Corrosion Behavior of Fe-Al-Zn Interphased Dual Phase Steel in Marine Environment
- 1 Department of Metallurgical and Materials Engineering, Kogi State Polytechnic, Lokoja, Nigeria
- 2 Department of Metallurgical and Materials Engineering, Kogi State Polytechnic, Lokoja, Nigeria
Abstract
Intercritical heat treatment operation has been in use for the development of Dual Phase Steel (DPS) and has been found to improve the mechanical properties of the steel. In spite of the enhancement a limitation was however observed as to its corrosion susceptibility. In a bid to further enhance the corrosion resistance of the DPS while maintaining its mechanical properties, galvanealing operation was adopted which involving the immersion of the DPS into Al-Zn melt and subsequently subjecting it to annealing operation at 550 ° C. Weight loss and linear polarization technique were used to measure or evaluate its resistance in 3.5% NaCl (a simulated marine environment). A minimum of 3 samples was used per immersion time. From the result, it was observed that there is a general sharp decrease in the corrosion rate of the GAS as compared to the control sample. The sample immersed and allowed to dwell in the melt for 20 seconds and further annealed with a soaking time of 20 minutes exhibited the highest corrosion resistance. The polarization curve also shows that the substrate was generally passivated, and this is as a result of the Al-Zn/Fe adhesiveness.
- Alaneme, K.K. (2010) Influence of Tempered Microstructures on the Transformation Behaviour of Cold Deformed and Intercritically Annealed Medium Carbon Low Alloy Steel. Materials Research, 13, 203-209. https://doi.org/10.1590/S1516-14392010000200014
- Alaneme, K.K., Adejumo, O.J. and Borode, J.O. (2013) Influence of Different Cyclic Intercritical Heat Treatment Schedules on the Microstructure and Mechanical Behaviour of a Dual Phase Medium Carbon Low Alloy Steel. Association of Metallurgical Engineers of Serbia, Metallurgical and Materials Engineering, 19, 155-165.
- Dongsheng, L., Matthias, M. and Warren, P. (2007) Microstructure Model for a Dual-Phase Steel. Material Science Forum, 539-543, 4391-4396. https://doi.org/10.4028/www.scientific.net/MSF.539-543.4391
- Hambidge, K.M. and Krebs, N.F. (2007) Zinc Deficiency: A Special Challenge. Journal of Nutrition, 137, 1101-1105. https://doi.org/10.1093/jn/137.4.1101
- Holm, E.A., Miodownik, M.A. and Rollet, A.D. (2003) On Abnormal Subgrain Growth and the Origin of Recrystallization Nuclei. Acta Materialia, 51, 2701-2716. https://doi.org/10.1016/S1359-6454(03)00079-X
- Kato, T., Nunome, K., Morimoto, Y., Nishimura, K. and Saka, H. (2000) In-Situ High-Voltage Electron Microscopy Observation of Reactions between Molten Zn and Fe. Philosophical Magazine Letters, 80, 54-57. https://doi.org/10.1080/095008300176146
- Long, J.M., Haynes, D.A. and Hodgson, P.D. (2004) Characterization of Galvanneal Coating on Strip Steel. Materials Forum, 27, 62-67.
- Momoh, I.M. (2012) Microstructures, Corrosion and Mechanical Behavior of Dual Phase Medium Carbon Low Allow Steels. MSc Thesis, Department of Metallurgical and Materials Engineering, The Federal University of Technology, Akure, Nigeria. 1-5.
- Sepper, S., Peetsalu, P. and Saarna, M. (2011) Methods for Evaluating the Appearance of Hot Dip Galvanized Coatings. Agronomy Research, 9, 229-236.
- Reumont, G., Vogt, J.B., Iost, A. and Foct, J. (2001) The Effects of an Fe-Zn Intermetallic-Containing Coating on the Stress Corrosion Cracking Behavior of a Hot-Dip Galvanized Steel. Surface and Coatings Technology, 139, 265-271. https://doi.org/10.1016/S0257-8972(01)01017-9
- Yang, J.R. and Chen, L. (1991) Dual Ferrite-Martensite Treatment of a High Strength Low Alloy ASTM A588 Steel. Material Science, 26, 889-898. https://doi.org/10.1007/BF00576764
- Zeytin, H.K., Kubilay, C. and Aydin, H. (2008) Investigation of Dual Phase Transformation of Commercial Low Alloy Steels: Effect of Holding Time at Low Intercritical Annealing Temperatures. Materials Letters, 62, 2651-2653. https://doi.org/10.1016/j.matlet.2008.01.037