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Lattice Enthalpy Drives Hubbard U to Zero
Department of Chemistry, Chalmers, Sweden
- 1 Department of Chemistry, Chalmers, Sweden
Journal of Modern Physics·Volume 04 (2013)·Pages 29–32·Published 25 June 2013·DOI10.4236/jmp.2013.46A007
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Abstract
In the equation U = I – A for the Mott energy, the electron-hole interaction of the successor state is missing. Adding the attractive term, the energy for disproportionation (Hubbard U ), may adopt any sign. The missing term is related to the Born effect, the Madelung correction and the Lattice Enthalpy.
KeywordsHubbard ULattice EnthalpySuperconductivityCorrelationDisproportionation
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