The Fractal (BSf) Kinetics Equation and Its Approximations
- 1 Department of Chemical Engineering, Liege University, Liege, Belgium
Abstract
We discuss the Brouers-Sotolongo fractal (BSf) kinetics model. This formalism interpolates between the first and second order kinetics. But more importantly, it introduces not only a fractional order n but also a fractal time parameter a which characterizes the time variation of the rate constant. This exponent appears in non-exponential relaxation and complex reaction models as demonstrated by the extended use of the Weibull and Hill kinetics which are the two most popular approximations of the BSf ( n , a ) kinetic equation as well in non-Debye relaxation formulas. We show that the use of nonlinear programs allows an easy and precise fitting of the data yielding the BSf parameters which have simple physical interpretations.
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