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Time-of-Flight Mass Spectrometry of Highly Ordered Carbyne
Faculty of Physics, Moscow State University, Moscow, Russia
- 1 Faculty of Physics, Moscow State University, Moscow, Russia
Journal of Modern Physics·Volume 03 (2012)·Pages 895–901·Published 24 September 2012·DOI10.4236/jmp.2012.39117
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Abstract
Matrix-assisted laser desorption/ionization (MALDI) time-of-flight mass spectrometry was applied to a non-conven-tional object–highly ordered carbyne films. Mass spectra of both positive and negative ions were recorded in all tests. The spectra had a rather high number of hydrogen atom peaks and specific features indicative of hydrogen acting as a requisite stabilizer in the crystalline carbyne structure. A new model based on interchain dihydrogen bonds was proposed.
KeywordsCarbyneMALDIDihydrogen Bonds
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