The record efficiency for a thin-film, single-junction solar cell has remained static at 28.8% since 2012. This research presents a unique design that demonstrates potential to exceed record efficiency and approach the theoretical efficiency limit of ~33.5%. The findings of this study are significant, from an efficiency standpoint, and also because the cell design can be realized using existing fabrication methods that do not require complex, post-processing steps. In this study, a benchmark simulation is developed that closely resembles a high-efficiency, front-and-back contact cell. Intrinsic performance limiters are overcome by moving the emitter and front-contact to the back of the cell to eliminate electrical grid shading and improve optical performance. To further improve performance, the P-N junction formed by the emitter layer is removed from the model to allow selective Ohmic contacts to accept (reject) minority (majority) carriers as required. The design modifications improve open-circuit voltage, short-circuit current, and fill-factor which collectively boost efficiency above 30%-primarily due to a 2% gain of incident irradiance and improved optical performance.
Shockley, W. and Queisser, H. (1961) Detailed Balance Limit of Efficiency of P-N Junction Solar Cells. Journal of Applied Physics, 32, 510-520. https://doi.org/10.1063/1.1736034
Miller, O., Yablonovich, E. and Kurtz, S. (2012) Strong Internal and External Luminescence as Solar Cells Approach the Shockley-Queisser Limit. IEEE Journal of Photovoltaics, 2, 303-311. https://doi.org/10.1109/JPHOTOV.2012.2198434
Green, M., Emery, K., Hishikawa, Y., Warta, W. and Dunlop, E. (2016) Solar Cell Efficiency Tables (Version 47). Progress in Photovoltaics Research and Applications, 24, 3-11. https://doi.org/10.1002/pip.2728
Miller, O. and Yablonovich, E. (2013) Photon Extraction, the Key Physics for Approaching Solar Cell Efficiency Limits. Proceedings of SPIE Conference Optics + Photonics, San Diego, 25-29 August 2013, 880807-1-10. https://doi.org/10.1117/12.2024592
Wang, X., Khan, M., Gray, J., Alam, M. and Lundstrom, M. (2016) Design of Gaas Cells Operating Close to the Shockley-Queisser Limit. IEEE Journal of Photovoltaics, 3, 737-744. https://doi.org/10.1109/JPHOTOV.2013.2241594
Yablonovich, E. (2011) The Optoelectronic Physics That Just Broke the Efficiency Record in Solar Cells. http://energyseminar.stanford.edu
Kayes, B., et al. (2011) 27.6% Conversion Efficiency—A New Record for Single Junction Solar Cells under 1 Sun Illumination. Proceedings of IEEE Photovoltaic Specialist Conference, Seattle, 19-24 June 2011, 4-8. https://doi.org/10.1109/pvsc.2011.6185831
Kayes, B., et al. (2012) Light Management in Single-Junction III-V Solar Cells. SPIE Optics + Photonics Conference Plenary Presentation, San Diego, 12-16 August 2012.
Bauhuis, G., Mulder, P., Haverkamp, E., Huijben, J. and Schermer, J. (2009) 26.1% Thin-Film Gaas Cell Using Epitaxial Lift-Off. Solar Energy Materials & Solar Cells, 93, 1488-1491. https://doi.org/10.1016/j.solmat.2009.03.027
O’Connor, J. and Michael, S. (2016) Impact of Operating Temperature and Absorption-Layer Thickness on All-Back-Contact Solar Cell Efficiency. Proceedings of EU Photovoltaic Solar Energy Conference, Munich, 20-24 June 2016, 983-986.
O’Connor, J. and Michael, S. (2016) Design and Optimization of a Novel Back-Contact Solar Cell in Silvaco®. Space Photovoltaic Research and Technology Conference, Cleveland, 20-22 September 2016, 1-3.
