Al-Ni-Cu Glass Alloys”. Materials Transactions JIM. Vol. 41, No. 11, pp.1495-1500.
- Dandliker, R. B., Conner, R. D., and Johnson, W. L., 1998, “Melt Infiltration Casting of Bulk Metallis-Glass Matrix Composites”. Journal of Materials Research. Vol. 13, No. 10, pp.2896-2901.
- Choi-Yim, H., Conner, R. D., and Johnson, W. L., 2002, “Processing, Microstructure and Properties of Ductile Metal Particulate Reinforced Zr 57 Al 10 Nb 5 Cu 15.4 Ni 12.6 Bulk Metallic Glass Composites”. Acta Materialia. Vol. 50, No.10, pp.2737-2745.
- Hufnagel, T. C., Fan, C., Ott R, T., Li, J., and Brennah, S., 2002, “Controlling Shear Band Behavior in Metallic Glasses Through Microstructure Design”. Intermetallics. Vol. 10, pp.1163-1166.
- Conner, R. D., Dandliker, R. B., and Johnson, W. L., 1998, “Mechanical Properties of Tungsten and Steel Fiber Reinforced Zr 41.25 Ti 13.75 Cu 12.5 Ni 10 Be 22.5 Metallic Glass Matrix Composites”. Acta Materialia. Vol. 46, No.17. pp.6089-6102.
- Hirano, T., Kato, H., Matsuo, A., Kawamura, Y., and Inoue, A., 2000, “Synthesis and Mechanical Properties of Zr 55 Al 10 Ni 5 Cu 30 Bulk Metallic Glass Composites Containing ZrC Particles Formed by the In-Situ Reaction”. Materials Transactions JIM. Vol. 41, No.11, pp1454-1459.
- Choi-Yim, H., Busch, R., and Johnson, W. L., 1998, “The Effect of Silicon on the Glass Forming Ability of the Cu 47 Ti 34 Zr 11 Ni 8 Bulk Metallic Alloy During Processing of Composites”. Journal of Applied Physics. Vol. 83, No. 12, pp.7993-7997