Study of Optical and Electrical Properties of Nickel Oxide (NiO) Thin Films Deposited by Using a Spray Pyrolysis Technique
- 1 Department of Physics, College of Science, University of Thi-Qar, Thi-Qar, Iraq
Abstract
Nickel oxide (NiO) thin film has been deposited on a glass substrate at a temperature of 390°C ± 10°C using a simple and inexpensive spray pyrolysis technique. Nickel nitrate salt solution (Ni(NO 3 ) 2 · 6H 2 O) was employed to prepare the films and the film thickness was in order of 200 ± 5 nm. The structural, optical and electrical properties of NiO films were investigated using X-ray diffraction (XRD), visible spectrum, DC conductivity and Seebeck effect measurements. The results show that X-ray diffraction techniques have shown that prepared film is polycrystalline structure type cubic phase. The measurements of optical properties (transmittance ( T ) and absorbance ( A )) of NiO films show that higher transmittance is 37.4% within the wavelength range (300 - 900 nm). Also the results have shown that the higher absorbance is 77.7%. The results of electrical properties have shown that at room temperature electrical conductivity is 1.3 × 10 -5 (Ω · cm) -1 , and also results have shown that all the films are of p-type due to the negative Seebeck coefficient.
- Fujii, E., Tomozawa, A., Torii, H. and Takayama, R. (1996) Japanese Journal of Applied Physics, 35, L328. http://dx.doi.org/10.1143/JJAP.35.L328
- Sato, H., Minami, T., Takata, S. and Yamada, T. (1993) Thin Solid Films, 236, 27. http://dx.doi.org/10.1016/0040-6090(93)90636-4
- Sasi, B., Gopchandran, K.G., Manoj, P.K., Koshy, P., Prabhakara Rao, P. and Vaidyan, V.K. (2003) Vacuum, 68, 149. http://dx.doi.org/10.1016/S0042-207X(02)00299-3
- Roslik, A.K., Konev, V.N. and Maltsev, A.M. (1995) Oxidation of Metals, 43, 1. http://dx.doi.org/10.1007/BF01046745
- Ahn, K.S., Nah, Y.C. and Sung, Y.E. (2002) Applied Surface Science, 199, 259. http://dx.doi.org/10.1016/S0169-4332(02)00863-2
- Chen, X., Wu, N.J., Smith, L. and Ignatiev, A. (2004) Applied Physical Letters, 84, 2700. http://dx.doi.org/10.1063/1.1697623
- Fasaki, I., Giannoudakos, A., Stamataki, M., Kompitsas, M., Gyorgy, E., Mihailescu, I.N., Roubani-Kalantzopoulou, F., Lagoyannis, A. and Harissopulos, S. (2008) Applied Physics A, 91, 487. http://dx.doi.org/10.1007/s00339-008-4435-0
- Sasi, B., Gopchandran, K., Manoj, P., Koshy, P., Rao, P. and Vaidyan, V.K. (2003) Vacuum, 68, 149-154. http://dx.doi.org/10.1016/S0042-207X(02)00299-3
- Desai, J.D., Min, S.K., Jung, K.D. and Joo, O.S. (2006) Applied Surface Science, 253, 1781-1786. http://dx.doi.org/10.1016/j.apsusc.2006.03.009
- Kang, J.-K. and Rhee, S.W. (2001) Thin Solid Films, 391, 57-61. http://dx.doi.org/10.1016/S0040-6090(01)00962-2
- Nakaoka, K., Ueyama, J. and Ogura, K. (2004) Journal of Electroanalytical Chemistry, 571, 93-99. http://dx.doi.org/10.1016/j.jelechem.2004.05.003
- Taylor, D.J., Fleig, P.F., Schwab, S.T. and Page, R.A. (1999) Surface and Coatings Technology, 120-121, 465-469. http://dx.doi.org/10.1016/S0257-8972(99)00418-1
- Garcia-Miquel, J.L., Zhang, Q., Allen, S.J., Rougier, A., Blyr, A., Davies, H.O., Jones, A.C., Leedham, T.J., William, P.A. and Impey, S.A. (2003) Thin Solid Films, 424, 165-170. http://dx.doi.org/10.1016/S0040-6090(02)01041-6
- Park, J.W., Park, J.W., Kim, D.Y. and Lee, J.K. (2005) Journal of Vacuum Science & Technology A, 23, 1309-1313. http://dx.doi.org/10.1116/1.1953687
- Chen, H.L., Lu, Y.M. and Hwang, W.S. (2005) Thin Solid Films, 514, 361-365. http://dx.doi.org/10.1016/j.tsf.2006.04.041