Effect of Heat Treatment on the Nanoscale Structure and Optical Properties of Cd<sub>2</sub>SnO<sub>4</sub> Thin Films Deposited by RF Magnetron Sputtering — Oak Academic Publishing
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Effect of Heat Treatment on the Nanoscale Structure and Optical Properties of Cd<sub>2</sub>SnO<sub>4</sub> Thin Films Deposited by RF Magnetron Sputtering
Department of Physics, Taif University, Taif, Kingdom of Saudi Arabia
1 Department of Physics, Taif University, Taif, Kingdom of Saudi Arabia
Cadmium tin oxide Cd2SnO4 thin films with a thickness of 228.5 nm were prepared by RF magnetron sputtering technique on glass substrates at room temperature. AFM has been utilized to study the morphology of these films as a function of annealing temperature at the nanoscale. The optical properties of these films, such as the transmittance, T(λ), and reflectance, R(λ), have been studied as a function of annealing temperature. The optical constants, such as optical energy gap, width of the band tails of the localized states, refractive index, oscillatory energy, dispersion energy, real and imaginary parts of both dielectric constant and optical conductivity have been found to be affected by changing the annealing temperature of the films.
KeywordsThin FilmsAtomic Force MicroscopeTransmittanceReflectanceOptical Energy GapOptical Conductivity
Wang, J.X., Xie, S.S., Gao, Y., Yan, X.Q., Liu, D.F., Yuan, H.J. and Wang, G. (2004) Journal of Crystal Growth, 267, 177-183. http://dx.doi.org/10.1016/j.jcrysgro.2004.03.052
Shannon, R.D., Gillson, J.L. and Bouchard, R.J. (1977) Journal of Physics and Chemistry of Solids, 38, 877-881. http://dx.doi.org/10.1016/0022-3697(77)90126-3
Omata, T., Ueda, N., Ueda, K. and Kawazoe, H. (1994) Applied Physics Letters, 64, 1077-1078. http://dx.doi.org/10.1063/1.110937
Wu, X., Mulligan, W.P. and Coutts, T.J. (1996) Thin Solid Films, 286, 274-276. http://dx.doi.org/10.1016/S0040-6090(95)08527-0
Coutts, T.J., Young, D.L., Li, X., Mulligan, W.P. and Wu, X. (2000) Journal of Vacuum Science & Technology A, 18, 2646-2660. http://dx.doi.org/10.1116/1.1290371
Wu, X., Dhere, R.G., Albin, D.S., Gessert, T.A., Dehart, C., Keane, J.C. and Sheldon, P. (2001) High-Efficiency CTO/ ZTO/CdS/CdTe Polycrystalline Thin-Film Solar Cells. Proceedings of NCPV Program Review Meeting, 47.
Jayakrishnan, R. andHodes, G. (2003) Thin Solid Films, 440, 19-25. http://dx.doi.org/10.1016/S0040-6090(03)00811-3
Biswas, P.K., De, A., Pramanik, N.C., Chakraborty, P.K., Ortner, K., Hock, V. and Korder, S. (2003) Materials Letters, 57, 2326-2332. http://dx.doi.org/10.1016/S0167-577X(02)01220-X
Yamamoto, S., Yamanaka, T. and Ueda, Z. (1987) Journal of Vacuum Science & Technology A, 5, 1952-1955. http://dx.doi.org/10.1116/1.574889
Kobayashi, H., Mori, H., Ishida, T. and Nakato, Y. (1995) Journal of Applied Physics, 77, 1301-1307. http://dx.doi.org/10.1063/1.358932
Pla, J., Tamasi, M., Rizzoli, R., Losurdo, M., Centurioni, E., Summonte, C. and Rubinelli, F. (2003) Thin Solid Films, 425, 185-192. http://dx.doi.org/10.1016/S0040-6090(02)01143-4
Togashi, S. (1992) Optoelectronics—Devices and Technologies, 7, 271.
