An Evaluation of the Calorific Values of the Branches and Stems of 11 Tropical Trees
- 1 Department of Pure and Industrial Chemistry, Nnamdi Azikwe University Awka, Awka, Nigeria
- 2 Department of Pure and Industrial Chemistry, Nnamdi Azikwe University Awka, Awka, Nigeria
- 3 Department of Pure and Industrial Chemistry, Nnamdi Azikwe University Awka, Awka, Nigeria
- 4 Department of Pure and Industrial Chemistry, Nnamdi Azikwe University Awka, Awka, Nigeria
Abstract
This work investigated and quantified the calorific values of the main branches and trunks of eleven (11) tropical trees in correlation with their chemical composition in order to assess their suitability for use as credible sources of wood fuel. The determination of the carbon, hydrogen, nitrogen, oxygen and sulphur (CHNOS) content of the samples was done using an organic elemental analyser, while an oxygen bomb calorimeter was used to experimentally determine their corresponding gross heat values. The experimental gross heat values for the branches examined ranged from 18,703.37 kJ/kg in Lophira lanceolata to 21,350.35 kJ/kg in Afzelia africana while that of the trunks ranged from 19,747.74 kJ/kg in Tectonia grandis to 22,408.68 kJ/kg in Prosopis africana . These values were within and about the expected ranges observed for tropical trees and may be considered adequate for wood fuel. The general trend in both branches and trunks was that the higher the carbon content, the higher the gross heat value of sample. The absence of sulphur in almost all the samples except, Prosopis africana , (0.055%) was indicative of the fact that the negative environmental impact with respect to harmful emissions of oxides of sulphur is practically non-existent with respect to these species. In the light of the aforementioned variables, the main branches of Afzelia africana (21,350.35 kJ/kg), Nauclea diderrichii (21,157.30 kJ/kg) and Tectonia grandis (20,257.13 kJ/kg) could be used as credible sources of firewood and charcoal production. With respect to the trunks, the timbers in order of preference would ideally be Prosopis africana (22,408.68 kJ/kg), Nauclea diderichii (21,436.42 kJ/kg) and Brachstigia eurychoma (20,924.7 kJ/kg).
- Khider, T.O. and Elsaki, T.O. (2012) Heat Value of Four Hardwood Species from Sudan. Journal of Forest Products & Industries, 1, 5-9.
- Ramachandra, T. and Kamakshi, G. (2005) Bioresource Potential of Karnataka. Technical Report No: 109: The Ministry of Environment and Forests, Government of India, Centre for Ecological Sciences, Indian Institute of Science, Bangalore. http://wgbis.ces.iisc.ernet.in/energy/paper/TR109/tr109_mainframe.htm
- Keita, J.D., (1987). Wood or Charcoal—Which Is Better? Unasylva: An International Journal of Forestry and Forest Industries. Vol.39. FAO—Food and Agriculture Organization of the United Nations, Rome. Richard Pardo (Ed.). http://www.fao.org/docrep/s4550e/s4550e09.htm
- Meathead, G. (2013) The Science of Charcoal: How Charcoal Is Made and How Charcoal Works. www.biofuelregion.se/UserFiles/file/Forest Refine/1_2_IS_2013-01-31_Basic_chemical_composition. pdf
- Tancredi, N., Cuna, A. and Yoshida, M. (2010) Wood Pyrolysis: Influence of Pyrolysis Temperature and Heating Rate on Charcoal Properties and Pyrolysis Process. Chemical Physics Research Journal, 3, 104-114.
- Moka, V.K. (2012) Estimation of Calorific Value of Biomass from Its Elementary Components by Regression Analysis. BTech Thesis. http://mechdocs-thesis.blogspot.com/2013/01/estimation-of-calorific-value-of.html
- Thermo Fisher Scientific Inc. (2008) Flash 2000 Series CHN/CHNS/ Oxygen Automatic Elemental Analyser. https://www.thermoscientific.com/content/dam/tfs/ATG/CMD/CMD%20Documents/BR-11012-FLASH-2000-Series-CHN-CHNS-Oxygen-Automatic-Elemental-Analyzer.pdf
- Parr Instrument Company (2008) Oxygen Bomb Calorimeter (1341). Illinois, p. 16.
- Dara, S.S. (1991) Experiments and Calculations in Engineering Chemistry. S. Chand and Co. Ltd., New Delhi, 185-191.
- Aloko, D.F. and Adebayo, G.A. (2007) Production and Characterization of Activated Carbon from Agricultural Wastes (Rice Husk and Corn Cob). Journal of Engineering and Applied Sciences, 2, 440-444.
- Azubuike, C.P and Okhamafe, A.O. (2012) Physicochemical, Spectroscopic and Thermal Properties of Microcrystalline Cellulose Derived from Corn Cobs. International Journal of Recycling Organic Waste in Agriculture, 1, 9.
- Mitchual, S.J., Frimpong-Mensah, K. and Darkwa, N.A. (2014) Evaluation of Fuel Properties of Six Tropical Hardwood Timber Species for Briquettes. Journal of Sustainable Bioenergy Systems, 4, 1-9. http://dx.doi.org/10.4236/jsbs.2014.41001