Lumb, M., Steiner, M., Geisz, J. and Walters, R. (2014) Incorporating Photon Diffusion Recycling into the Analytical Drift-Diffusion Model of High Efficiency Solar Cells. Journal of Applied Physics, 116, 116-125. https://doi.org/10.1063/1.4902320
Walker, A., et al. (2015) Impact of Photon Recycling on GaAs Solar Cell Designs. IEEE Journal of Photovoltaics, 5, 1636-1645. https://doi.org/10.1109/JPHOTOV.2015.2479463
Steiner, M., et al. (2013) Effects of Internal Luminescence and Internal Optics of Voc and Jsc of III-V Solar Cells. IEEE Journal of Photovoltaics, 3, 1437-1442. https://doi.org/10.1109/JPHOTOV.2013.2278666
Steiauf, D., Kioupakis, E. and van de Walle, C., (1993) Auger Recombination in GaAs from First Principles. ACS Photonics, 1, 643-646. https://doi.org/10.1021/ph500119q
IoffePhysico-Technical Institute (2016) Characteristics and Properties of Semiconductor Materials. http://www.ioffe.ru/SVA/NSM/
Lush, L., et al. (1991) Determination of Minority Carrier Lifetimes in N-Type GaAs and their Implications for Solar Cells. Proceedings of IEEE Photovoltaic Specialist Conference, Las Vegas, 7-11 October 1991, 182-187. https://doi.org/10.1109/pvsc.1991.169205
Ahrenkiel, R. (1992) Measurement of Minority-Carrier Lifetime by Time-Resolved Photoluminescence. Solid State Electronics, 35, 239-250. https://doi.org/10.1016/0038-1101(92)90228-5
Skauli, T., et al. (2003) Improved Dispersion Relations for GaAs and Applications to Nonlinear Optics. Journal of Applied Physics, 94, 6447-6455. https://doi.org/10.1063/1.1621740
Jellison Jr., G. (1992) Optical Functions of GaAs, GaP, and Ge Determined by Two-Channel Polarization Modulation Ellipsometry. Optical Materials, 1, 151-160. https://doi.org/10.1016/0925-3467(92)90022-F
Aspnes, D., Kelso, S., Logan, R. and Bhat, R. (1986) Optical Properties of AlGaAs. Journal of Applied Physics, 60, 754-767. https://doi.org/10.1063/1.337426
Kachare, A., Spitzer, W. and Fredrickson, J. (1976) Refractive Index of Ion-Implanted GaAs. Journal of Applied Physics, 47, 4209-4212. https://doi.org/10.1063/1.323292
Schroder, D. and Meier, D. (1984) Solar Cell Contact Resistance—A Review. IEEE Transactions on Electronic Devices, 31, 637-647. https://doi.org/10.1109/T-ED.1984.21583
Baca, A., Ren, F., Zolper, J., Briggs, R. and Pearton, S. (1997) A Survey of Ohmic Contacts to III-V Compound Semiconductors. Thin Solid Films, 308, 599-606. https://doi.org/10.1016/S0040-6090(97)00439-2
Ren, R., Cho, A., Sivco, D., Pearton, S. and Abernathy, C. (1994) Use of Sn-Doped GaAs for Non-Alloyed Ohmic Contacts to HEMTs. Electronic Letters, 30, 912-914. https://doi.org/10.1049/el:19940599
Green, M., Emery, K., Hishikawa, Y., Warta, W. and Dunlop, E. (2012) Solar Cell Efficiency Tables (Version 40). Progress in Photovoltaics: Research and Applications, 20, 606-614. https://doi.org/10.1002/pip.2267
Blakemore, J. (1982) Semiconducting and Other Major Properties of Gallium Arsenide. Journal of Applied Physics, 53, 123-181. https://doi.org/10.1063/1.331665
Michael, S. and O’Connor, J. (2016) GaAs Solar Cell with Back-Surface, Alternating-Contacts. US Patent Application 15/207,128.
O’Connor, J. and Michael, S. (2016) Emitter-Less, Back-Surface, Alternating-Contact Solar Cell. US Patent Application 15/282,460.