Kawachi, G., Kimura, E., Wakui, Y., Konishi, N., Yamamoto, H., Matsukawa, Y. and Sasano, A. (1994) IEEE Transactions on Electron Devices, 41, 1120-1124. http://dx.doi.org/10.1109/16.293338
Stanimirova, T.J., Atanasov, P.A., Dimitrov, I.G. and Dikovska, A.O. (2005) Journal of Optoelectronics and Advanced Materials, 7, 1335-1340.
Al-Baradi, A.M., El-Nahass, M.M., El-Raheem, M.A., Atta, A.A. and Hassanien, A.M. (2014) Radiation Physics and Chemistry, 103, 227-233. http://dx.doi.org/10.1016/j.radphyschem.2014.05.055
El-Nahass, M.M., Atta, A.A., El-Raheem, M.A. and Hassanien, A.M. (2014) Journal of Alloys and Compounds, 585, 1-6. http://dx.doi.org/10.1016/j.jallcom.2013.09.079
Mamazza, R., Morel, D.L. and Ferekides, C.S. (2005) Thin Solid Films, 484, 26-33. http://dx.doi.org/10.1016/j.tsf.2005.01.097
Burstein, E. (1954) Physical Review, 93, 632-633. http://dx.doi.org/10.1103/PhysRev.93.632
Moss, T.S. (1954) Proceedings of the Physical Society, Section B, 67, 775-782. http://dx.doi.org/10.1088/0370-1301/67/10/306
Ali, H.M., El-Raheem, M.A., Megahed, N.M. and Mohamed, H.A. (2006) Journal of Physics and Chemistry of Solids, 67, 1823-1829. http://dx.doi.org/10.1016/j.jpcs.2006.04.005
El-Raheem, M.A., Wakkad, M.M., Megahed, N.M., Ahmed, A.M., Shokr, E.K. and Dongol, M. (1996) Journal of Materials Science, 31, 5759-5764. http://dx.doi.org/10.1007/BF01160825
Urbach, F. (1953) Physical Review, 92, 1324. http://dx.doi.org/10.1103/PhysRev.92.1324
El-Raheem, M.A. (2007) Journal of Physics: Condensed Matter, 19, Article ID: 216209. http://dx.doi.org/10.1088/0953-8984/19/21/216209
Vigil, O., Cruz, F., Morales-Acevedo, A., Contreras-Puente, G., Vaillant, L. and Santana, G. (2001) Materials Chemistry and Physics, 68, 249-252. http://dx.doi.org/10.1016/S0254-0584(00)00358-8
Wemple, S.H. and DiDomenico Jr., M. (1971) Physical Review B, 3, 1338-1351. http://dx.doi.org/10.1103/PhysRevB.3.1338
Caglar, Y., Ilican, S. and Caglar, M. (2007) The European Physical Journal B, 58, 251-256. http://dx.doi.org/10.1140/epjb/e2007-00227-y
Wang, J.X., Xie, S.S., Gao, Y., Yan, X.Q., Liu, D.F., Yuan, H.J. and Wang, G. (2004) Journal of Crystal Growth, 267, 177-183. http://dx.doi.org/10.1016/j.jcrysgro.2004.03.052
Shannon, R.D., Gillson, J.L. and Bouchard, R.J. (1977) Journal of Physics and Chemistry of Solids, 38, 877-881. http://dx.doi.org/10.1016/0022-3697(77)90126-3
Omata, T., Ueda, N., Ueda, K. and Kawazoe, H. (1994) Applied Physics Letters, 64, 1077-1078. http://dx.doi.org/10.1063/1.110937
Wu, X., Mulligan, W.P. and Coutts, T.J. (1996) Thin Solid Films, 286, 274-276. http://dx.doi.org/10.1016/S0040-6090(95)08527-0
Coutts, T.J., Young, D.L., Li, X., Mulligan, W.P. and Wu, X. (2000) Journal of Vacuum Science & Technology A, 18, 2646-2660. http://dx.doi.org/10.1116/1.1290371
Wu, X., Dhere, R.G., Albin, D.S., Gessert, T.A., Dehart, C., Keane, J.C. and Sheldon, P. (2001) High-Efficiency CTO/ ZTO/CdS/CdTe Polycrystalline Thin-Film Solar Cells. Proceedings of NCPV Program Review Meeting, 47.
Jayakrishnan, R. andHodes, G. (2003) Thin Solid Films, 440, 19-25. http://dx.doi.org/10.1016/S0040-6090(03)00811-3
Biswas, P.K., De, A., Pramanik, N.C., Chakraborty, P.K., Ortner, K., Hock, V. and Korder, S. (2003) Materials Letters, 57, 2326-2332. http://dx.doi.org/10.1016/S0167-577X(02)01220-X
Yamamoto, S., Yamanaka, T. and Ueda, Z. (1987) Journal of Vacuum Science & Technology A, 5, 1952-1955. http://dx.doi.org/10.1116/1.574889
Kobayashi, H., Mori, H., Ishida, T. and Nakato, Y. (1995) Journal of Applied Physics, 77, 1301-1307. http://dx.doi.org/10.1063/1.358932
Pla, J., Tamasi, M., Rizzoli, R., Losurdo, M., Centurioni, E., Summonte, C. and Rubinelli, F. (2003) Thin Solid Films, 425, 185-192. http://dx.doi.org/10.1016/S0040-6090(02)01143-4
Togashi, S. (1992) Optoelectronics—Devices and Technologies, 7, 271.
Kawachi, G., Kimura, E., Wakui, Y., Konishi, N., Yamamoto, H., Matsukawa, Y. and Sasano, A. (1994) IEEE Transactions on Electron Devices, 41, 1120-1124. http://dx.doi.org/10.1109/16.293338
Stanimirova, T.J., Atanasov, P.A., Dimitrov, I.G. and Dikovska, A.O. (2005) Journal of Optoelectronics and Advanced Materials, 7, 1335-1340.
Al-Baradi, A.M., El-Nahass, M.M., El-Raheem, M.A., Atta, A.A. and Hassanien, A.M. (2014) Radiation Physics and Chemistry, 103, 227-233. http://dx.doi.org/10.1016/j.radphyschem.2014.05.055
El-Nahass, M.M., Atta, A.A., El-Raheem, M.A. and Hassanien, A.M. (2014) Journal of Alloys and Compounds, 585, 1-6. http://dx.doi.org/10.1016/j.jallcom.2013.09.079
Mamazza, R., Morel, D.L. and Ferekides, C.S. (2005) Thin Solid Films, 484, 26-33. http://dx.doi.org/10.1016/j.tsf.2005.01.097
Burstein, E. (1954) Physical Review, 93, 632-633. http://dx.doi.org/10.1103/PhysRev.93.632
Moss, T.S. (1954) Proceedings of the Physical Society, Section B, 67, 775-782. http://dx.doi.org/10.1088/0370-1301/67/10/306
Ali, H.M., El-Raheem, M.A., Megahed, N.M. and Mohamed, H.A. (2006) Journal of Physics and Chemistry of Solids, 67, 1823-1829. http://dx.doi.org/10.1016/j.jpcs.2006.04.005
El-Raheem, M.A., Wakkad, M.M., Megahed, N.M., Ahmed, A.M., Shokr, E.K. and Dongol, M. (1996) Journal of Materials Science, 31, 5759-5764. http://dx.doi.org/10.1007/BF01160825
Urbach, F. (1953) Physical Review, 92, 1324. http://dx.doi.org/10.1103/PhysRev.92.1324
El-Raheem, M.A. (2007) Journal of Physics: Condensed Matter, 19, Article ID: 216209. http://dx.doi.org/10.1088/0953-8984/19/21/216209
Vigil, O., Cruz, F., Morales-Acevedo, A., Contreras-Puente, G., Vaillant, L. and Santana, G. (2001) Materials Chemistry and Physics, 68, 249-252. http://dx.doi.org/10.1016/S0254-0584(00)00358-8
Wemple, S.H. and DiDomenico Jr., M. (1971) Physical Review B, 3, 1338-1351. http://dx.doi.org/10.1103/PhysRevB.3.1338